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Volumn 2, Issue 9, 2010, Pages 1346-1354

Amperometric measurement of gaseous hydrogen sulfide via a Clark-type approach

Author keywords

[No Author keywords available]

Indexed keywords

AMPEROMETRIC; AMPEROMETRIC MEASUREMENTS; CURRENT TRANSIENTS; DIRECT OXIDATION; GAS SENSING; GASEOUS HYDROGEN; MEASUREMENT SYSTEM; MOLECULAR HYDROGEN; PARTS PER MILLIONS; STEADY-STATE VALUES;

EID: 77958086720     PISSN: 17599660     EISSN: 17599679     Source Type: Journal    
DOI: 10.1039/c0ay00338g     Document Type: Article
Times cited : (7)

References (41)
  • 16
    • 0031812831 scopus 로고    scopus 로고
    • Note that Clark probes are usually exposed, in operation, to dissolved dioxygen not gaseous dioxygen, see, for example, ref. 6d and 6e
    • C. E. W. Hahn Analyst 1998 123 57
    • (1998) Analyst , vol.123 , pp. 57
    • Hahn, C.E.W.1
  • 19
    • 49049115017 scopus 로고    scopus 로고
    • and references cited therein
    • J.-M. Savéant Chem. Rev. 2008 108 2348
    • (2008) Chem. Rev. , vol.108 , pp. 2348
    • Savéant, J.-M.1
  • 23
    • 0347256371 scopus 로고
    • i) can be approximated for the solution via the Extended Debye-Hückel Limiting Law, where z is the formal charge on species i and I is the ionic strength of the electrolyte
    • M. P. Sotto J. C. Boulliard Surf. Sci. 1985 162 285
    • (1985) Surf. Sci. , vol.162 , pp. 285
    • Sotto, M.P.1    Boulliard, J.C.2
  • 30
    • 33845265020 scopus 로고    scopus 로고
    • 2S sample causes a very large current which then decays rapidly (data not shown). Such phenomena were also observed when the aqueous electrolyte was replaced by a room temperature ionic liquid such as 1-butyl-3-methyl- imidazolium hexafluorophosphate (purchased from Sigma-Aldrich, data not shown) This has been suggested for the case of platinum electrodes immersed in highly alkaline sulfide solutions, q.v. ref. 17b and 17c
    • V. A. Sethuraman A. L. Wise S. Balasubramanian J. W. Weidner ECS Trans. 2006 1 111
    • (2006) ECS Trans. , vol.1 , pp. 111
    • Sethuraman, V.A.1    Wise, A.L.2    Balasubramanian, S.3    Weidner, J.W.4
  • 36
    • 0003598780 scopus 로고
    • A. J. Bard, R. Parsons, J. Jordan (ed.), Marcel Dekker, Inc., New York
    • A. J. Bard, R. Parsons, J. Jordan, (ed.), Standard potentials in aqueous solution, Marcel Dekker, Inc., New York, 1985
    • (1985) Standard Potentials in Aqueous Solution


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.