New dual initiators to combine quasiliving carbocationic polymerization and atom transfer radical polymerization

Macromolecules

Volumn 43, Issue 17, 2010, Pages 7048-7055

  Zhu, Yaling ^a   Storey, Robson F ^a  

^a University of Southern Mississippi   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BLOCK LENGTHS; CARBOCATIONIC POLYMERIZATION; DIBLOCK COPOLYMER; DOUBLE BONDS; DUAL INITIATOR; HEAD GROUPS; HYDROBORATION-OXIDATION; HYDROXYL GROUPS; INITIATION EFFICIENCY; LOW TEMPERATURES; METHYL ACRYLATES; RADICAL INITIATIONS; TRIMETHYL;

ACRYLIC MONOMERS; BLOCK COPOLYMERS; BROMINE COMPOUNDS; BUTENES; FREE RADICAL REACTIONS; POLYDISPERSITY; POLYMERIZATION; POLYMERS; SYNTHESIS (CHEMICAL);

ATOM TRANSFER RADICAL POLYMERIZATION;

EID: 77956411282     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma1011655     Document Type: Article

References (36)

1. Kaszas, G.; Puskas, J. E.; Kennedy, J. P.; Hager, W. G. J. Polym. Sci., Part A: Polym. Chem. Ed. 1991, 29, 421-426
2. Kaszas, G.; Puskas, J. E.; Kennedy, J. P.; Hager, W. G. J. Polym. Sci., Polym. Chem. Ed. 1991, 29, 427-435
3. Tsunogae, Y.; Kennedy, J. P. J. Polym. Sci., Part A: Polym. Chem. Ed. 1994, 32, 403-412
4. Li, D.; Faust, R. Macromolecules 1995, 28, 1383-1389
5. Kwon, Y.; Cao, X.; Faust, R. Macromolecules 1999, 32, 6963-6968
6. Puskas, J. E.; Kaszas, G.; Kennedy, J. P.; Hager, W. G. J. Polym. Sci., Part A: Polym. Chem. Ed. 1992, 30, 41-48
7. Fodor, Z.; Faust, R. J. Macromol. Sci., Part A: Pure Appl. Chem. 1994, A31, 1985-2000
8. Kennedy, J. P.; Kurian, J. J. Polym. Sci., Part A: Polym. Chem. 1990, 3725-3738
9. Hadjikyriacou, S.; Faust, R. Macromolecules 1996, 29, 5261-5267
10. Matyjaszewski, K. Macromol. Symp. 1998, 132, 85-101
11. Zheng, F.; Kennedy, J. P. J. Polym. Sci., Part A: Polym. Chem. 2002, 40, 3662-3678
12. Storey, R. F.; Scheuer, A. D.; Achord, B. C. Polymer 2005, 46, 2141-2152
13. Storey, R. F.; Scheuer, A. D.; Achord, B. C. J. Macromol. Sci., Part A: Pure Appl. Chem. 2006, 43, 1493-1512
14. Coca, S.; Matyjaszewski, K. Macromolecules 1997, 30, 2808-2810
15. Jakubowski, W.; Tsarevsky, N. V.; Higashihara, T.; Faust, R.; Matyjaszewski, K. Macromolecules 2008, 41, 2318-2323
16. Magenau, A. J. D.; Martinez-Castro, N.; Savin, D. A.; Storey, R. F. Macromolecules 2009, 42, 2353-2359
17. Magenau, A. J. D.; Martinez-Castro, N.; Storey, R. F. Macromolecules 2009, 42, 8044-8051
18. Feng, D.; Chandekar, A.; Whitten, J. E.; Faust, R. ACS Div. Polym. Chem., Polym. Prepr. 2007, 48 (2) 1017-1018
19. Martinez-Castro, N.; Zhang, M.; Pergushov, D. V.; Mueller, A. H. E. Des. Monomers Polym. 2006, 9, 63-79
20. Martinez-Castro, N.; Lanzendoerfer, M. G.; Mueller, A. H. E.; Cho, J. C.; Acar, M. H.; Faust, R. Macromolecules 2003, 36, 6985-6994
21. Kwon, Y.; Faust, R. J. Macromol. Sci., Part A: Pure Appl. Chem. 2005, A42, 385-401
22. Kwon, Y.; Faust, R.; Chen, C. X.; Thomas, E. L. Macromolecules 2002, 35, 3348-3357
23. Bernaerts, K. V.; Du Prez, F. E. Polymer 2005, 46, 8469-8482
24. Bernaerts, K. V.; Schacht, E. H.; Goethals, E. J.; Du Prez, F. E. J. Polym. Sci., Part A: Polym. Chem. 2003, 41, 3206-3217
25. Bernaerts, K. V.; Willet, N.; Van Camp, W.; Jérôme, R.; Du Prez, F. E. Macromolecules 2006, 39, 3760-3769
26. Becer, C. R.; Paulus, R. M.; Hoppener, S.; Hoogenboom, R.; Fustin, C.-A.; Gohy, J.-F.; Schubert, U. S. Macromolecules 2008, 41, 5210-5215
27. Breland, L. K.; Murphy, J. C.; Storey, R. F. Polymer 2006, 47, 1852-1860
28. Chance, R. R.; Baniukiewicz, S. P.; Mintz, D.; Ver Strate, G.; Hadjichristidis, N. Int. J. Polym. Anal. Charact. 1995, 1 (1) 3-34
29. Storey, R. F.; Donnalley, A. B.; Maggio, T. L. Macromolecules 1998, 31, 1523-1526
30. Iovu, M. C.; Jeffries-EL, M.; Sheina, E. E.; Cooper, J. R.; McCullough, R. D. Polymer 2005, 46, 8582-8586
31. Simison, K. L.; Stokes, C. D.; Harrison, J. J.; Storey, R. F. Macromolecules 2006, 39, 2481-2487
32. 4- coinitiated isobutylene polymerizations at higher temperatures such as those reported here, e.g.,-50 °C. These structures result from unimolecular proton transfer to the paired counterion. This process does not cause loss of control over molecular weight, nor does it create any chains without the desired ATRP initiating sites because the eliminated proton cannot initiate a new chain in the presence of proton traps and/or strong bases such as 2,6-lutidine. These concepts are discussed in detail in the following paper: Fodor, Zs.; Bae, Y. C.; Faust, R. Macromolecules 1998, 31, 4439-4446
33. Balogh, L.; Takacs, A.; Faust, R. ACS Div. Polym. Chem., Polym. Prepr. 1992, 33 (1) 958-959
34. Storey, R. F.; Choate, K. R., Jr. Macromolecules 1997, 30, 4799-4806
35. Smith, Q. A.; Storey, R. F. Macromolecules 2005, 38, 4983-4988
36. Brar, A. S.; Goyal, A. K.; Hooda, S. J. Mol. Struct. 2008, 885, 15-17