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77958090889
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The presence of at least two types of titanium(III) species in partially decomposed samples has also been detected by EPR (see SI).
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The presence of at least two types of titanium(III) species in partially decomposed samples has also been detected by EPR (see SI).
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24
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77958091250
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note
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CC ca. 30 Hz) in the case of 3a and 149.1 (broad) in the case of 3b, respectively. Details will be given in future publications.
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25
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77958104682
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note
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CH. "Through-space" F-H and F-C couplings, on the other hand, have been observed in many cases where the interatomic distances do not exceed the respective van der Waals contact distances (i.e., 2.5 Å for F⋯H vs 3.1 Å for F⋯C) and have been attributed to orbital interactions that transmit scalar couplings but do not cause net chemical bonding. (11) A "through-space" contribution to the observed F,C coupling might also take place for 3a.
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