GPC and ESI-MS analysis of labeled poly(1-hexene): Rapid determination of initiated site counts during catalytic alkene polymerization reactions

Journal of the American Chemical Society

Volumn 132, Issue 41, 2010, Pages 14352-14354

  Moscato, Beth M ^a   Zhu, Bolin ^a   Landis, Clark R ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1-HEXENE; ALKENE POLYMERIZATION; CATALYST RATIOS; CURRENT TECHNIQUES; MONOMER CONVERSIONS; NOVEL METHODS; OLEFIN POLYMERIZATION; POLYMER CHAINS; POLYMER MOLECULAR WEIGHT; RAPID DETERMINATION; UV DETECTOR; WEIGHT DISTRIBUTIONS; ZIRCONOCENES;

CATALYSTS; CHROMOPHORES; MOLECULAR WEIGHT DISTRIBUTION; MONOMERS; OLEFINS; POLYMERIZATION; STANDARDIZATION; ZIRCONIUM COMPOUNDS;

POLYMERS;

1 HEXENE; ALKENE; POLYMER; POLYOLEFIN; ZIRCONOCENE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHROMATOPHORE; ELECTROSPRAY MASS SPECTROMETRY; FLUORINE NUCLEAR MAGNETIC RESONANCE; GEL PERMEATION CHROMATOGRAPHY; MOLECULAR WEIGHT; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 77958031679     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105775r     Document Type: Article

References (23)

1. Boussie, T. R., Diamond, G. M., Goh, C., Hall, K. A., LaPointe, A. M., Leclerc, M. K., Murphy, V., Shoemaker, J. A. W., Turner, H., Rosen, R. K., Stevens, J. C., Alfano, F., Busico, V., Cipullo, R., and Talarico, G. Angew. Chem., Int. Ed. 2006, 45 (20) 3278-3283
2. Jones, D. J., Gibson, V. C., Green, S. M., Maddox, P. J., White, A. J. P., and Williams, D. J. J. Am. Chem. Soc. 2005, 127 (31) 11037-11046
3. Busico, V., Pellecchia, R., Cutillo, F., and Cipullo, R. Macromol. Rapid Commun. 2009, 30, 1697-1708
4. Gibson, V. C. and Spitzmesser, S. K. Chem. Rev. 2003, 103 (1) 283-315
5. Resconi, L., Cavallo, L., Fait, A., and Piemontesi, F. Chem. Rev. 2000, 100 (4) 1253-1346
6. Busico, V., Cipullo, R., Pellecchia, R., Rongo, L., Talarico, G., Macchioni, A., Zuccaccia, C., Froese, R. D. J., and Hustad, P. D. Macromolecules 2009, 42 (13) 4369-4373
7. Froese, R. D. J., Hustad, P. D., Kuhlman, R. L., and Wenzel, T. T. J. Am. Chem. Soc. 2007, 129 (25) 7831-7840
8. Kuhlman, R. L. and Wenzel, T. T. Macromolecules 2008, 41 (12) 4090-4094
9. Zuccaccia, C., Macchioni, A., Busico, V., Cipullo, R., Talarico, G., Alfano, F., Boone, H. W., Frazier, K. A., Hustad, P. D., Stevens, J. C., Vosejpka, P. C., and Abboud, K. A. J. Am. Chem. Soc. 2008, 130 (31) 10351-10368
10. Busico, V. Dalton Transactions 2009, 8794-8802
11. Liu, Z., Somsook, E., and Landis, C. R. J. Am. Chem. Soc. 2001, 123 (12) 2915-2916
12. Vatamanu, M., Boden, B. N., and Baird, M. C. Macromolecules 2005, 38 (24) 9944-9949
13. Chien, J. C. W. and Wang, B.-P. J. Polym. Sci., Part A: Polym. Chem. 1989, 27, 1539-1557
14. Chien, J. C. W. and Sugimoto, R. J. Polym. Sci., Part A: Polym. Chem. 1991, 29 (4) 459-470
15. Landis, C. R., Rosaaen, K. A., and Sillars, D. R. J. Am. Chem. Soc. 2003, 125 (7) 1710-1711
16. Tritto, I., Donetti, R., Sacchi, M. C., Locatelli, P., and Zannoni, G. Macromolecules 1999, 32 (2) 264-269
17. Detailed examination reveals that 3a -catalyzed 1-hexene polymerization exhibits complex behavior, probably due to the effects of the end group. Full details will be disclosed in a separate publication.
18. di Lena, F., Quintanilla, E., and Chen, P. Chem. Commun. 2005, 46, 5757-5759
19. Dietiker, R., di Lena, F., and Chen, P. J. Am. Chem. Soc. 2007, 129 (10) 2796-2802
20. Quintanilla, E., di Lena, F., and Chen, P. Chem. Commun. 2006, 41, 4309-4311
21. Moscato, B. M. and Landis, C. Chem. Commun. 2008, 44) 5785-5787
22. Novstrup, K. A., Travia, N. E., Medvedev, G. A., Stanciu, C., Switzer, J. M., Thomson, K. T., Delgass, W. N., Abu-Omar, M. M., and Caruthers, J. M. J. Am. Chem. Soc. 2010, 132 (2) 558-566
23. We note that, should transalkylation with other metal alkyls occur, this presents a mechanism for introducing the chromophore label in situ.