Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-1

Inorganic Chemistry Communications

Volumn 13, Issue 11, 2010, Pages 1357-1360

  Wei, Ying ^a,b   Gies, Hermann ^c   Tian, Zhijian ^a   Marler, Bernd ^c   Xu, Yunpeng ^a   Wang, Lei ^a   Ma, Huaijun ^a   Pei, Renyan ^a,b   Li, Keda ^a,b   Wang, Bingchun ^a  

^a DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^c RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

Ionic liquids; Ionothermal synthesis; Layered structure; Nickel diphosphate; Open framework

Indexed keywords

EID: 77956928314     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.07.036     Document Type: Article

References (31)

1. R. Murugavel, A. Choudhury, M.G. Walawalkar, R. Pothiraja, and C.N.R. Rao Chem. Rev. 108 2008 3549
2. S. Natarajan, and S. Mandal Angew. Chem. Int. Ed. 47 2008 4798
3. D. Maspoch, D. Ruiz-Molina, and J. Veciana Chem. Soc. Rev. 36 2007 770
4. N. Guillou, Q.M. Gao, M. Nogues, R.E. Morris, M. Hervieu, G. Ferey, and A.K. Cheetham C. R. Acad. Sci. Paris, Ser. II C 2 1999 387
5. N. Guillou, Q. Gao, P.M. Forster, J.S. Chang, M. Nogues, S.E. Park, G. Ferey, and A.K. Cheetham Angew. Chem. Int. Ed. 40 2001 2831
6. J.S. Chang, S.E. Park, Q.M. Gao, G. Ferey, and A.K. Cheetham Chem. Commun. 2001 859
7. P.M. Forster, J. Eckert, J.S. Chang, S.E. Park, G. Ferey, and A.K. Cheetham J. Am. Chem. Soc. 125 2003 1309
8. S.H. Jhung, J.H. Lee, A.K. Cheetham, G. Ferey, and J.S. Chang J. Catal. 239 2006 97
9. A. Goni, J.L. Pizarro, L.M. Lezama, G.E. Barberis, M.I. Arriortua, and T. Rojo J. Mater. Chem. 6 1996 421
10. N. Hamanaka, and H. Imoto Inorg. Chem. 37 1998 5844
11. W. Liu, X.X. Yang, H.H. Chen, Y.X. Huang, W. Schnelle, and J.T. Zhao Solid State Sci. 6 2004 1375
12. A. Daidouh, J.L. Martinez, C. Pico, and M.L. Veiga J. Solid State Chem. 144 1999 169
13. F. Sanz, C. Parada, J.M. Rojo, and C. Ruiz-Valero Chem. Mater. 11 1999 2673
14. J. Escobal, J.L. Pizarro, J.L. Mesa, M.I. Arriortua, and T. Rojo J. Solid State Chem. 154 2000 460
15. E.R. Cooper, C.D. Andrews, P.S. Wheatley, P.B. Webb, P. Wormald, and R.E. Morris Nature 430 2004 1012
16. E.R. Parnham, and R.E. Morris Acc. Chem. Res. 40 2007 1005
17. E.R. Parnham, P.S. Wheatley, and R.E. Morris Chem. Commun. 2006 380
18. E.R. Parnham, and R.E. Morris J. Am. Chem. Soc. 128 2006 2204
19. E.A. Drylie, D.S. Wragg, E.R. Parnham, P.S. Wheatley, A.M.Z. Slawin, J.E. Warren, and R.E. Morris Angew. Chem. Int. Ed. 46 2007 7839
20. H.Z. Xing, J.Y. Li, W.F. Yan, P. Chen, Z. Jin, J.H. Yu, S. Dai, and R.R. Xu Chem. Mater. 20 2008 4179
21. L. Liu, Y. Li, H.B. Wei, M. Dong, J.G. Wang, A.M.Z. Slawin, J.P. Li, J.X. Dong, and R.E. Morris Angew. Chem. Int. Ed. 48 2009 2206
22. L. Liu, D.S. Wragg, H. Zhang, Y. Kong, P.J. Byrne, T.J. Prior, J.E. Warren, Z. Lin, J. Dong, and R.E. Morris Dalton Trans. 2009 6715
23. J.D. Feng, K.Z. Shao, S.W. Tang, R.S. Wang, and Z.M. Su Cryst. Eng. Comm. 12 2010 1401
24. H.Z. Xing, W.T. Yang, T. Su, Y. Li, J. Xu, T. Nakano, J.H. Yu, and R.R. Xu Angew. Chem. Int. Ed. 49 2010 2328
25. Y. Wei, Z.J. Tian, H. Gies, R.S. Xu, H.J. Ma, R.Y. Pei, W.P. Zhang, Y.P. Xu, L. Wang, K.D. Li, G.D. Wan, L.W. Wen, and L.W. Lin Angew. Chem. Int. ed. 49 2010 5367
26. 2O) dissolved completely in the ionic liquid, 1-butyl-3-methyl imidazolium bromide ([BMIM]Br) (20.10 g, 91.8 mmol). The mixture was placed in a 70 ml PTFE-lined stainless-steel autoclave, and then was heated in an oven at 170 °C for 6 days. The obtained light-green solid was filtered off, washed with an excess of distilled water and dried at 110 °C overnight. Scanning electron micrograph obtained on a Hitachi S4800 field-emission scanning electron microscopes shows uniformly shuttle-like crystals with a length of about 15 μm (See Fig.4). The inductively coupled plasma (ICP) analysis performed on an IRIS Intrepid II XSP instrument gives the content (obs./calcd., wt.%) of Ni, 29.87/29.65 and P, 20.42/20.77. The CHN elemental analysis conducted on an Elementar elemental analyzer shows the content (obs./calcd., wt.%) of C, 0.188/0.000; N, 4.812/4.690 and H, 1.997/2.010.
27. 2 [30], which may have a same structure type with DRM-1. The observed and calculated data and residuals of the PXRD of DRM-1 are shown in Fig. 5. A summary of the experimental and crystallographic data, final atomic coordinates, and selected bond distances and angles are given in Tables1-3 respectively.
28. A. Boultif, and D. Louer J. Appl. Cryst. 37 2004 724
29. J. Rodriguez-Carvajal Physica B 192 1993 55
30. P. Lightfoot, A.K. Cheetham, and A.W. Sleight J. Solid State Chem. 85 1990 275
31. A.M. Chippindale, F.O.M. Gaslain, A.D. Bond, and A.V. Powell J. Mater. Chem. 13 2003 1950