The heterogeneous photo-Fenton reaction using goethite as catalyst

Water Science and Technology

Volumn 61, Issue 12, 2010, Pages 3109-3116

  Ortiz De La Plata, Guadalupe B ^a   Alfano, Orlando M ^a   Cassano, Alberto E ^a  

^a UNIVERSIDAD NACIONAL DEL LITORAL   (Argentina)

Author keywords

2 Chlorophenol; Fenton; Goethite; Heterogeneous; Radiation enhancement

Indexed keywords

2-CHLOROPHENOLS; FENTON; GOETHITE; HETEROGENEOUS; RADIATION ENHANCEMENT;

CATALYSTS; DEGRADATION; DISSOLUTION; HEAT RADIATION; HYDROGEN PEROXIDE; LEACHING; METAL RECOVERY; REACTION INTERMEDIATES;

SURFACE REACTIONS;

2 CHLOROPHENOL; FERRIC HYDROXIDE; HYDROGEN PEROXIDE; IRON; 2-CHLOROPHENOL; ACETIC ACID; ACETONITRILE; ACETONITRILE DERIVATIVE; CHLOROPHENOL; FENTON'S REAGENT; IRON DERIVATIVE; METHANOL;

CATALYSIS; CATALYST; CHLOROPHENOL; CONCENTRATION (COMPOSITION); DEGRADATION; DISSOLUTION; GOETHITE; HETEROGENEITY; HIGH TEMPERATURE; HYDROGEN PEROXIDE; IRON;

ARTICLE; CATALYST; CHEMICAL REACTION; DEGRADATION; HETEROGENEOUS PHOTO FENTON REACTION; HIGH TEMPERATURE; LEACHING; RADIATION; BIOREMEDIATION; CATALYSIS; KINETICS; METHODOLOGY; PHOTOCHEMISTRY; SEWAGE; THEORETICAL MODEL;

ACETIC ACID; ACETONITRILES; BIODEGRADATION, ENVIRONMENTAL; CATALYSIS; CHLOROPHENOLS; HYDROGEN PEROXIDE; IRON; IRON COMPOUNDS; KINETICS; METHANOL; MODELS, THEORETICAL; PHOTOCHEMISTRY; WASTE DISPOSAL, FLUID;

EID: 77956628603     PISSN: 02731223     EISSN: None     Source Type: Journal    
DOI: 10.2166/wst.2010.258     Document Type: Article

References (41)

