AlCl3-catalyzed hydrosilylation of alkynes with hydropolysilanes

Organometallics

Volumn 29, Issue 21, 2010, Pages 5274-5282

  Kato, Nobu ^a   Tamura, Yusuke ^a   Kashiwabara, Taigo ^a   Sanji, Takanobu ^a   Tanaka, Masato ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

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EID: 78149354825     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100376d     Document Type: Article

References (54)

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38. GC analysis showed that traces of many other products were also formed. GC-MS suggested that one of them was a compound coming from one molecule of 1-decyne and two molecules of pentamethyldisilane. Although detailed structural characterization was not made, it can be a simple double addition product or a compound like 4 found in the phenylacetylene reaction (vide infra).
39. (2-p -Anisylethyl)pentamethyldisilane was also formed in approximately 1% yield.
40. 3 has been reported. See ref 5n.
41. Details will be reported separately.
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45. (Z),α-and α,α-isomers corresponding to (Z, Z)-8fC could have also been formed as byproduct, although we did not try to search for these.
46. We have encountered similar observations in transition metal-catalyzed reactions of α,ω-dihydrooligosilanes. Among α,ω- dihydrooligosilanes, 1,2-dihydrodisilanes undergo more extensive redistribution than longer chained congeners. Details will be reported separately.
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53. 2Si. However we are unable to exclude the possibility that the material was contaminated with other octyl-rich polymeric materials.
54. 1H NMR spectroscopy.