Chromatographic Reactors: Esterification of Glycerol with Acetic Acid Using Acidic Polymeric Resins

Industrial and Engineering Chemistry Research

Volumn 42, Issue 25, 2003, Pages 6536-6544

  Gelosa, D ^a   Ramaioli, M ^a   Valente, G ^a   Morbidelli, M ^b  

^a POLITECNICO DI MILANO   (Italy)

^b ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ADSORPTION; CHEMICAL REACTORS; CHROMATOGRAPHY; ESTERIFICATION; MATHEMATICAL MODELS; REACTION KINETICS; RESINS; SYNTHESIS (CHEMICAL);

CHROMATOGRAPHIC REACTORS;

GLYCEROL;

ACETIC ACID; GLYCEROL; POLYMER; RESIN; TRIACETIN;

ACETIC ACID; CHROMATOGRAPHY; ESTERIFICATION; FIXED BED; INDUSTRIAL APPLICATION; REACTOR; SEPARATION;

ARTICLE; CALCULATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHROMATOGRAPHY; ESTERIFICATION; MATHEMATICAL MODEL; REACTION ANALYSIS; SYNTHESIS;

EID: 0344305526     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie030292n     Document Type: Article

References (15)

1. Lode, F.; Houmard M.; Migliorini, C.; Mazzoti, M.; Morbidelli, M. Continuous reactive chromatography. Chem. Eng. Sci. 2001, 56, 269-291.
2. Sardin, M.; Villermaux, J. Esterification catalysee par une resine echangeuse de cation dans un reacteur chromatographique. Nouv. J. Chim. 1979, 3, 225-235.
3. Kawase, M.; Suzuki, T. B.; Inoue, K.; Yoshimoto, K.; Hashimoto, K. Increased esterification convertion by application of the simulated moving bed reactor. Chem. Eng. Sci. 1996, 51, 2971-2981.
4. Mazzotti, M.; Kruglov, A.; Neri, B.; Gelosa, D.; Morbidelli, M. A continuous chromatographic reactor: SMBR. Chem. Eng. Sci. 1996, 51, 1827-1836.
5. Schmidt, J.; Reusch, D.; Elgeti, K.; Schoemacker, R.; Kinetic der Umesterung von Ethanol und Butylacetat-Ein Modellsystem fuer die Reaktivdestillation. Chemie Ingenieur Technik 1999, 71, 704-708.
6. Klier, K.; Beretta, A.; Sun, Q.; Feeley, O.; Herman, R. Catalytic synthesis of methanol, higher alcohols and ethers. Catal. Today 1997, 36, 3-14.
7. Ray, A.; Carr, R. W. Experimental study of a laboratory-scale simulated countercurrent moving bed chromatographic reactor. Chem. Eng. Sci. 1995, 50, 2195-2202.
8. Tonkovich, A. L.; Carr, R. W. A simulated countercurrent moving bed chromatographic reactor for the oxidative coupling of methane: Experimental results. Chem. Eng. Sci. 1994, 49, 4647-4656.
9. Kruglov, A. V.; Bjorklund, M. C.; Carr, R. W. Optimization of the simulated countercurrent moving-bed chromatographic reactor for the oxidative coupling of methane. Chem. Eng. Sci. 1996, 5, 2945-2950.
10. Hashimoto, K.; Adachi, S.; Noujima, H.; Ueda, Y. A new process combining adsorption and enzyme reaction for producing higher-fructose syrup. Biotechnol. Bioeng. 1983, 25, 2371-2393.
11. Lode, F. A Simulated Moving Bed Reactor (SMBR) for Esterifications. Ph.D. Dissertation, ETH Zurich, Zurich, Switzerland, 2001.
12. Foerster, D.; Neumann, D.; Bergmann, H. German (East) Patent, 134,867, 1979.
13. Flory, P. Principles of Polymer Chemistry; Cornell University Press: Ithaca, NY, 1953.
14. Reid, R. C.; Prausnitz, J. M.; Sherwood, T. K. The Properties of Gases and Liquids; McGraw-Hill: New York, 1977.
15. Chung, S. F.; Wen, C. Y. Longitudinal dispersion of liquid moving through fixed and fluidized beds. AIChE J. 1968, 17, 857-874.