Flower micelle of amphiphilic random copolymers in aqueous media

Journal of Physical Chemistry B

Volumn 114, Issue 35, 2010, Pages 11403-11408

  Tominaga, Yukio ^a   Mizuse, Mari ^b   Hashidzume, Akihito ^b   Morishima, Yotaro ^c   Sato, Takahiro ^b  

^a DAINIPPON SUMITOMO PHARMA CO LTD   (Japan)

^b OSAKA UNIVERSITY   (Japan)

^c UNIVERSITY OF FUKUI   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTER SIMULATION; COPOLYMERIZATION; LIGHT SCATTERING; MICELLES; MOLECULAR DYNAMICS; REFRACTION; SODIUM; SODIUM CHLORIDE;

AMPHIPHILICS; AQUEOUS MEDIA; ATOMISTIC MOLECULAR DYNAMICS SIMULATIONS; CENTER OF MASS; DEGREE OF POLYMERIZATION; DENSITY DISTRIBUTION FUNCTIONS; DODECYL GROUPS; HOMOPOLYMERS; HYDRODYNAMIC RADIUS; LOOP SIZE; MAIN CHAINS; MICELLAR STRUCTURES; RADIAL DISTANCE; RADIUS OF GYRATION; RANDOM COPOLYMER; SIMULATION TIME; STRUCTURAL FEATURE; SULFONATE GROUPS;

DISTRIBUTION FUNCTIONS;

EID: 77956329439     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp104711q     Document Type: Article

References (53)

