Temperature effects on the living cationic polymerization of isobutylene: Determination of spontaneous chain-transfer constants in the presence of terminative chain transfer

Macromolecules

Volumn 31, Issue 14, 1998, Pages 4439-4446

  Fodor, Zsolt ^a,b   Bae, Young Cheol ^a   Faust, Rudolf ^a  

^a University of Massachusetts Lowell   (United States)

^b Teknor Apex Company   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CALCULATIONS; MIXTURES; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLVENTS; STRUCTURE (COMPOSITION); THERMAL EFFECTS;

ARRHENIUS PLOT; CHAIN TRANSFER CONSTANT; ISOBUTYLENE; KINETIC TREATMENT; LIVING CATIONIC POLYMERIZATION; OLEFINIC END GROUP; TERMINATIVE CHAIN TRANSFER;

CATIONIC POLYMERIZATION;

EID: 0032120504     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma980193z     Document Type: Article

References (21)

1. Kresge, E. N.; Schatz, R. H.; Wang, H.-C. In Encyclopedia of Polymer Science and Engineering, 2nd ed.; Mark, H. F., Bikales, N. M., Overberger, C. C., Menges, G., Eds.; Wiley-Interscience: New York, 1987; Vol. 8, p 423.
2. Vairon, J.-P.; Spassky, N. In Cationic Polymerization. Mechanism, Synthesis, and Applications; Matyjaszewski, K., Ed.; Marcel Dekker: New York, 1996; Chapter 8.
3. Gyor, M.; Wang, H.-C.; Faust, R. J. Macromol. Sci., Pure Appl. Chem. 1992, A29 (8), 639.
4. Kaszas, G.; Puskas, J. E.; Chen, C. C. Polym. Bull. 1988, 20, 413; Macromolecules 1990, 23, 3909.
5. Kaszas, G.; Puskas, J. E.; Chen, C. C. Polym. Bull. 1988, 20, 413; Macromolecules 1990, 23, 3909.
6. Bae, Y. C.; Faust, R. Macromolecules 1997, 30, 7341; Mac romol. Symp., in press.
7. Bae, Y. C.; Faust, R. Macromolecules 1997, 30, 7341; Mac romol. Symp., in press.
8. Kennedy, J. P.; Majoras, I.; Nagy, A. Adv. Polym. Sci. 1994, 112, 1.
9. Storey, R. F.; Chisholm, B. J.; Brister, L. B. Macromolecules 1995, 28, 4055.
10. Storey, R. F.; Choate, K. R., Jr. Macromolecules 1997, 30, 4799.
11. Storey, R. F.; Choate, K. R., Jr. J. Macromol. Sci., Pure Appl. Chem. 1997, A34 (7), 1195.
12. Sigwalt, P. Macormol. Symp., in press.
13. Fodor, Zs.; Faust, R. J. Macromol. Sci., Pure Appl. Chem. 1998, A35 (2), 375.
14. Penczek, S.; Kubisa, P.; Szymanski, R. Makromol. Chem., Rapid Commun. 1991, 12, 77.
15. Kennedy, J. P.; Marechal, E. Carbocationic Polymerization; Wiley: New York, 1982.
16. Kennedy, J. P.; Ivan, B. Designed Polymers by Carbocationic Macromolecular Engineering; Hanser: Munich, Germany 1991.
17. Pari, B.; Tardi, M.; Polton, A.; Sigwalt, P. Eur. Polym. J. 1985, 21, 393.
18. Taxi, M.; Tardi, M.; Polton, A.; Sigwalt, P. Br. Polym. J. 1987, 19, 369.
19. Sigwalt, P. Makromol. Chem., Macromol. Symp.1991, 47, 179.
20. Kennedy, J. P.; Huang, S. Y.; Feinberg, S. C. J. Polym. Sci. 1977, 15, 2801.
21. Matyjaszewski, K.; Pugh, C. In Cationic Polymerization. Mechanism, Synthesis, and Applications; Matyjaszewski, K., Ed.; Marcel Dekker: New York, 1996; Chapter 3.