Hydrolysis study of bis-1,2-(triethoxysilyl)ethane silane by NMR

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 369, Issue 1-3, 2010, Pages 53-56

  Diaz Benito B ^a   Velasco, F ^a   Martinez F J ^a   Encinas, N ^a  

^a UNIVERSIDAD CARLOS III DE MADRID   (Spain)

Author keywords

BTSE silane; Hydrolysis; Nuclear magnetic resonance

Indexed keywords

ETHANE; HYDROLYSIS; METHANOL; RESONANCE;

BTSE SILANE; METHANOL SOLUTION; SILANOLS; TRIETHOXYSILYL;

NUCLEAR MAGNETIC RESONANCE;

BIS 1,2 (TRIETHOXYSILYL)ETHANE SILANE; METHANOL; SILANE; SILANOL; UNCLASSIFIED DRUG; WATER;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; HYDROLYSIS; NUCLEAR MAGNETIC RESONANCE; PH; PRIORITY JOURNAL;

EID: 77956885519     PISSN: 09277757     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2010.07.036     Document Type: Article

References (30)

1. Plueddemann E.P. Silane Coupling Agents 1982, Plenum Press, New York.
2. Franquet A., Biesemans M., Willem R., Terryn H., Vereecken J. Multinuclear 1D- and 2D-NMR study of the hydrolysis and condensation of bis-1,2-(triethoxysilyl)ethane. J. Adhes. Sci. Technol. 2004, 18:765-778.
3. Franquet A., Biesemans M., Terryn H., Willem R., Vereecken J. Study of the interaction of hydrolysed silane solutions with pre-treated aluminium substrates. Surf. Interface Anal. 2006, 38:172-175.
4. Arkles B., Steinmetz J.R., Zazyczny J., Mehta P. Factors contributing to the stability of alkoxysilanes in aqueous solution. J. Adhes. Sci. Technol. 1992, 6:193-206.
5. Pantoja M., Díaz-Benito B., Velasco F., Abenojar J., del Real J.C. Analysis of hydrolysis process of γ-methacryloxypropyltrimethoxysilane and its influence on the formation of silane coatings on 6063 aluminum alloy. Appl. Surf. Sci. 2009, 255:6386-6390.
6. Child F.T., van Ooij W.J. Protecting metals with silanes coupling agents. Chemtech 1998, 28:26-35.
7. Brochier-Salon M.C., Belgacem M.N. Competition between hydrolysis and condensation reactions of trialkoxysilanes, as a function of the amount of water and the nature of the organic group. Colloids Surf. A 2010, 366:147-154.
8. Brochier-Salon M.C., Bayle P.A., Abdelmouleh M., Boufi S., Belgacem M.N. Kinetics of hydrolysis and self condensation reactions of silanes by NMR spectroscopy. Colloids Surf. A 2008, 312:83-91.
9. Frignani A., Zucchi F., Trabanelli G., Grassi V. Protective action towards aluminium corrosion by silanes with a long aliphatic chain. Corros. Sci. 2006, 48:2258-2273.
10. Kuo K.-H., Chiu W.-Y., Hsieh K.-H. Synthesis of UV-curable silane-coupling agent as an adhesion promoter. Mater. Chem. Phys. 2009, 113:941-945.
11. Beccaria A.M., Chiaruttini L. The inhibitive action of metacryloxypropylmethoxysilane (MAOS) on aluminium corrosion in NaCl solutions. Corros. Sci. 1999, 41:885-899.
12. Kono M., Sun X., Li R., Wong K.C., Mitchell K.A.R. Characterization of aluminum surfaces after different pre-treatments and exposure to silane coupling agents. Surf. Rev. Lett. 2001, 8:43.
13. Franquet A., Terryn H., Vereecken J. Study of the effect of different aluminium surface pretreatments on the deposition of thin non-functional silane coatings. Surf. Interface Anal. 2004, 36:681-684.
