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Volumn 20, Issue 43, 2010, Pages 9613-9615

How much can an electric dipole stabilize a nematic phase? Polar and non-polar isosteric derivatives of [closo-1-CB9H10] - and [closo-1,10-C2B8H10]

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC DIPOLE; HIGH DIELECTRIC ANISOTROPY; ISOSTERIC; MOLECULAR DIPOLE MOMENT; NEMATIC PHASE; NEMATIC SOLUTIONS; NEMATICS; NON-POLAR;

EID: 78049345255     PISSN: 09599428     EISSN: 13645501     Source Type: Journal    
DOI: 10.1039/c0jm02876b     Document Type: Article
Times cited : (31)

References (40)
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    • (1998) Handbook of Liquid Crystals , vol.1 , pp. 477-534
    • Blinov, L.M.1
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    • (2000) Angew. Chem. , vol.112 , pp. 4384-4405
  • 9
    • 0001268982 scopus 로고    scopus 로고
    • ed. D. Demus, J. W. Goodby, G. W. Gray, H.-W. Spiess and V. Vill, Wiley-VCH, New York
    • I. C. Sage, in Handbook of Liquid Crystals, ed., D. Demus,,, J. W. Goodby,,, G. W. Gray,,, H.-W. Spiess, and, V. Vill,, Wiley-VCH, New York, 1998, vol. 1, pp. 731-762
    • (1998) Handbook of Liquid Crystals , vol.1 , pp. 731-762
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  • 18
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    • It is assumed that the computed dipole moment values in vacuum are consistent in each series and well reflect the trend. The experimental dipole moments are solvent dependent and exact values are not important for present considerations
    • It is assumed that the computed dipole moment values in vacuum are consistent in each series and well reflect the trend. The experimental dipole moments are solvent dependent and exact values are not important for present considerations.
  • 19
    • 78049350529 scopus 로고    scopus 로고
    • For details see ESI
    • For details see ESI
  • 29
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    • and 643
    • W. H. Keesom Phys. Z. 1921 22 129 and 643;
    • (1921) Phys. Z. , vol.22 , pp. 129
    • Keesom, W.H.1
  • 31
    • 78049347011 scopus 로고    scopus 로고
    • NI in series 1-5 based on dimer formation (see ref. 6b) is also possible although less consistent with the data
    • NI in series 1-5 based on dimer formation (see ref. 6b) is also possible although less consistent with the data
  • 35
    • 78049342587 scopus 로고    scopus 로고
    • Electronic polarizability α is higher by 8% and its anisotropy Δα by 23% in the polar derivative 11b relative to 11a
    • Electronic polarizability α is higher by 8% and its anisotropy Δα by 23% in the polar derivative 11b relative to 11a.
  • 37
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    • 2-Chloro-4-heptylphenyl 4-heptylbicyclo[2.2.2]octane-1-carboxylate
    • 2-Chloro-4-heptylphenyl 4-heptylbicyclo[2.2.2]octane-1-carboxylate.
  • 38
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    • (2001) Physical Properties of Liquid Crystals: Nematics , pp. 523-581
    • Naemura, S.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.