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1
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a) D. Fenske, H. Krautscheid, S. Balter, Angew. Chem. 1990, 102, 799-801;
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Angew. Chem.
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Fenske, D.1
Krautscheid, H.2
Balter, S.3
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5
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0000725860
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H. Krautscheid, D. Fenske, G. Baum, M. Semmelmann, ibid. 1993, 105, 1364-1367
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Angew. Chem. Int. Ed. Engl.
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Krautscheid, H.1
Fenske, D.2
Baum, G.3
Semmelmann, M.4
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9
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0001301125
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S. Dehnen, A. Schäfer, D. Fenske, R. Ahlrichs, Angew. Chem. 1994, 106, 786-790;
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Angew. Chem.
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Dehnen, S.1
Schäfer, A.2
Fenske, D.3
Ahlrichs, R.4
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14
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0002887099
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A. Scḧfer, C. Huber, J. Gauss, R. Ahlrichs. Theor. Chim. Acta 1993, 87, 29.
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Theor. Chim. Acta
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Scḧfer, A.1
Huber, C.2
Gauss, J.3
Ahlrichs, R.4
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15
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0000443938
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D. van der Putten, D. Olevano, R. Zanoni, H. Krautscheid, D. Fenske, J. Electron Spectrosc. Relat. Phenom. 1995, 76, 207-211.
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J. Electron Spectrosc. Relat. Phenom.
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Van Der Putten, D.1
Olevano, D.2
Zanoni, R.3
Krautscheid, H.4
Fenske, D.5
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16
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84891319762
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note
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max = 38°; 21933 reflections, 9239 independent reflections, 8248 with I>2σ(I), 643 parameters (Se, Cu, P anisotropically refined; some of the C atoms of the phosphine ligands are disordered, therefore the coordinates were refined isotropically); the positions of the C atoms have been calculated; R = 0.078. Further details of the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen (Germany), on quoting the depository numbers CSD-404875, -404876, -404877, -404878, -404879 and -404880.
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19
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27744445874
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S. Dehnen, A. Schäfer, R. Ahlrichs, D. Fenske, Chem. Eur. J. 1996, 2, 429-435.
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(1996)
Chem. Eur. J.
, vol.2
, pp. 429-435
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Dehnen, S.1
Schäfer, A.2
Ahlrichs, R.3
Fenske, D.4
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20
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84891297326
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note
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The relation between the cluster size and the value of the corresponding HOMO-LUMO gap has been investigated theoretically in several systems, e.g. Mg clusters [11]. With increasing cluster size the HOMO-LUMO gap decreases. However, the value for the gap does not have to follow a strictly linear course.
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23
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0003395029
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Landoldt-Börnstein, Springer, Berlin
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Landoldt-Börnstein, Numerical Data and Functional Relationships in Science and Technology, New Series. Group III. Vol. 17e (Ed.: K.-H. Hellwege), Springer, Berlin, 1983.
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(1983)
Numerical Data and Functional Relationships in Science and Technology, New Series. Group III.
, vol.17 E
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Hellwege, K.-H.1
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24
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0003732720
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5th ed., Clarendon, Oxford
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A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon, Oxford, 1984, 1142.
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(1984)
Structural Inorganic Chemistry
, pp. 1142
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Wells, A.F.1
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27
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84891296785
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note
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3 have similar Tolman angles (161 and 160°) [7] and consist of the same numbers of atoms.
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28
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84891283300
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Dissertation, Karlsruhe
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F. Simon, Dissertation, Karlsruhe, 1995.
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(1995)
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Simon, F.1
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29
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84891289914
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note
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The third potential bond, Cu15-Se1, 311.4 pm, is too long for a covalent bond. Cu15 is, strictly speaking, twofold coordinated with an Se 2-Cu 5-Se5 angle of 138.4°. The sum of the angles around this metal atom, taking the Cu15-Se1, into account is 338.6 (and thus clearly deviates from planarity). Also the Cu18 trigonal environment is no longer planar. The sum of the Se-Cu-Se angles around copper is 338.6°.
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32
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84990673683
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N. Frangis, C. Monolikas, S. Amelinckx, Phys. Stat. Solidi 1991, A126, 9.
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(1991)
Phys. Stat. Solidi
, vol.A126
, pp. 9
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Frangis, N.1
Monolikas, C.2
Amelinckx, S.3
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