Electrochemical preparation of Pt-based ternary alloy catalyst for direct methanol fuel cell anode

International Journal of Hydrogen Energy

Volumn 35, Issue 24, 2010, Pages 13309-13316

  Ahn, Sang Hyun ^a   Kwon, Oh Joong ^b   Kim, Soo Kil ^c   Choi, Insoo ^a   Kim, Jae Jeong ^a  

^a Seoul National University   (South Korea)

^b SolarLight Ltd   (South Korea)

^c Korea Institute of Science and Technology   (South Korea)

Author keywords

Direct methanol fuel cell; Electrodeposition; Galvanic displacement; Platinum based alloy catalyst

Indexed keywords

ALLOY CATALYST; CARBON PAPER; CATALYTIC ACTIVITY; CO PARTICLES; CO POISONING; CO-ELECTRODEPOSITION; DEPOSITION POTENTIAL; DIRECT METHANOL; ELECTROCHEMICAL METHODS; ELECTROCHEMICAL PREPARATION; ELECTROCHEMICAL PROCESS; ELECTRODEPOSITION PROCESS; GALVANIC DISPLACEMENT; MASS SPECTROSCOPY; METHANOL OXIDATION; PTRU/C CATALYSTS; SURFACE COMPOSITIONS;

ALLOYS; CATALYST POISONING; CATALYTIC OXIDATION; CHEMICAL ANALYSIS; DIRECT METHANOL FUEL CELLS (DMFC); ELECTRODEPOSITION; ELECTROMAGNETIC INDUCTION; INDUCTIVELY COUPLED PLASMA; MASS SPECTROMETRY; METHANOL; METHANOL FUELS; PAPER; PLATINUM; PLATINUM ALLOYS; X RAY PHOTOELECTRON SPECTROSCOPY;

CATALYST ACTIVITY;

EID: 78049465357     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.09.035     Document Type: Article

References (23)

1. 2/Ti anodes with a varying Pt:Ru ratio for direct methanol fuel cells J Power Sources 161 2 2006 813 819
2. B. Viswanathan Architecture of carbon support for Pt anodes in direct methanol fuel cells Catal Today 141 2008 52 55
3. A. Caillard, C. Coutanceau, P. Brault, J. Mathias, and J.-M. Léger Structure of Pt/C and PtRu/C catalytic layers prepared by plasma sputtering and electric performance in direct methanol fuel cells (DMFC) J Power Sources 162 1 2006 66 73
4. M. Chen, Z. Wang, and Y. Ding Investigation of the Pt-Ni-Pb/C ternary alloy catalysts for methanol electrooxidation Electrochem Commun 10 2008 443 446
5. J. Zeng, and J.Y. Lee Ruthenium-free, carbon-supported cobalt and tungsten containing binary & ternary Pt catalysts for the anodes of direct methanol fuel cells Int J Hydrogen Energy 32 2007 4389 4396
6. Q. Huang, H. Yang, Y. Tang, T. Lu, and D.L. Akins Carbon-supported Pt-Co alloy nanoparticles for oxygen reduction reaction Electrochem Commun 8 2006 1220 1224
7. X. Zhang, F. Zhang, and K.-Y. Chan Preparation of Pt-Ru-Co trimetallic nanoparticles and their electrocatalytic properties Catal Commun 5 2004 749 753
8. R. Bashyam, and P. Zelenay A class of non-precious metal composite catalysts for fuel cells Nature 443 2006 63 66
9. S.C. Zignani, E. Antolini, and E.R. Gonzalez Evaluation of the stability and durability of Pt and Pt-Co/C catalysts for polymer electrolyte membrane fuel cells J Power Sources 182 2008 83 90
10. Y. Kiros Electrocatalytic properties of Co, Pt, and Pt-Co on carbon for the reduction of oxygen in alkaline fuel cells J Electrochem Soc 143 1996 2152 2157
11. T. Iwasita, H. Hoster, A. John-Anaker, W.F. Lin, and W. Vielstich Methanol oxidation on PtRu electrodes. influence of surface structure and Pt-Ru atom distribution Langmuir 16 2000 522 529
12. 2/CO electro-oxidation on carbon supported Pt and its alloys using impedance based models J Electroanal Chem 556 2003 117 126
13. D. Lee, S. Hwang, and I. Lee A study on composite PtRu(1:1)-PtSn(3:1) anode catalyst for PEMFC J Power Sources 145 2005 147 153
14. Z. Cui, C. Liu, J. Liao, and W. Xing Highly active PtRu catalysts supported on carbon nanotubes prepared by modified impregnation method for methanol electro-oxidation Electrochim Acta 53 2008 7807 7811
15. P. Strasser, Q. Fan, M. Devenney, and W.H. Weinberg High throughput experimental and theoretical predictive screening of materials - a comparative study of search strategies for new fuel cell anode catalysts J Phys Chem B 107 2003 11013 11021
16. M.M.E. Duarte, A.S. Pilla, J.M. Sieben, and C.E. Mayer Platinum particles electrodeposition on carbon substrates Electrochem Commun 8 2006 159 164
17. K.H. Choi, H.S. Kim, and T.H. Lee Electrode fabrication for proton exchange membrane fuel cells by pulse electrodeposition J Power Sources 75 1998 230 235
18. Z. He, J. Chen, D. Liu, H. Zhou, and Y. Kuang Electrodeposition of Pt-Ru nanoparticles on carbon nanotubes and their electrocatalytic properties for methanol electrooxidation Diam Relat Mater 13 2004 1764 1770
19. D. Grujicic, and B. Pesic Electrochemical and AFM study of cobalt nucleation mechanisms on glassy carbon from ammonium sulfate solutions Electrochim Acta 49 2004 4719 4732
20. 2 reduction: Pt monolayer on Pd(111) and on carbon-supported Pd nanoparticles J Phys Chem B 108 2004 10955 10964
21. E. Herrero, and J.M. Feliu Scanning tunneling microscopy images of ruthenium submonolayers spontaneously deposited on a Pt(111) electrode Langmuir 15 1999 4944 4948
22. A. Dacc, G. Gemme, L. Mattera, and R. Parodi XPS analysis of the surface composition of niobium for superconducting RF cavities Appl Surf Sci 126 1998 219 230
23. J. Zeng, and J.Y. Lee Effects of preparation conditions on performance of carbon-supported nanosize Pt-Co catalysts for methanol electro-oxidation under acidic conditions J Power Sources 140 2005 268 273