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Volumn 21, Issue 17, 2010, Pages 2153-2157

Fine-tunable monodentate phosphoroamidite and aminophosphine ligands for Rh-catalyzed asymmetric hydroformylation

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; PHOSPHINE DERIVATIVE; PHOSPHORAMIDOUS ACID; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; RHENIUM; VINYL DERIVATIVE;

EID: 77956186149     PISSN: 09574166     EISSN: 1362511X     Source Type: Journal    
DOI: 10.1016/j.tetasy.2010.07.005     Document Type: Article
Times cited : (18)

References (48)
  • 8
    • 0004147148 scopus 로고    scopus 로고
    • P.W.N.M. van Leeuwen, C. Claver, Kluwer Academic Press Dordrecht
    • P.W.N.M. van Leeuwen, C. Claver, Rhodium Catalysed Hydroformylation 2000 Kluwer Academic Press Dordrecht
    • (2000) Rhodium Catalysed Hydroformylation
  • 25
    • 4644234208 scopus 로고    scopus 로고
    • It should be pointed out that related monophosphite ligands provided lower enantioselectivities (up to 43%) in the Rh-catalyzed hydroformylation of allyl cyanide. See: C.J. Cobley, J. Klosin, C. Qin, and G.T. Whiteker Org. Lett. 6 2004 3277
    • (2004) Org. Lett. , vol.6 , pp. 3277
    • Cobley, C.J.1    Klosin, J.2    Qin, C.3    Whiteker, G.T.4
  • 34
    • 77956189319 scopus 로고
    • See for instance U.S. Patent 43,76,208
    • See for instance: Vietti, D. E. U.S. Patent 43,76,208, 1983
    • (1983)
    • Vietti, D.E.1
  • 43
    • 77956187793 scopus 로고    scopus 로고
    • There are only two Rh-catalytic systems that have provided better enantioselectivities. One modified with the phosphine-phosphite binaphos ligand (ees up to 76% and 69% for S8 and S9, respectively, see Ref. 14b) and the second modified with a furanoside diphosphite ligand (ees up to 68%, see Ref. 14e)
    • There are only two Rh-catalytic systems that have provided better enantioselectivities. One modified with the phosphine-phosphite binaphos ligand (ees up to 76% and 69% for S8 and S9, respectively, see Ref. 14b) and the second modified with a furanoside diphosphite ligand (ees up to 68%, see Ref. 14e).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.