The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks

Journal of the American Chemical Society

Volumn 128, Issue 7, 2006, Pages 2204-2205

  Parnham, Emily R ^a   Morris, Russell E ^a  

^a UNIVERSITY OF ST ANDREWS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

1 METHYL 3 ETHYLIMIDAZOLIUM BORMIDE; ALUMINUM DERIVATIVE; COBALT; IMIDAZOLE DERIVATIVE; PHOSPHATE; SOLVENT; TRANSITION ELEMENT; UNCLASSIFIED DRUG; ZEOLITE;

ADSORPTION; ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; OXIDATION REDUCTION REACTION; SYNTHESIS; TEMPERATURE;

EID: 33644550927     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja057933l     Document Type: Article

References (15)

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5. (b) Wheatley, P. S.; Butler, A. R.; Crane, M. S.; Fox, S.; Xiao, B.; Rossi, A. G.; Megson, I. L.; Morris, R. E. J. Am. Chem. Soc 2006, 128, 502.
6. (a) Cooper, E. R.; Andrews, C. D.; Wheatley, P. S.; Webb, P. B.; Wormald P.; Morris, R. E. Nature, 2004, 430, 1012.
7. (b) Parnham, E. R.; Wheatley, P. S.; Morris, R. E. Chem. Commun. 2006, 380.
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9. (b) Bu, X. H.; Feng, P. Y.; Stucky, G. D. Science 1997, 278, 2080.
10. (a) Barrett P. A.; Sankar, G.; Catlow, C. R. A.; Thomas, J. M. J. Phys. Chem. 1996, 100, 8977.
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12. 2O were 1:2.9:0.69:40:1.6:3.6. The stainless steel autoclave was heated to 170 °C for 3 days. After cooling to room temperature the product was suspended in distilled water, sonicated, filtered, and washed with acetone. The product was a blue solid and contained all three phases, SIZ-7, SIZ-8, and SIZ-9 as a physical mixture.
13. 2/c, a = 13.999(2) Å, b = 12.763(2) Å, c = 18.680(2) Å, β = 90.01(1)°; see Marchese, L.; Chen, J. S.; Thomas, J. M.; Coluccia, S.; Zecchina, A. J. Phvs. Chem. 1994, 98, 13350 for structural details.
14. (b) Unit cell data for SIZ-9: Cubic Pm3m, a = 8.9332(6) Å. See ref 5a for structural details.
15. 2 (all data) = 0.200 and S = 1.035. The organic template was disordered and could not be located. The diffuse electron density in the pores was therefore treated using the SQUEEZE routine in the program PLATON.