Alkaline hydrogen peroxide as a degradation agent of methylene blue-kinetic and mechanistic studies

Reaction Kinetics, Mechanisms and Catalysis

Volumn 101, Issue 2, 2010, Pages 251-266

  Katafias, Anna ^a   Lipińska, Monika ^a   Strutyński, Karol ^a  

^a NICOLAUS COPERNICUS UNIVERSITY   (Poland)

Author keywords

Hydrogen peroxide; Kinetics; Methylene blue degradation; Thiazine dye hydrolytic decomposition

Indexed keywords

ALKALINE PEROXIDE; CATIONIC DYES; DEGRADATION AGENTS; DEMETHYLATION; FIRST ORDER KINETICS; FIRST-ORDER RATE CONSTANTS; HIGHER ORDER; HYDROGEN PEROXIDE CONCENTRATION; HYDROLYTIC PROCESS; ION CONCENTRATIONS; ION PAIRS; LINEAR DEPENDENCE; MECHANISTIC STUDIES; METHYLENE BLUE; RATE DEPENDENCE; RATE EXPRESSION; SUPPORTING ELECTROLYTE; THIAZINE DYE HYDROLYTIC DECOMPOSITION;

CHLORINE COMPOUNDS; DEGRADATION; DYES; HYDROGEN; HYDROGEN PEROXIDE; IONS; RATE CONSTANTS;

OXIDATION;

EID: 78049383153     PISSN: 18785190     EISSN: 18785204     Source Type: Journal    
DOI: 10.1007/s11144-010-0234-7     Document Type: Article

References (30)

