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A interaction between receptor and dye with respect to analyte molecules could be modeled to some extent in a non-polar organic solvent that mimics the environment in the bilayer membrane (see the Supporting Information)
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A interaction between receptor and dye with respect to analyte molecules could be modeled to some extent in a non-polar organic solvent that mimics the environment in the bilayer membrane (see the Supporting Information).
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The different responses can be explained on the basis of our suggested hypothesis. The carboxyfluorescein-derived dye presents rather bulky head groups that provide a comparatively large free volume, which contracts to a tight packing in homogeneous phase. When expelled from the receptor-ligand proximity during patch segregation, the molecular structure of the dye suggests that it tends to distribute more or less separately within the lipid-enriched phase surrounding the patch. This results in the emission increase owing to the enhanced freedom of movement of the dye. The coumarin-derived dye presents relatively compact aromatic heads, which can stack and form tightly arranged assemblies around the phosphate-bound patch during segregation, which causes self-quenching
-
The different responses can be explained on the basis of our suggested hypothesis. The carboxyfluorescein-derived dye presents rather bulky head groups that provide a comparatively large free volume, which contracts to a tight packing in homogeneous phase. When expelled from the receptor-ligand proximity during patch segregation, the molecular structure of the dye suggests that it tends to distribute more or less separately within the lipid-enriched phase surrounding the patch. This results in the emission increase owing to the enhanced freedom of movement of the dye. The coumarin-derived dye presents relatively compact aromatic heads, which can stack and form tightly arranged assemblies around the phosphate-bound patch during segregation, which causes self-quenching.
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This refers to the charge of the coordinated metal ion in the amphiphilic ligand, neglecting the counterion
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This refers to the charge of the coordinated metal ion in the amphiphilic ligand, neglecting the counterion.
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38
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77956915265
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At present, data for a detailed phase-diagram plotting are not fully obtained; we are actively pursuing this goal
-
At present, data for a detailed phase-diagram plotting are not fully obtained; we are actively pursuing this goal.
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