Mechanistic elucidation of the formation of the inverse Ca(I) sandwich complex [(thf)3Ca(μ-C6H3-1,3,5-Ph 3)Ca(thf)3] and stability of aryl-substituted phenylcalcium complexes

Journal of the American Chemical Society

Volumn 132, Issue 35, 2010, Pages 12492-12501

  Krieck, Sven ^a   Görls, Helmar ^a   Westerhausen, Matthias ^a  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CALCIUM CATIONS; DEGRADATION REACTION; DINUCLEAR; DIRECT REACTIONS; GOOD YIELD; GRIGNARD REAGENT; ION PAIRS; KINETIC STABILIZATION; LOW TEMPERATURES; ORTHO-SUBSTITUTION; PARA POSITION; PHENYL SUBSTITUENTS; REDUCING REAGENTS; SANDWICH COMPLEXES; STOICHIOMETRIC RATIO; SUBSTITUTION PATTERNS; TERPHENYLS; TRIMETHYL;

BENZENE; CARBON DIOXIDE; DYES; ETHERS; ORGANIC COMPOUNDS; TOLUENE;

CALCIUM;

BENZOIC ACID; CALCIUM; CALCIUM DERIVATIVE; CARBON DIOXIDE; GRIGNARD REAGENT; TOLUENE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; GRIGNARD REACTION; KINETICS; LOW TEMPERATURE; PH; STOICHIOMETRY; X RAY DIFFRACTION;

CALCIUM; CRYSTALLOGRAPHY, X-RAY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS;

EID: 77956233156     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105534w     Document Type: Article

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