Quantification of C-H quenching in near-IR luminescent ytterbium and neodymium cryptates

Journal of the American Chemical Society

Volumn 132, Issue 41, 2010, Pages 14334-14335

  Bischof, Caroline ^a   Wahsner, Jessica ^a   Scholten, Julia ^a   Trosien, Simon ^a   Seitz, Michael ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CRYPTATES; EMISSION BANDS; GLOBAL FITTING; LANTHANOIDS; LIFETIME DATA; LUMINESCENCE LIFETIME; NEAR-IR; NON-RADIATIVE DEACTIVATION;

DEUTERIUM; LUMINESCENCE; STRUCTURAL ANALYSIS; YTTERBIUM;

NEODYMIUM;

NEODYMIUM; YTTERBIUM;

ARTICLE; LUMINESCENCE; NONPHOTOCHEMICAL QUENCHING; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 77958054758     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105768w     Document Type: Article

References (27)

1. Wang, F. and Liu, X. Chem. Soc. Rev. 2009, 38, 976
2. Binnemans, K. Chem. Rev. 2009, 109, 4283
3. Eliseeva, S. V. and Bünzli, J.-C. G. Chem. Soc. Rev. 2010, 39, 189
4. Faulkner, S., Pope, S. J. A., and Burton-Pye, B. P. Appl. Spectrosc. Rev. 2005, 40, 1
5. Comby, S. and Bünzli, J.-C. G. In Handbook on the Physics and Chemistry of Rare Earths, Vol. 37; Gschneidner, K. A., Jr., Bünzli, J.-C. G., and Pecharsky, V. K., Eds.; Elsevier: Amsterdam, 2007; p 217.
6. Browne, W. R. and Vos, J. G. Coord. Chem. Rev. 2001, 219-221, 761
7. Yanagida, S., Hasegawa, Y., Murakoshi, K., Wada, Y., Nakashima, N., and Yamanaka, T. Coord. Chem. Rev. 1998, 171, 461
8. Glover, P. B., Bassett, A. P., Nockemann, P., Kariuki, B. M., Van Deun, R., and Pikramenou, Z. Chem.-Eur. J. 2007, 13, 6308
9. Tan, R. H. C., Motevalli, M., Abrahams, I., Wyatt, P. B., and Gillin, W. P. J. Phys. Chem. B 2006, 110, 24476
10. Mancino, G., Ferguson, A: J., Beeby, A., Long, N. J., and Jones, T. S. J. Am. Chem. Soc. 2005, 127, 524
11. Hasegawa, Y., Sogabe, K., Wada, Y., and Yanagida, S. J. Lumin. 2003, 101, 235
12. Sveshnikova, E. B., Shakhverdov, P. A., Shakhverdov, T. A., Lanin, V. E., Safina, R. U., Bolotin, B. M., and Ermolaev, V. L. Opt. Spectrosc. (Eng. Transl.) 2003, 95, 898
13. Beeby, A., Burton-Pye, B. P., Faulkner, S., Motson, G. R., Jeffery, J. C., McCleverty, J. A., and Ward, M. D. J. Chem. Soc., Dalton Trans. 2002, 1923
14. Tsvirko, M. P., Meshkova, S. B., Venchikov, V. Ya., Topilova, Z. M., and Bol'shoǐ, D. V. Opt. Spectrosc. (Eng. Transl.) 2001, 90, 748
15. Hebbink, G. A., Reinhoudt, D. N., and van Veggel, F. C. J. M. Eur. J. Org. Chem. 2001, 4101
16. Faulkner, S., Beeby, A., Carrie, M.-C., Dadabhoy, A., Kenwright, A. M., and Sammes, P. G. Inorg. Chem. Commun. 2001, 4, 187
17. Beeby, A., Clarkson, I. M., Dickins, R. S., Faulkner, S., Parker, D., Royle, L., de Sousa, A. S., Williams, J. A. G., and Woods, M. J. Chem. Soc., Perkin Trans. 2 1999, 493
18. Wolbers, M. P. O., van Veggel, F. C. J. M., Snellink-Ruël, B. H. M., Hofstraat, J. W., Geurts, F. A. J., and Reinhoudt, D. N. J. Chem. Soc., Perkin Trans. 2 1998, 2141
19. Beeby, A. and Faulkner, S. Chem. Phys. Lett. 1997, 266, 116
20. Alpha, B., Lehn, J.-M., and Mathis, G. Angew. Chem., Int. Ed. 1987, 26, 266
21. Coldwell, J. B., Felton, C. E., Harding, L. P., Moon, R., Pope, S. J. A., and Rice, C. R. Chem. Commun. 2006, 5048
22. Korovin, V., Rusakova, N. V., and Popkov, A. J. Appl. Spectrosc. 2002, 69, 89
23. See Supporting Information for details.
24. 6]-DMSO for Nd proved to give the cleanest possible monoexponential decay kinetics in both cases.
25. 30]- Ln in the fitting procedures.
26. The quenching rate differences are only lower limits for the actual C-H quenching rates because the vibrational energies of C-D oscillators may also contribute to nonradiative deactivation.
27. i can only be approximative estimates.