Development of Fe-Ni/YSZ-GDC electrocatalysts for application as SOFC anodes: XRD and TPR characterization and evaluation in the ethanol steam reforming reaction

International Journal of Hydrogen Energy

Volumn 35, Issue 20, 2010, Pages 11216-11228

  Da Paz Fiuza, Raigenis ^a   Aurélio Da Silva, Marcos ^a   Boaventura, Jaime Soares ^a  

^a FEDERAL UNIVERSITY OF BAHIA   (Brazil)

Author keywords

Anode; Carbon deposition; Ethanol; Iron nickel catalyst; Reforming; Solid oxide fuel cell (SOFC)

Indexed keywords

BIMETALLIC SAMPLES; CARBON DEPOSITION; ETHANOL CONVERSION; ETHANOL STEAM REFORMING; FENI ALLOYS; GADOLINIA DOPED CERIA; HYDROGEN YIELDS; IRON-NICKEL CATALYST; METAL CONTENT; MIXED OXIDE; PECHINI; PHYSICAL MIXTURES; POLYMERIC PRECURSORS; REDUCTION TEMPERATURES; REFORMING; SOFC ANODE; SOLID OXIDE; SPINEL STRUCTURE; TEMPERATURE RANGE; TEMPERATURE-PROGRAMMED REDUCTION; XRD;

CALCINATION; CATALYST ACTIVITY; CERIUM COMPOUNDS; ELECTROCATALYSTS; ETHANOL; GAS PRODUCERS; IRON ALLOYS; MIXTURES; NICKEL; REFORMING REACTIONS; SOLID OXIDE FUEL CELLS (SOFC); STEAM ENGINEERING; X RAY DIFFRACTION; YTTRIA STABILIZED ZIRCONIA; ZIRCONIA;

HYDROGEN PRODUCTION;

EID: 77957367403     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.07.026     Document Type: Article

References (55)