14. Franquet A., Le Pen C., Terryn H., Vereecken J. Effect of bath concentration and curing time on the structure of non-functional thin organosilane layers on aluminium. Electrochim. Acta 2003, 48:1245-1255.
15. Pu Z., van Ooij W.J., Mark J.E. Hydrolysis kinetics and stability of bis(triethoxysilyl)ethane in the water-system by FTIR spectroscopy. J. Adhes. Sci. Technol. 1997, 11:29-47.
16. Matinlinna J.P., Lassila L.V.J., Özcan M., Yli-Urpo A., Vallittu P.K. An introduction to silanes and their clinical applications in dentistry. Int. J. Prosthodont. 2004, 17:155-164.
17. Matinlinna J.P., Özcan M., Lassila L.V.J., Kalk W., Vallittu P.K. Effect of the cross-linking silane concentration in a novel silane system on bonding resin-composite cement. Acta Odontol. Scand. 2008, 66:250-255.
18. De Graeve I., Tourwé E., Biesemans M., Willem R., Terryn H. Silane solution stability and film morphology of water-based bis-1,2-(triethoxysilyl)ethane for thin-film deposition on aluminium. Prog. Org. Coat. 2008, 63:38-42.
19. Bertelsen C.M., Boerio F.J. Linking mechanical properties of silanes to their chemical structure: an analytical study of γ-GPS solutions and films. Prog. Org. Coat. 2001, 41:239-246.
20. Brochier-Salon M.C., Abdelmouleh M., Boufi S., Belgacem M.N., Gandini A. Silane adsorption onto cellulose fibers: hydrolysis and condensation reactions. J. Colloid Interface Sci. 2005, 289:249-261.
21. Brochier M.C., Gerbaud G., Abdelmouleh M., Bruzzese C., Boufi S., Belgacem M.N. Studies of interactions between silane coupling agents and cellulose fibers with liquid and solid-state NMR. Magn. Reson. Chem. 2007, 45:473-483.
22. Wu K.H., Chao C.M., Yeh T.F., Chang T.C. Thermal stability and corrosion resistance of polysiloxane coatings on 2024-T3 and 6061-T6 aluminum alloy. Surf. Coat. Technol. 2007, 201:5782-5788.
23. 29Si NMR. Silicon Chem. 2008, 3:335-350.
24. Sheen Y.-C., Chang W.-H., Chen W.-C., Chang Y.-H., Huang Y.-C., Chang F.-C. Non-fluorinated superamphiphobic surfaces through sol-gel processing of methyltriethoxysilane and tetraethoxysilane. Mater. Chem. Phys. 2009, 114:63-68.
25. Metroke T., Wang Y., van Ooij W.J., Schaefer D.W. Chemistry of mixtures of bis-[trimethoxysilylpropyl]amine and vinyltriacetoxysilane: an NMR analysis. J. Sol-Gel Sci. Technol. 2009, 51:23-31.
26. Gandhi J., Metroke T.L., Eastman M.A., van Ooij W.J., Apblatt A. Effect of the degree of hydrolysis and condensation of bis-[triethoxysilylpropyl]tetrasulfide on the corrosion protection of coated aluminum alloy 2024-T3. Corrosion 2006, 62:612-623.
27. Del Real J.C., Cano de Santayana M., Abenojar J., Martinez M.A. Adhesive bonding of aluminium with structural acrylic adhesives: durability in wet environments. J. Adhes. Sci. Technol. 2006, 20:1801-1818.
28. 29Si NMR study of the hydrolysis and condensation reactions of tetraethoxysilane. Appl. Magn. Reson. 2000, 18:187-197.
29. Cui Y., Wang M., Chen L., Qian G. Synthesis and spectroscopic characterization of an alkoxysilane dye containing C. I. Disperse Red 1. Dyes Pigments 2004, 62:43-47.
30. 1H NMR study of the hydrolysis of vinyltrialkoxysilanes. Mater. Chem. Phys 2000, 64:45-53.