1. For example
2. McCormick, C. L.; Bock, J.; Schulz, D. N. In Encyclopedia of Polymer Science and Engineering; Kroschwitz, J. I., Ed.; Wiley & Sons: New York, 1989; Vol. 17, pp 730 - 784.
3. Varadaraj, R.; Branham, K. D.; McCormick, C. L.; Bock, J. In Macromolecular Complexes in Chemistry and Biology; Dubin, P., Bock, J., Davies, R. M., Schulz, D. N., Thies, C., Eds.; Springer-Verlag: Berlin, 1994; pp 15 - 31.
4. For example
5. Polymers in Aqueous Media; Glass, J. E., Ed.; Advances in Chemistry Series 223; American Chemical Society: Washington, DC, 1989.
6. Hydrophilic Polymers. Performance with Environmental Acceptability; Glass, J. E., Ed.; Advances in Chemistry Series 248; American Chemical Society: Washington, DC, 1996.
7. Associative Polymers in Aqueous Solutions; Glass, J. E., Ed.; ACS Symposium Series 765; American Chemical Society: Washington, DC, 2000.
8. For example
9. Qin, A.; Tian, M.; Ramireddy, C.; Webber, S. E.; Munk, P.; Tuzar, Z. Macromolecules 1994, 27, 120-126
10. Chu, B. Langmuir 1995, 11, 414-421
11. Förster, S.; Zisenis, M.; Wenz, E.; Antonietti, M. J. Chem. Phys. 1996, 104, 9956-9970
12. Moffitt, M.; Khougaz, K.; Eisenberg, A. Acc. Chem. Res. 1996, 29, 95-102
13. Förster, S.; Antonietti, M. Adv. Mater. (Weinheim, Ger.) 1998, 10, 195-217
14. Förster, S.; Abetz, V.; Müller, A. H. E. Adv. Polym. Sci. 2004, 166, 173-210
15. Hashidzume, A.; Morishima, Y.; Szczubialka, K. In Handbook of Polyelectrolytes and Their Applications; Tripathy, S. K.; Kumar, J.; Nalwa, H. S., Eds.; American Scientific Publishers: Stevenson Ranch, CA, 2002; Vol. 2, pp 1 - 63.
16. Yamamoto, H.; Mizusaki, M.; Yoda, K.; Morishima, Y. Macromolecules 1998, 31, 3588-3594
17. Yamamoto, H.; Morishima, Y. Macromolecules 1999, 32, 7469-7475
18. Yamamoto, H.; Tomatsu, I.; Hashidzume, A.; Morishima, Y. Macromolecules 2000, 33, 7852-7861
19. Yamamoto, H.; Hashidzume, A.; Morishima, Y. Polym. J. (Tokyo, Jpn.) 2000, 32, 745-752
20. Halperin, A. Macromolecules 1991, 24, 1418-1419
21. Borisov, O. V.; Halperin, A. Langmuir 1995, 11, 2911-2919
22. Borisov, O. V.; Halperin, A. Macromolecules 1996, 29, 2612-2617
23. Urakami, N.; Takasu, M. J. Phys. Soc. Jpn. 1996, 65, 2694-2699
24. Urakami, N.; Takasu, M. Prog. Theor. Phys. Suppl. 1997, 126, 329-332
25. Halperin, A. In Supramolecular Polymers; Ciferri, A., Ed.; Marcel Dekker: New York, 2000; pp 93 - 146.
26. Zhang, G.; Winnik, F. M.; Wu, C. Phys. Rev. Lett. 2003, 90 035506/035501-035506/035504
27. Kawata, T.; Hashidzume, A.; Sato, T. Macromolecules 2007, 40, 1174-1180
28. Yamakawa, H. Modern Theory of Polymer Solutions; Harper & Row: New York, 1971; Chapter II.
29. Yamakawa, H. Helical Wormlike Chains in Polymer Solutions; Springer-Verlag: Berlin, 1997.
30. Yamakawa, H.; Stockmayer, W. H. J. Chem. Phys. 1972, 57, 2843-2854
31. Yamakawa, H. Modern Theory of Polymer Solutions: Harper & Row: New York, 1971; Chapter V.
32. Yashiro, J.; Hagino, R.; Sato, S.; Norisuye, T. Polym. J. (Tokyo, Jpn.) 2006, 38, 57-63
33. According to the Manning theory (32) of polyelectrolytes, the ion condensation occurs at l /(1 - x) < 0.714 nm (the Bjerrum length) or at x (the content of C12) < 0.65 for AMPS/C12, so that the effective charge density of AMPS/C12 with x = 0.5 can be identified with that for the AMPS homopolymer with x = 0. Furthermore, side-chain dodecyl groups affect the excluded volume effect (the long range interaction) but not the local chain stiffness in a first approximation. Therefore, we may approximate q of AMPS/C12 with x = 0.5 to that of the AMPS homopolymer.
34. Israelachvili, J. N. Intermolecular and Surface Forces, 2nd ed., Acedemic Press: London, 1992; Chapter 17.
35. Although Kawata et al. (16) originally assumed that λ would be proportional to x, we here take this parameter to be constant.
36. Shelley, J.; Watanabe, K.; Klein, M. L. Int. J. Quantum Chem., Quantum Biol. Symp. 1990, 17, 103-117
37. MacKerell, A. D., Jr. J. Phys. Chem. 1995, 99, 1846-1855
38. Bruce, D.; Berkowitz, M. L.; Perera, L.; Forbes, M. D. E. J. Phys. Chem. B 2002, 106, 3788-3793
39. Bruce, D.; Senapati, S.; Berkowitz, M. L.; Perera, L.; Forbes, M. D. E. J. Phys. Chem. B 2002, 106, 10902-10907
40. Gao, J.; Ge, W.; Hu, G.; Li, J. Langmuir 2005, 21, 5223-5229
41. Yoshii, N.; Okazaki, S. Chem. Phys. Lett. 2006, 425, 58-61
42. Khalatur, P. G.; Khokhlov, A. R. Adv. Polym. Sci. 2006, 195, 1-100
43. Okhapkin, I. M.; Makhaeva, E. E.; Khokhlov, A. R. Adv. Polym. Sci. 2006, 195, 177-210
44. Khokhlov, A. R.; Khalatur, P. G. Physica A 1998, 249, 253-261
45. Vasilevskaya, V. V.; Khalatur, P. G.; Khokhlov, A. R. Macromolecules 2003, 36, 10103-10111
46. Berezkin, A. V.; Khalatur, P. G.; Khokhlov, A. R. J. Chem. Phys. 2003, 118, 8049-8060
47. Yashiro, J.; Norisuye, T. Polym. Bull. 2006, 56, 467-474
48. Mizuse, M. Master Thesis, Osaka University, 2010.
49. Ueda, M.; Hashidzume, A.; Sato, T. Polym. Prepr. Jpn. 2009, 58, 3057-3058
50. -1, and the excluded volume strength = 15 nm.
51. Tanford, C. Physical Chemistry of Macromolecules; John Wiley & Sons: New York, 1961; Chapter 6.
52. Sato, T.; Kimura, T.; Hashidzume, A. Prog. Theor. Phys., Suppl. 2008, 175, 54-63
53. Manning, G. S. J. Chem. Phys. 1969, 51, 924-933