1. E.S. Hecht, G.K. Gupta, H. Zhu, A.M. Dean, R.J. Kee, and L. Maier Methane reforming kinetics within a Ni-YSZ SOFC anode support Applied Catalysis A: General 295 2005 40 51
2. A. Atkinson, S. Barnett, R.J. Gorte, J.T.S. Irvine, A.J. McEvoy, and M. Mogensen Advanced anodes for high-temperature fuel cells Nature Materials 3 2004 17 27
3. B. Huang, S.R. Wang, R.Z. Liu, and T.L. Wen Preparation and performance characterization of the Fe-Ni/ScSZ cermet anode for oxidation of ethanol fuel in SOFCs Journal of Power Sources 167 2007 288 294 (Pubitemid 46575156)
4. S.L. Douvartzides, F.A. Coutelieris, A.K. Demin, and P.E. Tsiakaras Electricity from ethanol fed SOFCs: the expectations for sustainable development and technological benefits International Journal of Hydrogen Energy 29 2004 375 379
5. I.C. Macedo, J.E.A. Seabra, and J.E.A.R. Silva Green house gases emissions in the production and use of ethanol from sugarcane in Brazil: the 2005/2006 averages and a prediction for 2020 Biomass & Bioenergy 32 2008 582 595
6. S.D. Park, J.M. Vohs, and R.J. Gorte Direct oxidation of hydrocarbons in a solid-oxide fuel cell Nature 404 2000 265 267
7. S.A. Venancio, T.F. Gutierres, B.J.M. Sarruf, and P.E.V. Miranda Direct oxidation of ethanol in SOFC anodes Materia-Rio De Janeiro 13 2008 560 568
8. 2 anodes for SOFCs running on ethanol fuels Solid State Ionics 180 2009 276 281
9. M. Cimenti, and J.M. Hill Direct utilization of ethanol on ceria-based anodes for solid oxide fuel cells Asia-Pacific Journal of Chemical Engineering 4 2009 45 54
10. C. Resini, M.C.H. a Delgado, S. Presto, L.J. Alemany, P. Riani, and R. Marazza Yttria-stabilized zirconia (YSZ) supported Ni-Co alloys (precursor of SOFC anodes) as catalysts for the steam reforming of ethanol International Journal of Hydrogen Energy 33 2008 3728 3735
11. S.P. Jiang, and S.H. Chan A review of anode materials development in solid oxide fuel cells Journal of Materials Science 39 2004 4405 4439
12. R.S. Amado, L.F.B. Malta, F.M.S. Garrido, and M.E. Medeiros Solid oxide fuel cells: materials, components and configurations Quimica Nova 30 2007 189 197
13. X.Y. Zhao, Q. Yao, S.Q. Li, and N.S. Cai Studies on the carbon reactions in the anode of deposited carbon fuel cells Journal of Power Sources 185 2008 104 111
14. J. Mermelstein, M. Millan, and N.P. Brandon The impact of carbon formation on Ni-YSZ anodes from biomass gasification model tars operating in dry conditions Chemical Engineering Science 64 2009 492 500
15. I. Gavrielatos, V. Drakopoulos, and S.G. Neophytides Carbon tolerant Ni-Au SOFC electrodes operating under internal steam reforming conditions Journal of Catalysis 259 2008 75 84
16. D. La Rosa, A. Sin, M. Lo Faro, G. Monforte, V. Antonucci, and A.S. Arico Mitigation of carbon deposits formation in intermediate temperature solid oxide fuel cells fed with dry methane by anode doping with barium Journal of Power Sources 193 2009 160 164
17. R.T.K. Baker Catalytic growth of carbon filaments Carbon 27 1989 315 323
18. J.-H. Koh, Y.-S. Yoo, J.-W. Park, and H.C. Lim Carbon deposition and cell performance of Ni-YSZ anode support SOFC with methane fuel Solid State Ionics 149 2002 157 166
19. H.C. Park, and A.V. Virkar Bimetallic (Ni-Fe) anode-supported solid oxide fuel cells with gadolinia-doped ceria electrolyte Journal of Power Sources 186 2009 133 137
20. R.F. Martins, M.C. Brant, R.Z. Domingues, R.M. Paniago, K. Sapag, and T. Matencio Synthesis and characterization of NiO-YSZ for SOFCs Materials Research Bulletin 44 2009 451 456
21. N.F.P. Ribeiro, M. Souza, O.R.M. Neto, S.M.R. Vasconcelos, and M. Schmal Investigating the microstructure and catalytic properties of Ni/YSZ cermets as anodes for SOFC applications Applied Catalysis A-General 353 2009 305 309
22. 4 synthesized by a sol-gel method for Li-ion batteries Journal of the Electrochemical Society 157 2010 A528 A535
23. M.A. Silva, M.G.F. Alencar, R.P. Fiuza, and J.S. Boaventura Preparaão e Avaliaão de Célula a Combustível do Tipo PaCOS Unitária com Ânodo a base de Níquel e Cobalto Revista Matéria 12 2007 72 85
24. A.W. Burton, K. Ong, T. Rea, and I.Y. Chan On the estimation of average crystallite size of zeolites from the Scherrer equation: A critical evaluation of its application to zeolites with one-dimensional pore systems Microporous and Mesoporous Materials 117 2009 75 90