1. Alfano, O. M., Cabrera, M. I. & Cassano, A. E. 1997 Photocatalytic reactions involving hydroxyl radical attack: I. Reaction kinetics formulation with explicit photon absorption effects. J. Catal. 172(2), 370-379.
2. Allen, A. O., Hochanadel, C. J., Ghormley, J. A. & Davis, T. W. 1952 Decomposition of water and aqueous solutions under mixed fast neutron and gamma radiation. J. Phys. Chem. 56(5), 575-586.
3. Bergendahl, J. A. & Thies, T. P. 2004 Fenton's oxidation of MTBE with zero-valent iron. Water Res. 38(2), 327-334.
4. Bozzi, A., Yuranova, T., Mielczarski, J. & Kiwi, J. 2004 Evidence for immobilized photo-Fenton degradation of organic compounds on structured silica surfaces involving Fe recycling. New J. Chem. 28(4), 519-526.
5. Cassano, A. E., Martin, C. A., Brandi, R. J. & Alfano, O. M. 1995 Photoreactor analysis and design: fundamentals and applications. Ind. Eng. Chem. Res. 34(7), 2155-2201.
6. Chen, R. & Pignatello, J. J. 1997 Role of quinone intermediates as electron shuttles in Fenton and photoassisted Fenton oxidations of aromatic compounds. Environ. Sci. Technol. 31(8), 2399-2406.
7. Chou, S., Huang, C. & Huang, Y. H. 2001 Heterogeneous and homogeneous catalytic oxidation by supported α-FeOOH in a fluidized-bed reactor: kinetic approach. Environ. Sci. Technol. 35(6), 1247-1251.
8. 2. Appl. Catal. B Environ. 36(3), 231-237.
9. Devi, L. G., Girish Kumar, S., Mohan Reddy, K. & Munikrishnappa, C. 2009 Photo degradation of methyl orange an azo dye by advanced Fenton process using zero valent metallic iron: Influence of various reaction parameters and its degradation mechanism. J. Hazard. Mater. 164(2-3), 459-467.
10. Duderstadt, J. J. & Martin, R. 1979 Transport Theory. Wiley, New York.
11. Feng, J., Hu, X. & Yue, P. L. 2004 Discoloration and mineralization of orange II using different heterogeneous catalysts containing Fe: a comparative study. Environ. Sci. Technol. 38(21), 5773-5778.
12. Feng, J., Hu, X. & Yue, P. L. 2005 Discoloration and mineralization of orange II by using a bentonite clay-based Fe nanocomposite film as a heterogeneous photo-Fenton catalyst. Water Res. 39(1), 89-96. (Pubitemid 40017759)
13. Feng, J., Hu, X., Yue, P. L. & Qiao, S. 2009 Photo Fenton degradation of high concentration orange II (2mM) using catalysts containing Fe: a comparative study. Sep. Purif. Technol. 67(2), 213-217.
14. Fenton, H. J. H. 1894 Oxidation of tartaric acid in presence of iron. J. Chem. Soc. Trans. 65, 899-911.
15. Fernandez, J., Bandara, J., Lopez, A., Albers, P. & Kiwi, J. 1998 Efficient photo-assisted Fenton catalysis mediated by Fe ions on Nafion membranes active in the abatement of non-biodegradable azo-dye. Chem. Commun. 14, 1493-1494.
16. Fernandez, J., Dhananjeyan, M. R., Kiwi, J., Senuma, Y. & Hilborn, J. 2000 Evidence for Fenton photoassisted processes mediated by encapsulated Fe ions at biocompatible pH values. J. Phys. Chem. B 104(22), 5298-5301.
17. Garrido-Ramirez, E. G., Theng, B. K. G. & Mora, M. L. 2010 Clays and oxide minerals as catalysts and nanocatalysts in Fentonlike reactions-a review. Appl. Clay Sci. 47(3-4), 182-192.
18. Gordon, T. R. & Marsh, A. L. 2009 Temperature dependence of the oxidation of 2-chlorophenol by hydrogen peroxide in the Presence of goethite. Catal. Lett. 132(3-4), 349-354.
19. Gurol, M. D. & Lin, S. S. 2001 Hydrogen peroxide/iron oxide-induced catalytic oxidation of organic compounds. Water Sci. Technol. Water Supply 1(4), 131-138.
20. Huang, C. P. & Huang, Y. H. 2008 Comparison of catalytic decomposition of hydrogen peroxide and catalytic degradation of phenol by immobilized iron oxides. Appl. Catal. A Gen. 346(1-2), 140-148.
21. Huang, H. H., Lu, M. C. & Chen, J. N. 2001 Catalytic decomposition of hydrogen peroxide and 2-chlorophenol with iron oxides. Water Res. 35(9), 2291-2299.