1. TJ Collins 2002 TAML oxidant activators: a new approach to the activation of hydrogen peroxide for environmentally significant problems Acc Chem Res 35 782 1:CAS:528:DC%2BD38Xktl2ntLo%3D 10.1021/ar010079s
2. A Ghosh DA Mitchell A Chanda AD Ryabov DL Popescu EC Upham GJ Collins TJ Collins 2008 Catalase-peroxidase activity of iron(III)-TAML activators of hydrogen peroxide J Am Chem Soc 130 15116 1:CAS:528:DC%2BD1cXht1GnurbL 10.1021/ja8043689
3. CAS Regino DE Richardson 2007 Bicarbonate-catalyzed hydrogen peroxide oxidation of cysteine and related thiols Inorg Chim Acta 360 3971 1:CAS:528:DC%2BD2sXhtFKitr7L 10.1016/j.ica.2007.05.020
4. BS Lane K Burgess 2003 Metal-catalyzed epoxidation of alkenes with hydrogen peroxide Chem Rev 103 2457 1:CAS:528:DC%2BD3sXjsl2hs70%3D 10.1021/cr020471z
5. S-S Lin MD Gurol 1996 Heterogeneous catalytic oxidation of organic compounds by hydrogen peroxide Wat Sci Tech 34 57 10.1016/S0273-1223(96)00787-1 (Pubitemid 27007242)
6. Sawyer DT (1994) Oxygen: inorganic chemistry. In: King E (ed) Encyclopedia of inorganic chemistry, vol. 6. Wiley & Sons, Chichester, p 2951
7. SK Lee A Mills 2003 Novel photochemistry of leuco-methylene blue Chem Comm 18 2366 10.1039/b307228b
8. JP Tardivo AD Giglio CS de Oliveir DS Gabrielli HC Junqueira DB Tada D Severino R de Fátima Turchiello MS Baptista 2005 Methylene blue in photodynamic therapy: from basic mechanisms to clinical applications Photodiagn Photodyn Ther 2 175 1:CAS:528:DC%2BD28Xot1ehtw%3D%3D 10.1016/S1572-1000(05) 00097-9 (Pubitemid 41751085)
9. AC LeClaire TW Mullett MS Jahania JD Flynn 2005 Methemoglobinemia secondary to topical benzocaine use in a lung transplant patient Ann Pharmacother 39 373 10.1345/aph.1E315 (Pubitemid 40165233)
10. AD Quintǎo K Coutinho S Canuto 2002 Theoretical study of the hydrogen bond interaction between methylene blue and water and possible role on energy transfer for photodynamics Int J Quantum Chem 90 634 10.1002/qua.10059 and References therein
11. W Tang H Xu R Kopelman MA Philbert 2005 Photodynamic characterization and in vitro application of methylene blue-containing nanoparticle platforms Photochem Photobiol 81 242 1:CAS:528:DC%2BD2MXjslGmsL4%3D 10.1562/2004-05-24-RA- 176.1 (Pubitemid 40551499)
12. RA Floyd JE Schneider Jr DP Dittmer 2004 Methylene blue photoinactivation of RNA viruses Antivir Res 61 3 141 1:CAS:528:DC%2BD2cXpsV2ntA%3D%3D 10.1016/j.antiviral.2003.11.004 (Pubitemid 38183053)
13. M Wainwright 2003 Local treatment of viral disease using photodynamic therapy Int J Antimicrob Agents 21 510 1:CAS:528:DC%2BD3sXkt1ynu78%3D 10.1016/S0924-8579(03)00035-9 (Pubitemid 36668003)
14. (a) http://clinicaltrials.gov/ct2/show/NCT00587652. Accessed 05 Jan 2010;
15. (b) http://www.medscape.com. Accessed 10 Apr 2010;
16. (c) Chen YW, Lin JS, Fong JH, Wang IK, Chou SJ, Wu CH, Lui MT, Chang CS, Kao SY (2007) Use of methylene blue as a diagnostic aid in early detection of oral cancer and precancerous lesion. Br J Oral Maxillofac Surg 45(7): 590 and References therein
17. 2: an ambiguous system? J Photochem Photobiol A: Chem 127 123 1:CAS:528:DyaK1MXmtlSlt7s%3D 10.1016/S1010-6030(99)00143-4
18. Impert O, Katafias A, Kita P, Mills A, Pietkiewicz-Graczyk A, Wrzeszcz G (2003) Kinetics and mechanism of a fast leuco-Methylene Blue oxidation by copper(II)-halide species in acidic aqueous media. Dalton Trans pp 348-353
19. A Pietkiewicz-Graczyk O Impert A Katafias P Kita 2003 Reactivity of two protolytic forms of methylene blue in reaction with ascorbic acid Polish J Chem 77 75
20. A Katafias S Koter 2009 Autooxidation of leuco-methylene blue-the role of the methylene blue radicals and reactive oxygen species Polish J Chem 83 1139 1:CAS:528:DC%2BD1MXosFelsrc%3D
21. A Katafias P Kita A Mills G Wrzeszcz 2007 Kinetics of the methylene blue oxidation by cerium(IV) in sulfuric acid solutions Transition Met Chem 32 31 1:CAS:528:DC%2BD2sXns1SktQ%3D%3D 10.1007/s11243-006-0120-3 (Pubitemid 46154524)
22. VS Ferreira DB Magalhães SH Kling JG da Silvia EPS Bon 2000 N-demethylation of methylene blue by lignin peroxidase from phanerochaete chrysosporium Appl Biochem Biotechnol 84-86 255 10.1385/ABAB:84-86:1-9:255
23. 3+ on the oxidation of methylene blue by hydrogen peroxide Microchim Acta 143 53 1:CAS:528: DC%2BD3sXotVSgsLY%3D 10.1007/s00604-003-0036-y
24. AH Gemeay IA Mansour RG El-Sharkawy AB Zaki 2004 Kinetics of the oxidative degradation of thionine dye by hydrogen peroxide catalyzed by supported transition metal ions complexes J Chem Technol Biotechnol 79 85 1:CAS:528:DC%2BD2cXjvFSmtg%3D%3D 10.1002/jctb.917 (Pubitemid 38075581)
25. WJ MacNeal JA Kilian 1926 Chemical studies on polychrome methylene blue J Am Chem Soc 48 740 1:CAS:528:DyaB28XpvVCi 10.1021/ja01414a031
26. Plater MJ (2003) A degradation product of methylene blue. Arkivoc (i): 37
27. Brereton RG (2003) Chemometrics: data analysis for the laboratory and chemical plant. John Wiley & Sons, Chichester
28. Katritzky AR (1985) Handbook of heterocyclic chemistry. Pergamon Press, Oxford
29. A Katafias O Impert P Kita 2008 Hydrogen peroxide as a reductant of hexacyanoferrate(III) in alkaline solutions-kinetic studies Transition Met Chem 33 1041 1:CAS:528:DC%2BD1cXht1equrnM 10.1007/s11243-008-9150-3
30. Carey FA, Sundberg RJ (2007) Advanced organic chemistry, part A: structure and mechanism, 4th edn. Kluwer Academic, New York