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/3 ] / ( π d3 6 / Vn,l 12 ), where d denotes the diameter of 18 nm and Vn,l donotes the unit-cell volume in the low-temperature phase of the nanosample that is obtained to be 118.32 Å3, as listed in Table .
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/ 3] / (π d 3 6 / V n, l 12), where d denotes the diameter of 18 nm and V n, l donotes the unit-cell volume in the low-temperature phase of the nanosample that is obtained to be 118.32 Å 3, as listed in Table.
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40
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77957691494
-
-
The nanosample used in the magnetic-susceptibility measurement in Fig. was prepared by ball milling for 30 h in H2 (1% ) /Ar gas. Another sample milled for 50 h in air, that was used in SR-XRD experiments, showed an almost identical result.
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The nanosample used in the magnetic-susceptibility measurement in Fig. was prepared by ball milling for 30 h in H 2 (1 %) / Ar gas. Another sample milled for 50 h in air, that was used in SR-XRD experiments, showed an almost identical result.
-
-
-
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42
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77957720898
-
-
/2, where ℏ, rd, m, and d denote the Planck's constant, the d -state radius, the electron mass, and the internuclear distance, respectively (Ref.). The energy splitting due to the π bonding is roughly determined by 2√ V pdπ 2 + V32 in using the diatomic molecule model, where V3 denotes the polar energy.
-
/ 2, where ℏ, r d, m, and d denote the Planck's constant, the d -state radius, the electron mass, and the internuclear distance, respectively (Ref.). The energy splitting due to the π bonding is roughly determined by 2 √ V p d π 2 + V 3 2 in using the diatomic molecule model, where V 3 denotes the polar energy.
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