22. Kang, N., Lee, D. S. & Yoon, J. 2002 Kinetic modeling of Fenton oxidation of phenol and monochlorophenols. Chemosphere 47(9), 915-924.
23. Liao, C. H., Kang, S. F. & Hsu, Y. W. 2003 Zero-valent iron reduction of nitrate in the presence of ultraviolet light, organic matter and hydrogen peroxide. Water Res. 37(17), 4109-4118.
24. Lin, S. S. & Gurol, M. D. 1998 Catalytic decomposition of hydrogen peroxide on iron oxide: kinetics, mechanism, and implications. Environ. Sci. Technol. 32(10), 1417-1423.
25. Lin, Y. T. & Lu, M. C. 2007 Catalytic action of goethite in the oxidation of 2-chlorophenols with hydrogen peroxide. Water Sci. Technol. 55(12), 101-106.
26. Lu, M. C., Chen, J. N. & Huang, H. H. 2002 Role of goethite dissolution in the oxidation of 2-chlorophenol with hydrogen peroxide. Chemosphere 46(1), 131-136.
27. Ma, J., Song, W., Chen, C., Cheng, M., Ma, W., Zhao, J. & Tang, Y. 2005 Fenton degradation of organic compounds promoted by dyes under visible irradiation. Environ. Sci. Technol. 39(15), 5810-5815.
28. Martínez, F., Calleja, G., Melero, J. A. & Molina, R. 2007 Iron species incorporated over different silica supports for the heterogeneous photo-Fenton oxidation of phenol. Appl Catal. B Environ. 70(1-4), 452-460.
29. Morgada, M. E., Levy, I. K., Salomone, V., Farías, S. S., López, G. & Litter, M. I. 2009 Arsenic (V) removal with nanoparticulate zerovalent iron: effect of UV light and humic acids. Catal. Today 143(3-4), 261-268.
30. Neamtu, M., Zaharia, C., Catrinescu, C., Yediler, A., Macoveanu, M. & Kettrup, A. 2004 Fe-exchanged Y zeolite as catalyst for wet peroxide oxidation of reactive azo dye Procion Marine H-EXL. Appl. Catal. B Environ. 48(4), 287-294.
31. Ortiz de la Plata, G. B., Alfano, O. M. & Cassano, A. E. 2008 Optical properties of goethite catalyst for heterogeneous photo-Fenton reactions: Comparison with a titanium dioxide catalyst. Chem. Eng. J. 137(2), 396-410.
32. Ortiz de la Plata, G. B., Alfano, O. M. & Cassano, A. E. 2010 Decomposition of 2-chlorophenol employing goethite as Fenton catalyst. I. Proposal of a feasible, combined reaction scheme of heterogeneous and homogeneous reactions. Appl. Catal. B Environ. 95(1-2), 1-13.
33. Ozisik, M. N. 1973 Radiative Transfer and Interactions with Conduction and Convection. J. Wiley, New York.
34. Pawliszyn, J. 1999 Applications of Solid Phase Microextracción. The Royal Society of Chemistry, UK.
35. Pignatello, J. J., Oliveros, E. & MacKay, A. 2006 Advanced oxidation processes for organic contaminant destruction based on the fenton reaction and related chemistry. Crit. Rev. Environ. Sci. Technol. 36(1), 1-84.
36. Son, H. S., Im, J. K. & Zoh, K. D. 2009 A Fenton-like degradation mechanism for 1,4-dioxane using zero-valent iron (Fe0) and UV light. Water Res. 43(5), 1457-1463.
37. Teel, A. L., Dennis, D. F., Jeremy, T. S., Lynn, M. C. & Richard, J. W. 2007 Rates of trace mineral-catalyzed decomposition of hydrogen peroxide. J. Environ. Eng. 133(8), 853-858.
38. Toxicological Profile for Chlorophenols 1999 U.S. Department of Health and Human Services; Public Health Service Agency for Toxic Substances and Disease Registry, U.S. Government printing office: Washington, DC.
39. Yuranova, T., Enea, O., Mielczarski, E., Mielczarski, J., Albers, P. & Kiwi, J. 2004 Fenton immobilized photo-assisted catalysis through a Fe/C structured fabric. Appl. Catal. B Environ. 49(1), 39-50.
40. Standard Methods for the Examination of Water and Wastewater 1995 19th edition, American Public Health Association, Washington, DC.
41. Zheng, Z. W., Lei, L. C., Xu, S. J. & Cen, P. L. 2004 Heterogeneous UV/Fenton catalytic degradation of wastewater containing phenol with Fe-Cu-Mn-Y catalyst. J. Zhejiang Univ. Sci. 5(2), 206-211.