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Volumn 40, Issue 4, 2007, Pages 1174-1180

Micellar structure of amphiphilic statistical copolymers bearing dodecyl hydrophobes in aqueous media

Author keywords

[No Author keywords available]

Indexed keywords

AMINO ACIDS; FLUORESCENCE; HYDROPHOBICITY; IONIC STRENGTH; LIGHT SCATTERING; MICELLES;

EID: 33847753544     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma062299x     Document Type: Article
Times cited : (82)

References (55)
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    • For example: Hashidzume, A.; Morishima, Y.; Szczubialka, K. In Handbook of Polyelectrolytes and Their Applications; Tripathy, S. K., Kumar, J., Nalwa, H. S., Eds.; American Scientific Publishers: Stevenson Ranch, CA, 2002; 2, pp 1-63 and references therein.
    • For example: Hashidzume, A.; Morishima, Y.; Szczubialka, K. In Handbook of Polyelectrolytes and Their Applications; Tripathy, S. K., Kumar, J., Nalwa, H. S., Eds.; American Scientific Publishers: Stevenson Ranch, CA, 2002; Vol. 2, pp 1-63 and references therein.
  • 2
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    • For example: (a) Hydrophilic Polymers. Performance with Environmental Acceptability; Glass, J. E., Ed.; Advances in Chemistry Series 248; American Chemical Society: Washington, DC, 1996.
    • For example: (a) Hydrophilic Polymers. Performance with Environmental Acceptability; Glass, J. E., Ed.; Advances in Chemistry Series 248; American Chemical Society: Washington, DC, 1996.
  • 3
    • 0003206421 scopus 로고    scopus 로고
    • Associative Polymers in Aqueous Solutions
    • Glass, J. E, Ed, American Chemical Society: Washington, DC
    • (b) Associative Polymers in Aqueous Solutions; Glass, J. E., Ed.; ACS Symposium Series 765; American Chemical Society: Washington, DC, 2000.
    • (2000) ACS Symposium Series , vol.765
  • 4
    • 0041402746 scopus 로고    scopus 로고
    • Stimuli-Responsive Water Soluble and Amphiphilic Polymers
    • McCormick, C. L, Ed, American Chemical Society: Washington, DC
    • (c) Stimuli-Responsive Water Soluble and Amphiphilic Polymers; McCormick, C. L., Ed.; ACS Symposium Series 780; American Chemical Society: Washington, DC, 2001.
    • (2001) ACS Symposium Series , vol.780
  • 6
    • 0029251939 scopus 로고
    • (b) Chu, B. Langmuir 1995, 11, 414-421.
    • (1995) Langmuir , vol.11 , pp. 414-421
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    • Morishima, Y. In Solvents and Self-Organization of Polymers; Webber, S. E., Tuzar, D., Munk, P., Eds.; NATO ASI Series, Ser. E; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1996; 327, pp 331-358.
    • Morishima, Y. In Solvents and Self-Organization of Polymers; Webber, S. E., Tuzar, D., Munk, P., Eds.; NATO ASI Series, Ser. E; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1996; Vol. 327, pp 331-358.
  • 45
    • 33847739368 scopus 로고    scopus 로고
    • This may be because most of all the amino acid residues are in the anionic carboxylate state, and thus the difference in their hydrophobicity may be screened by the strong electrostatic interaction under the present solvent conditions i.e, at pH, 10 in 0.05 M aqueous NaCl
    • This may be because most of all the amino acid residues are in the anionic carboxylate state, and thus the difference in their hydrophobicity may be screened by the strong electrostatic interaction under the present solvent conditions (i.e., at pH = 10 in 0.05 M aqueous NaCl).
  • 49
    • 33847697764 scopus 로고    scopus 로고
    • The statistical copolymer micelle may not form a well-defined hydrophobic microdomain where all the hydrophobes in the micelle are included. Here, we use a simplified hydrophobic microdomain model consisting of single or plural well-defined hydrophobic cores where not all hydrophobes are included
    • The statistical copolymer micelle may not form a well-defined hydrophobic microdomain where all the hydrophobes in the micelle are included. Here, we use a simplified hydrophobic microdomain model consisting of single or plural well-defined hydrophobic cores where not all hydrophobes are included.
  • 53
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    • Modern Theory of Polymer Solutions; Harper's Chemistry
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    • (1971) Series
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  • 54
    • 33847749933 scopus 로고    scopus 로고
    • In this calculation of the micellar radius, we have neglected the train part of the main chain, the linker between the dodecyl group and the main chain, and dodecyl groups outside of the core. A minor error due to these parts may be absorbed in the chosen value of λ
    • In this calculation of the micellar radius, we have neglected the train part of the main chain, the linker between the dodecyl group and the main chain, and dodecyl groups outside of the core. A minor error due to these parts may be absorbed in the chosen value of λ.
  • 55
    • 33847695768 scopus 로고    scopus 로고
    • 12-(0.38) agree with the theoretical values (the black solid lines). However, the agreements seem to be by accident because the theory is based on the uni-core flower micelle.
    • 12-(0.38) agree with the theoretical values (the black solid lines). However, the agreements seem to be by accident because the theory is based on the uni-core flower micelle.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.