25. C.B.P. Ligiero, L.A. dos Reis, G.L. Parrilha, M. Baptista, and M.C. Canela Comparison of quantification methods in gas chromatography: an experiment for chemistry courses Quimica Nova 32 2009 1338 1341
26. C.G. Hill Introduction to chemical engineering kinetics and reactor design 1977 Wiley New York
27. J.L. Figueredo, and F.R. Ribeiro Catálise heterogênea 2nd ed. 2007 Fundaão Calouste Gulbenkain Lisbone
28. Coordenaão de Aperfeioamento de Pessoal de Nível Superior (CAPES, Brazilian Agency for the Advancement of High Eduction) (2009) http://www.capes.gov.br, accessed on December 03, 2009.
29. 2-x Applied Catalysis B: Environmental 47 2004 127 131
30. 2 Applied Surface Science 161 2000 301 315
31. 2 for the steam reforming of ethanol: effect of the support and nickel load Journal of Power Sources 177 2008 24 32
32. J.B. Goodenough Oxide-ion electrolytes Annual Review of Materials Research 33 2003 91 128
33. K.S.A. Halim, M.H. Khedr, and N.K. Soliman Reduction characteristics of iron oxide in nanoscale Materials Science and Technology 26 2010 445 452
34. 2 film on Pd by the time lag method Journal of Alloys and Compounds 231 1995 315 320
35. 3 catalysts for carbon dioxide reforming of methane Applied Catalysis B-Environmental 19 1998 267 277
36. 3 catalysts Applied Catalysis A-General 251 2003 275 283
37. 3 supported catalysts for ethanol steam reforming Formation of hydrotalcite-type compounds as a result of metal-support interaction Applied Catalysis A-General 238 2003 41 54
38. 2 catalysts Catalysis Communications 7 2006 380 386 (Pubitemid 44389609)
39. 3 (M = Ce, La, Zr and Mg) catalysts: influence of support on the hydrogen production International Journal of Hydrogen Energy 32 2007 1462 1471
40. V.M. Gonzalez-DelaCruz, J.P. Holgado, R. Pereniguez, and A. Caballero Morphology changes induced by strong metal-support interaction on a Ni-ceria catalytic system Journal of Catalysis 257 2008 307 314
41. 2 system: hydrogen-induced burial and dig out of metallic nickel Chemical Communications 46 2010 1097 1099
42. P. Munster, and H.J. Grabke Kinetics of the steam reforming of methane with iron, nickel, and iron-nickel alloys as catalysts Journal of Catalysis 72 1981 279 287
43. V.A.D. O'Shea, R. Nafria, P.R. de la Piscina, and N. Homs Development of robust Co-based catalysts for the selective H-2-production by ethanol steam-reforming. The Fe-promoter effect International Journal of Hydrogen Energy 33 2008 3601 3606
44. Y. Sekine, A. Kazama, Y. Izutsu, M. Matsukata, and E. Kikuchi Steam reforming of ethanol over cobalt catalyst modified with small amount of iron Catalysis Letters 132 2009 329 334
45. 3, and Fe- and Mn-promoted Co/ZnO catalysts Journal of Power Sources 169 2007 158 166
46. H.F. Abbas, and W. Daud Hydrogen production by methane decomposition: a review International Journal of Hydrogen Energy 35 2010 1160 1190
47. X.F. Ye, S.R. Wang, Z.R. Wang, L. Xiong, X.E. Sun, and T.L. Wen Use of a catalyst layer for anode-supported SOFCs running on ethanol fuel Journal of Power Sources 177 2008 419 425
48. H. Muroyama, R. Nakase, T. Matsui, and K. Eguchi Ethanol steam reforming over Ni-based spinel oxide International Journal of Hydrogen Energy 35 2010 1575 1581
49. Silva MA. Célula a combustível do tipo SOFC a etanol com reforma direta. Master's thesis, Universidade Federal da Bahia, Instituto de Química, Salvador - Bahia, 2007.
50. M. Godinho, R.F. Gonalves, E.R. Leite, C.W. Raubach, H.L.V. Carreño, and L.F.D. Probst Gadolinium-doped cerium oxide nanorods: novel active catalysts for ethanol reforming Journal of Materials Science 45 2010 593 598
51. A.J. Vizcaíno, A. Carrero, and J.A. Calles Hydrogen Production by Ethanol Steam Reforming Over Cu-Ni Supported Catalysts International Journal of Hydrogen Energy 32 2007 1450 1461
52. A. Denis, W. Grzegorczyk, W. Gac, and A. Machocki Steam reforming of ethanol over Ni/support catalysts for generation of hydrogen for fuel cell applications Catalysis Today 137 2008 453 459
53. 3 supported nickel catalysts used for steam reforming of ethanol International Journal of Hydrogen Energy 34 2009 4735 4746
54. 3 catalysts: effect of mg International Journal of Hydrogen Energy 33 2008 3489 3492
55. 3 catalysts promoted by noble metals International Journal of Hydrogen Energy 34 2009 5049 5060