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Volumn 114, Issue 36, 2010, Pages 9788-9794

The influence of vibrational excitation on the photoisomerization of trans-stilbene in solution

Author keywords

[No Author keywords available]

Indexed keywords

BARRIER CROSSING; C-H STRETCH VIBRATIONS; ELECTRONIC EXCITATION; EXCITED MOLECULES; EXCITED-STATE LIFETIME; GROUND ELECTRONIC STATE; INFRARED EXCITATION; INITIAL STATE; ONE-PHOTON EXCITATION; STRETCH-BEND COMBINATION; TRANS-STILBENE; TWO-PHOTON EXCITATIONS; ULTRAVIOLET PHOTON; VIBRATIONAL ENERGIES; VIBRATIONAL ENERGY FLOW; VIBRATIONAL EXCITATION; VIBRATIONAL RELAXATION; VIBRATIONAL STATE; VIBRATIONALLY EXCITED;

EID: 77956532055     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp102752f     Document Type: Article
Times cited : (22)

References (53)
  • 36
    • 77956523419 scopus 로고    scopus 로고
    • note
    • In both cases, there is a rapid rise and fall in the signal followed by a slower decay. Because of a large coherence signal in the earlier measurements, the analysis of those experiments did not include the early signal. Instead, it used a 1 ps rise and fit the evolution at times longer than 2 ps to obtain a 1 ps decay followed by a 10 ps decay. In the present experiment, we observe both the rise and the fall without complications from a coherence signal. However, the long-time decay is barely observable in our more dilute solutions, and the decay rate we obtain from the single exponential fit is about twice as fast as determined in the previous measurement.
  • 38
    • 77956504309 scopus 로고    scopus 로고
    • note
    • The variation among data sets dominates the reported uncertainty. The uncertainty within any one data set is much smaller.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.