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note
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R=19.6 min for (-)-isomer.
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56
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note
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Asymmetric dihydroxylation of trans-3-pentenenitrile provided a 3,4-dihydroxypentanenitrile, which showed 80% ee in a HPLC-based analysis of the corresponding benzoate.
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57
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77956394775
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note
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Kinetic hydrolysis of the racemic acetate (±-18) with Novozyme in 0.2 M Na-phosphate buffer did not give satisfactory results in terms of yield and enantiomeric excess.
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