A polymer electrolyte hydrogen pump hydrogenation reactor

Industrial and Engineering Chemistry Research

Volumn 49, Issue 21, 2010, Pages 11052-11060

  Benziger, Jay ^a   Nehlsen, James ^a  

^a Princeton University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBED HYDROGEN; AU CATALYSTS; CARBONYL GROUPS; HETEROGENEOUS CATALYSIS; HIGH CURRENT DENSITIES; HYDROGEN ADDITION; HYDROGEN PUMP; HYDROGENATION RATE; HYDROGENATION REACTORS; LANGMUIR-HINSHELWOOD KINETICS; LOW CURRENT DENSITY; ORGANIC LIQUID; POLYMER ELECTROLYTE; POROUS CARBONS; PROTON CURRENT; RATE-LIMITING STEPS;

ACETONE; ADSORPTION; CATALYSIS; CATALYSTS; CURRENT DENSITY; HYDROGEN; OLEFINS; PALLADIUM; PLATINUM; POLYELECTROLYTES; PROTONS; PUMPS; REACTION RATES; SURFACE REACTIONS;

HYDROGENATION;

EID: 78049356705     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie100631a     Document Type: Conference Paper

References (40)

1. Bartholomew, C. H. and Farrauto, R. J. Fundamentals of Industrial Catalytic Processes; Wiley: New York, 2006; p 966.
2. Weissermel, K. and Arpe, H.-J. Industrial Organic Chemistry; VCH: Weinheim, 1993; p 457.
3. Smith, G. V. and Notheisz, F. Heterogeneous Catalysis in Organic Chemistry; Academic Press: San Diego, CA, 1999; p 346.
4. Wittcoff, H. A. and Reuben, B. G. Industrial Organic Chemicals; Wiley: New York, 1996.
5. Davda, R. R.; Shabaker, J. W.; Huber, G. W.; Cortright, R. D.; Dumesic, J. A. A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts Appl. Catal., B 2005, 56 (1-2) 171-186
6. Huber, G. W.; Cortright, R. D.; Dumesic, J. A. Renewable alkanes by aqueous-phase reforming of biomass-derived oxygenates Angew. Chem., Int. Ed. 2004, 43 (12) 1549-1551
7. Huber, G. W.; Dumesic, J. A. An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery Catal. Today 2006, 111 (1-2) 119-132
8. Kunkes, E. L.; Soares, R. R.; Simonetti, D. A.; Dumesic, J. A. An integrated catalytic approach for the production of hydrogen by glycerol reforming coupled with water-gas shift Appl. Catal., B 2009, 90 (3-4) 693-698
9. Singh, U. K.; Vannice, M. A. Kinetics of liquid-phase hydrogenation reactions over supported metal catalysts - a review Appl. Catal., A 2001, 213 (1) 1-24
10. Dudukovic, M. P.; Larachi, F.; Mills, P. L. Multiphase reactors-revisited Chem. Eng. Sci. 1999, 54 (13-14) 1975-1995
11. Dudukovic, M. P.; Larachi, F.; Mills, P. L. Multiphase catalytic reactors: A perspective on current knowledge and future trends Catal. Rev.-Sci. Eng. 2002, 44 (1) 123-246
12. Mondal, K.; Lalvani, S. B. Electrochemical hydrogenation of canola oil using a hydrogen transfer agent J. Am. Oil Chem. Soc. 2003, 80 (11) 1135-1141
13. Mondal, K.; Lalvani, S. B. Mediator-assisted electrochemical hydrogenation of soybean oil Chem. Eng. Sci. 2003, 58 (12) 2643-2656
14. An, W.; Hong, J. K.; Pintauro, P. N. Current efficiency for soybean oil hydrogenation in a solid polymer electrolyte reactor J. Appl. Electrochem. 1998, 28 (9) 947-954
15. Yusem, G.; Pintauro, P. N.; Cheng, P. C.; An, W. Electrocatalytic hydrogenation of soybean oil in a radial flow-through Raney nickel powder reactor J. Appl. Electrochem. 1996, 26 (10) 989-997
16. Pintauro, P. N.; Gil, M. P.; Warner, K.; List, G.; Neff, W. Electrochemical hydrogenation of soybean oil with hydrogen gas Ind. Eng. Chem. Res. 2005, 44 (16) 6188-6195
17. Ogumi, Z.; Nishio, K.; Yoshizawa, S. Application of the SPE Method to Organic Electrochemistry. 2. Electrochemical Hydrogenation of Olefinic Double-Bonds Electrochim. Acta 1981, 26 (12) 1779-1782
18. Nehlsen, J. P. Developing Clean Fuels: Novel Techniques for Desulfurization; Princeton University: Princeton, NJ, 2006.
