Entrainer-based reactive distillation for esterification of glycerol with acetic acid

Industrial and Engineering Chemistry Research

Volumn 49, Issue 19, 2010, Pages 9058-9067

  Hasabnis, Amit ^a   Mahajani, Sanjay ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY BOMBAY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

AMBERLYST-15; CATALYST LOADINGS; CONTINUOUS PROCESS; CONVENTIONAL REACTORS; ETHYLENE DICHLORIDE; MOLE RATIO; OPERATING PARAMETERS; REACTIVE DISTILLATION SYSTEMS; REACTIVE DISTILLATIONS; SEMI-BATCH; TRIACETIN;

ACETIC ACID; CATALYSTS; COMPUTER SIMULATION; DISTILLATION EQUIPMENT; ESTERIFICATION; ESTERS; ETHYLENE; EXPERIMENTS; GLYCEROL; PH EFFECTS;

DISTILLATION;

EID: 77957600193     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie100937p     Document Type: Article

References (23)

1. Pagliaro, M.; Rosario, C.; Kimura, H.; Rossi, M.; Pina, C. D. Glycerol to value-added products Angew. Chem. Ind. Ed. 2007, 46, 4434-4440
2. Sharma, M. M.; Mahajani, S. M. Reactive Distillation: Status and Future Directions; Wiley-VCH: Weinheim, Germany, 2002; pp 3 - 29.
3. Thotla, S.; Srinivas, S.; Mahajani, S. M. Entrainer based reactive distillation of ethylene glycol with acetic acid Ind. Eng. Chem. Res. 2008, 47, 698-703
4. Kimura, K.; Ito, M. Jpn Patent. Kokai Tokkyo JP, 7495918; C.A. 1975,82,98724, 1974.
5. Teijin Ltd. Tertiary amine compound containing (meth)acrylic acid ester group and its preparation. Jpn Patent. Kokai Tokkyo Koho JP, 57,154,150; C. A. 1983, 98,35127, 1982.
6. Dimian, A. C.; Omoto, F.; Bliek, A. Entrainer enhanced reactive distillation Chem. Eng. Process 2004, 43, 411-420
7. Galan, M.; Bonet, J.; Sire, R.; Reneaume, J.; Piea, A. From residual to useful oil: Revalorization of glycerin from the biodiesel synthesis Bioresour. Technol. 2008, 100, 3775-3778
8. Kharmove, M. Process for production and purification of triacetin. U.S. Patent 5777157, 1998.
9. Hou, J.; Zhang, Q.; Shi, W.; Li, Y. New processes for synthesis of triacetin Henan Huagong 1998, 15, 18-19
10. Zhang, M.; Yuan, X. Synthesis of glycerol triacetate catalyzed by phosphotungstic acid Hecheng Huaxue 2001, 9, 469-472
11. 40 and purified by activated carbon Jingxi Shiyou Huagong. 2003, 2, 47-50
12. Bremus, N.; Gerhard, D.; Lutz, J.; Wolfgang, R.; Hartwig, S. Process for continuous production of triacetin, U.S. Patent 4381407, 1981.
13. Gelosa, D.; Ramaioli, M.; Valente, G.; Morbidelli, M. Chromatographic reactors: Esterification of glycerol with acetic acid using acidic polymeric resins Ind. Eng. Chem. Res. 2003, 42, 6536-6544
14. Lu, Z.; Ma, W. Studies on esterification reactions (1) esterification of glycerin with AA using ion exchange resin and drying agents as catalysts. Guangzhou Shiyuan Xuebao Ziran kexueban 1991, 53-56
15. Li, Y.; Zhu, W.; Yuan, Y. New rare earth solid superacid iron-based preparation and triacetin catalytic synthesis preparation of rare earth ironic solid-superacid and its use in catalyzing the synthesis of glycerol triacetates Synth. Chin. J. Synth. Chem. 2004, 12
16. Rong-hua, M. Catalytic synthesis of triacetate by heteropoly acid Norm. Sci. J. 2005, 25 (4
17. 2 used in synthesis of glycerol triacetate Huagong Jinzhan 2007, 26, 1041-1043
18. Herseczki, Z.; Morton, J. Glycerol-based eco-technologies using environmentally benign chemicals. 10th International Conference on Environmental Science and Technology, Kos Island, Greece, 2007, 5-7, September.
19. Melero, J. A.; Van, G. R.; Morales, G.; Panjagua, M. Acidic mesoporous silica for the acetylation of glycerol: Synthesis of bioadditives to petrol fuel Energy Fuels 2007, 21, 1782-1791
20. Ferreira, P.; Fonseka, I.; Ramos, A.; Vital, J.; Castanheiro, J. E. Esterification of glycerol with acetic acid over dodecamolybdophosphoric acid encaged in USY zeolite Catal. Commun. 2009, 10, 481-484
21. Marzieh, R.; Hassan, S. Continuous synthesis of glycerol acetates in supercritical carbon dioxide using Amberlyst-15 Green Chem. 2005, 11, 710-715
22. Thotla, S.; Agarwal, V.; Mahajani, S. M. Aldol condensation of acetone with reactive distillation using water as a selectivity enhancer Ind. Eng. Chem. Res. 2007, 46 (25) 8371-8379
23. Aspen Plus User Manual, Aspen plus, version 13.2; Aspen Technologies Inc.: Cambridge, MA.