Stereoselective total synthesis of (3 R,5 R)-5-hydroxy-de- O -methyllasiodiplodin via the prins cyclization

Synthesis

Volumn , Issue 21, 2010, Pages 3657-3662

  Yadav, Jhillu S ^a   Thrimurtulu, N ^a   Rahman, Md Ataur ^a   Reddy, J Satyanarayana ^a   Prasad, A R ^a   Reddy, B V Subba ^a  

^a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

esterification; lactone; Prins cyclization; reductive ring opening; ring closing metathesis

Indexed keywords

LACTONE; PRINS CYCLIZATION; REDUCTIVE OPENING; RING CLOSING METATHESIS; RING OPENING; STEREO-SELECTIVE; SYNTHETIC SEQUENCE; TOTAL SYNTHESIS;

ESTERIFICATION; ESTERS; STEREOSELECTIVITY;

CYCLIZATION;

2 (HYDROXYMETHYL) 6 METHYL TETRAHYDRO 2H PYRAN 4 OL; 2 [(TERT BUTYLDIMETHYLSILYLOXY)METHYL] 6 METHYL TETRAHYDRO 2H PYRAN 4 OL; 4 (BENZYLOXY) 2 (IODOMETHYL) 6 METHYL TETRAHYDRO 2H PYRAN; 4 (BENZYLOXY) 6 (METHOXYMETHOXY)HEPTAN 1 OL; 4 (BENZYLOXY)HEPT 6 EN 2 OL; 4 (BENZYLOXY)OCT 7 EN 2 OL; 4 (BENZYLOXY)OCT 7 EN 2 YL 2 ALLYL 4 (BENZYLOXY) 6 HYDROXYBENZOATE; 4 HYDROXYLASIODIPLODIN; 5 ALLYL 7 (BENZYLOXY) 2,2 DIMETHYL 4H 1,3 BENZODIOXIN 4 ONE; 5 HYDROXY DE O METHYLLASIODIPLODIN; 5,12 BIS(BENZYLOXY) 14 HYDROXY 3 METHYL 4,5,6,7 TETRA HYDRO 3H BENZO[C][1]OXACYCLODODECEN (10H) ONE; 5,12,14 TRIHYDROXY 3 METHYL 3,4,5,6,7,8,9,10 OCTAHYDRO 1H 2 BENZOXACYCLODODECIN 1 ONE; 6 HYDROXY DE O METHYLLASIODIPLODIN; [4 (BENZYLOXY) 6 METHYL TETRAHYDRO 2H PYRAN 2 YL]METHANOL; [[2 (METHOXYMETHOXY)OCT 7 EN 4 YLOXY]METHYL]BENZENE; [[4 (BENZYLOXY) 6 METHYL TETRAHYDRO 2H PYRAN 2 YL]METHOXY](TERT BUTYL)DIMETHYLSILANE; [[6 (METHOXYMETHOXY)HEPT 1 EN 4 YLOXY]METHYL]BENZENE; LACTONE DERIVATIVE; UNCLASSIFIED DRUG;

ANTINEOPLASTIC ACTIVITY; ARTICLE; BIOSYNTHESIS; COLUMN CHROMATOGRAPHY; CYCLIZATION; DRUG STRUCTURE; DRUG SYNTHESIS; ESTERIFICATION; OXIDATION; PURIFICATION; RING CLOSING METATHESIS; RING OPENING; STEREOCHEMISTRY;

EID: 77958516594     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0030-1258244     Document Type: Article

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