19. Millet, P.; Andolfatto, F.; Durand, R. Design and performance of a solid polymer electrolyte water electrolyzer Int. J. Hydrogen Energy 1996, 21 (2) 87-93
20. Deshmukh, S. S.; Boehm, R. F. Review of modeling details related to renewably powered hydrogen systems Renewable Sustainable Energy Rev. 2008, 12 (9) 2301-2330
21. Lessing, P. A. Materials for hydrogen generation via water electrolysis J. Mater. Sci. 2007, 42 (10) 3477-3487
22. Wee, J. H. Applications of proton exchange membrane fuel cell systems Renewable Sustainable Energy Rev. 2007, 11 (8) 1720-1738
23. Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications; Wiley: New York, 2001; p 833.
24. Ogumi, Z.; Ohashi, S.; Takehara, Z. Application of the SPE Method to Organic Electrochemistry. 6. Oxidation of Cyclohexanol to Cyclohexanone on Pt-SPE in the Presence of Iodine and Iodide Electrochim. Acta 1985, 30 (1) 121-124
25. Ogumi, Z.; Yamashita, H.; Nishio, K.; Takehara, Z. I.; Yoshizawa, S. Application of the Solid Polymer Electrolyte (SPE) Method to Organic Electrochemistry. 3. Kolbe Type Reactions on Pt-SPE Electrochim. Acta 1983, 28 (11) 1687-1693
26. An, W. D.; Hong, J. K.; Pintauro, P. N.; Warner, K.; Neff, W. The electrochemical hydrogenation of edible oils in a solid polymer electrolyte reactor. I. Reactor design and operation J. Am. Oil Chem. Soc. 1998, 75 (8) 917-925
27. An, W. D.; Hong, J. K.; Pintauro, P. N.; Warner, K.; Neff, W. The electrochemical hydrogenation of edible oils in a solid polymer electrolyte reactor. II. Hydrogenation selectivity studies J. Am. Oil Chem. Soc. 1999, 76 (2) 215-222
28. Lamy-Pitara, E.; Belegridi, I.; Barbier, J. Liquid-Phase Catalytic-Hydrogenation under Potential Control of the Catalyst Catal. Today 1995, 24 (1-2) 151-156
29. Cleghorn, S. J. C.; Pletcher, D. The Mechanism of Electrocatalytic Hydrogenation of Organic-Molecules at Palladium Black Cathodes Electrochim. Acta 1993, 38 (2-3) 425-430
30. Pardillos-Guindet, J.; Vidal, S.; Court, J.; Fouilloux, P. Electrode Potential of a Dispersed Raney-Nickel Electrode During Acetone Hydrogenation-Influence of the Solution and Reaction-Kinetics J. Catal. 1995, 155 (1) 12-20
31. Gardner, C. L.; Ternan, M. Electrochemical separation of hydrogen from reformate using PEM fuel cell technology J. Power Sources 2007, 171 (2) 835-841
32. Perry, K. A.; Eisman, G. A.; Benicewicz, B. C. Electrochemical hydrogen pumping using a high-temperature polybenzimidazole (PBI) membrane J. Power Sources 2008, 177 (2) 478-484
33. Casati, C.; Longhi, P.; Zanderighi, L.; Bianchi, F. Some fundamental aspects in electrochemical hydrogen purification/compression J. Power Sources 2008, 180 (1) 103-113
34. Abdulla, A. Y. The Electro-chemical Purification of Hydrogen Using Polymer Electrolyte Membrane Fuel Cells; Princeton University: Princeton, NJ, 2009.
35. Abdulla, A. Y.; Laney, K.; Padilla, M.; Sundaresan, S.; Benziger, J., Recovery and Energy Efficiency of Hydrogen Recovery from Reformate with a Polymer Electrolyte Hydrogen Pump. AIChE J. 2010, submitted.
36. Barbir, F.; Gorgun, H. Electrochemical hydrogen pump for recirculation of hydrogen in a fuel cell stack J. Appl. Electrochem. 2007, 37 (3) 359-365
37. Fogler, H. S. Elements of Chemical Reaction Engineering; Prentice Hall: Upper Saddle River, NJ, 2004; p 1080.
38. Lide, D. R. Handbook of Chemistry and Physics; CRC Press: Boca Raton, FL, 1992.
39. Perry, R. H.; Chilton, C. H. Chemical Engineer's Handbook; McGraw-Hill: New York, 1973.
40. Somorjai, G. A. Introduction to Surface Chemistry and Catalysis; John Wiley & Sons: New York, 1994.