Cobalt coordination and clustering in α-Co(OH)2 revealed by synchrotron X-ray total scattering

Chemistry - A European Journal

Volumn 16, Issue 33, 2010, Pages 9998-10006

  Neilson, James R ^a   Kurzman, Joshua A ^a   Seshadri, Ram ^a   Morse, Daniel E ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Cobalt; Hydroxides; Materials science; Structure elucidation; Synchrotron radiation; X ray diffraction

Indexed keywords

ANION EXCHANGE CAPACITY; ATOMIC STRUCTURE; BRUCITE; CHLORIDE IONS; COBALT HYDROXIDES; COBALT ION; COBALT SITES; COORDINATION POLYHEDRA; DIFFUSE COMPONENTS; DISTRIBUTION OF METAL; ENERGY TRANSDUCTION; HYDROXIDES; INTRA-LAYER; KINETIC CONTROL; LAYERED COMPOUND; LAYERED HYDROXIDES; LAYERED MATERIAL; LAYERED STRUCTURES; LOCAL CLUSTERING; MAGNETIC BEHAVIOR; MATERIAL PROPERTY; METAL HYDROXIDE; METAL SALT; ORDERED PHASIS; REAL-SPACE ANALYSIS; SHORT LENGTHS; STRUCTURAL CHARACTERISTICS; STRUCTURE DETERMINATION; STRUCTURE ELUCIDATION; STRUCTURE-PROPERTY CORRELATION; SYNCHROTRON X RAYS; TOTAL SCATTERING; UNIT CELLS; WEIGHTED AVERAGES;

CHLORINE COMPOUNDS; COBALT; COORDINATION REACTIONS; DIFFRACTION; FUNCTIONAL MATERIALS; GEOMETRY; HYDRATES; HYDROLYSIS; ION EXCHANGE; ION EXCHANGERS; IONS; MATERIALS SCIENCE; SCATTERING; SYNCHROTRON RADIATION; SYNCHROTRONS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION; X RAYS;

COBALT COMPOUNDS;

COBALT; COBALT HYDROXIDE; HYDROXIDE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; KINETICS; METHODOLOGY; SYNCHROTRON; X RAY DIFFRACTION;

COBALT; HYDROXIDES; KINETICS; MOLECULAR STRUCTURE; SYNCHROTRONS; X-RAY DIFFRACTION;

EID: 77956126096     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201000661     Document Type: Article

References (32)

1. A. F. Wells, Structural Inorganic Chemistry; Clarendon Press, Oxford, 1984.
2. A. Radha, P. Kamath, C. Shivakumara, Acta Crystallogr. Sect. B 2007, 63, 243-250.
3. V. Rives, Layered Double Hydroxides: Present and Future, Nova, New York, 2001.
4. P. J. Sideris, U. G. Nielsen, Z. Gan, C. P. Grey, Science 2008, 321, 113-117.
5. G. Arizaga, K. Satyanarayana, F. Wypych, Solid State Ionics 2007, 178, 1143-1162.
6. M. Rajamathi, P. V. Kamath, R. Seshadri, Mater. Res. Bull. 2000, 35, 271-278.
7. Y. Du, D. O'Hare, J. Phys. Chem. Solids 2008, 69, 1040-1043.
8. R. Ma, Z. Liu, K. Takada, K. Fukuda, Y. Ebina, Y. Bando, T. Sasaki, Inorg. Chem. 2006, 45, 3964-3969.
9. J. Neilson, B. Schwenzer, R. Seshadri, D. Morse, Inorg. Chem. 2009, 48, 11017-11023.
10. T. Egami, S. Billinge, Underneath The Bragg Peaks: Structural Analysis of Complex Materials, Vol. 7, Pergamon Press, Oxford, 2003.
11. M. B. Smith, K. Page, T. Siegrist, P. L. Redmond, E. C. Walter, R. Seshadri, L. E. Brus, M. L. Steigerwald, J. Am. Chem. Soc. 2008, 130, 6955-6963.
12. I.-K. Jeong, F. Mohiuddin-Jacobs, V. Petkov, S. J. L. Billinge, S. Kycia, Phys. Rev. B 2001, 63, 205-202.
13. V. Petkov, P. Trikalitis, E. Bozin, S. Billinge, T. Vogt, M. Kanatzidis, J. Am. Chem. Soc. 2002, 124, 10157-10162.
14. V. Petkov, S. Billinge, J. Heising, M. Kanatzidis, J. Am. Chem. Soc. 2000, 122, 11571-11576.
15. M. Gateshki, S. Hwang, D. Park, Y. Ren, V. Petkov, Chem. Mater. 2004, 16, 5153-5157.
16. K. Page, T. Kolodiazhnyi, T. Proffen, A. Cheetham, Phys. Rev. Lett. 2008, 101, 205502.
17. B. Toby, Powder Diffr. 2006, 21, 67.
18. V. Petkov, R. G. Difrancesco, S. J. L. Billinge, M. Acharya, H. C. Foley, Philos. Mag. B 1999, 79, 1519-1530.
19. "Structural Aspects of Layered Double Hydroxides": D. G. Evans, R. C. T. Slade in Layered Double Hydroxides, Springer, Berlin, 2006, p. 187.
20. a) T. Proffen, S. J. L. Billinge, J. Appl. Crystallogr. 1999, 32, 572-575;
21. I.-K. Jeong, R. H. Heffner, M. J. Graf, Phys. Rev. B 2003, 67, 104301.
22. X. Qiu, E. Bozin, P. Juhas, T. Proffen, S. Billinge, J. Appl. Crystallogr. 2004, 37, 110-116.
23. F. Hawthorne, E. Sokolova, Can. Mineral. 2002, 40, 939-946.
24. B. C. Melot, K. Page, R. Seshadri, E. M. Stoudenmire, L. Balents, D. L. Bergman, T. Proffen, Phys. Rev. B 2009, 80, 104420.
25. B. Schwenzer, K. M. Roth, J. R. Gomm, M. Murr, D. E. Morse, J. Mater. Chem. 2006, 16, 401-407.
26. P. Chupas, X. Qiu, J. Hanson, P. Lee, C. Grey, S. Billinge, J. Appl. Crystallogr. 2003, 36, 1342-1347.
27. A. Hammersley, S. Svensson, M. Hanfland, A. Fitch, D. Hausermann, High Pressure Res. 1996, 14, 235-248.
28. B. Cullity, S. Stock, Elements of X-ray Diffraction, 3rd ed., Prentice Hall, Upper Saddle River, 2001.
29. C. L. Farrow, P. Juhas, J. W. Liu, D. Bryndin, E. S. Bozin, J. Bloch, T. Proffen, S. J. L. Billinge, J. Phys. Condens. Matter 2007, 19, 335219.
30. X. Qiu, J. W. Thompson, S. J. L. Billinge, J. Appl. Crystallogr. 2004, 37, 678.
31. A. C. Larson, R. B. V. Dreele, Los Alamos National Laboratory Report LAUR, 2000, 86748.
32. K. Mommas, F. Izumi, J. Appl. Crystallogr. 2008, 41, 653-658.