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The term phosphinidenoid is used here to describe a bonding situation at a formal phosphorus(III) center that has a very electropositive (group 1 metal) and an electronegative center (group 17 nonmetal) in a 1,1-position. In consequence, we use here phosphinidenoid-like to describe the N-coordination isomer.
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The term phosphinidenoid is used here to describe a bonding situation at a formal phosphorus(III) center that has a very electropositive (group 1 metal) and an electronegative center (group 17 nonmetal) in a 1,1-position. In consequence, we use here phosphinidenoid-like to describe the N-coordination isomer.
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17
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34547731266
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To the best of our knowledge no structures of η-(1)-1-aza-3- phosphaallene complexes have been described
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To the best of our knowledge no structures of η-(1)-1-aza-3- phosphaallene complexes have been described.
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18
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0039579826
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Yoshifuji, M.1
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Hirotsu, K.5
Odagaki, Y.6
Higuchi, T.7
Nagase, S.8
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19
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33745770836
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All DFT calculations were performed using GAUSSIAN03, Rev. B.02 at B3LYP/6-311**; tungsten was described by LanL2DZ, the ECP by P. J. Hay and W. R. Wadt: J. Chem. Phys. 1985, 82, 270.
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All DFT calculations were performed using GAUSSIAN03, Rev. B.02 at B3LYP/6-311**; tungsten was described by LanL2DZ, the ECP by P. J. Hay and W. R. Wadt: J. Chem. Phys. 1985, 82, 270.
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21
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34547809238
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5 group participates significantly in electron delocalization.
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5 group participates significantly in electron delocalization.
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