Metal-rich copper chalcogenide clusters at the border between molecule and bulk phase: The structures of [Cu93Se42(SeC 6H4SMe)9(PPh3)18], [Cu96Se45(SeC6H4SMe) 6(PPh3)18]

Angewandte Chemie - International Edition

Volumn 49, Issue 38, 2010, Pages 6899-6903

  Fu, Ming Lai ^a,b   Issac, Ibrahim ^a,b   Fenske, Dieter ^a,b   Fuhr, Olaf ^a,b  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

Chalcogenides; Cluster compounds; Coppercrystal structure analysis

Indexed keywords

BULK PHASE; CLUSTER COMPOUNDS; CUBIC PHASE; LIGAND-STABILIZED; STRUCTURAL FEATURE; STRUCTURE ANALYSIS; TITLE COMPOUNDS;

CHALCOGENIDES; SINGLE CRYSTALS; X RAY DIFFRACTION;

PHASE CHANGE MEMORY;

EID: 77956864536     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201001301     Document Type: Article

References (30)

1. J. F. Corrigan, O. Fuhr, D. Fenske, Adv. Mater. 2009, 27, 18671871.
2. D. Cave, J. F. Corrigan, A. Eichhöfer, D. Fenske, C. M. Kowalchuk, H. Rösner, P. Scheer, Z Cluster Sci 2007, 18, 157172.
3. S. Dehnen, A. Eichhöfer, D. Fenske, Eur. J. Inorg. Chem. 2002, 279-317, and articles cited therein.
4. S. Dehnen, D. Fenske, Chem. Eur. J. 1996, 2, 1407-1416.
5. D. Fenske, H. Krautscheid, Angew. Chem. 1990, 702, 1513 -1516;
6. Angew. Chem. Int Ed. Engl. 1990, 29, 1452-1454.
7. H. Krautscheid, Ph.D. Thesis, University of Karlsruhe, 1991.
8. N. Zhu, D. Fenske, Z Chem Soc. Dalton Trans 1999, 1067-1075.
9. D. Fenske, C. E. Anson, A. Eichhöfer, O. Fuhr, A. Ingendoh, C. Persau, C. Richert, Angew. Chem 2005, 777, 5376-5381;
10. Angew. Chem. Int. Ed. 2005, 44, 5242-5246.
11. C. E. Anson, A, Eichhöfer, I. Issac, D. Fenske, O. Fuhr, C. Persau, P. Sevillano, D. Stalke, J. Zhang, Angew. Chem. 2008, 720, 1346-1351;
12. Angew. Chem. InL Ed. 2008, 47, 1326-1331.
13. CCDC 766207, CCDC 766208, and CCDC 766209 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif. Structural and refinement data can be found in the Supporting Information. Powder diffraction patterns taken from crystals of 1-3 suspended in their mother solution are in good agreement with the corresponding patterns calculated from the singlecrystal data (Supporting Information, Figures S1-S3).
14. 3, ca. 17 additional toluene molecules.
15. A. L. Spek, Z Appl. Crystallogr. 2003, 36, 7-13;
16. P. van der Sluis, A. L. Spek, Acta Crystallogr. Sect. A 1990, 46, 194-201.
17. 3.)
18. K. Yamamoto, S. Kashida, Solid State Ionics 1991, 48, 241-248.
19. Physics of Superionic Conductors (Ed.: M. R Salamon), Zinate, Riga, 1982.
20. N. N. Hikkulova, & A. Danfllrin, H. Fuess, E. L. Yadrovskii, A. I. Reskrovnyi, A. N. Skomorokohov, Z. A. Yagafarova, G. N. Asylguzhina, Crystallogr. Rep. 2003, 48, 370-373.
21. A. N. Skomorokohov, D. M. Trote, M. Knapp, N. N. Bikkulova, H. Fuess, Z Alloys Compd. 2006, 421, 64-71.
22. 3.)
23. W. Borchert, Z. Kristallogr. 1945, 106, 5-24.
24. A. Tonejc, Z. Ogorelec, B Mestnik. J Appl Crystallogr. 1975, 8, 375-379.
25. P. Rahlfs, Z. Phys Chem. 1979, 150, 299-320.
26. H. T. Evans, Jr., Z. Kristallogr. 1979, 150, 299-320.
27. P. Lukashev, W. R. Lambrecht, Phys Rev. B 2007, 76, 195202.
28. L. D. Partain, P. S. McLeod, J. A, Duisman, T. M. Peterson, D. E. Sawyer, C S. Dean, Z AppL Phys 1983, 54, 6708-6720.
29. Semiconductors: data handbook, 3rded. (Ed.: O. Madelung), Springer, Rerun, 2004.
30. L. Reijnen, B. Meester, A. Goossens, J. Schoonman, Mater. Sci. Eng. C 2002, 19, 311-314.