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(a) Daudey, J. P.; De Loth, P.; Malrieu, J. P. In Magneto-Structural Correlations in Exchange Coupled Systems; Willet, R. D., Gatteschi, D., Kahn, O., Eds.; Reidel: Dordrecht, Holland, 1985: p 87.
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In ref 9a, p 37
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Kahn, O. In ref 9a, p 37.
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(a) Creutz, C.; Newton, M. D.; Sutin, N. J. Photochem. Photobiol. A: Chem. 1994, 82, 47.
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22
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0029357046
-
-
Polarization effects can reduce r significantly. See: Shin, Y. K.; Brunschwig, B.; Creutz, C.; Sutin, N. J. Am. Chem. Soc. 1995. 117, 8668; J. Phys. Chem. 1996, 100, 8157.
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Shin, Y.K.1
Brunschwig, B.2
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23
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0030134513
-
-
Polarization effects can reduce r significantly. See: Shin, Y. K.; Brunschwig, B.; Creutz, C.; Sutin, N. J. Am. Chem. Soc. 1995. 117, 8668; J. Phys. Chem. 1996, 100, 8157.
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(a) Aquino, M. A. S. Ph.D. Thesis, Carleton University, 1991.
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Ph.D. Thesis, Carleton University
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Naklicki, M. L. Ph.D. Thesis, Carleton University 1995.
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Naklicki, M.L.1
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Aquino, M. A. S.; White, C. A.; Bensimon, C.; Greedan, J. E.; Crutchley, R. J. Can. J. Chem. 1996, 74, 2201.
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34
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0003998388
-
-
CRC Press: Boca Raton, FL
-
At these concentrations, the amount of solvent displaced by solute is very small, and so the diamagnetic correction for the solvent is essentially the same in neat solvent and solution. For an example, see the tables of concentrative properties of aqueous solutions for metal salts in: CRC Handbook of Chemistry and Physics, 60th ed.; Weast, R. C., Astle, M. J., Eds.; CRC Press: Boca Raton, FL. 1980: p D-227.
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Weast, R.C.1
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41
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0002322432
-
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s) shows that X in acetonitrile is a good average. See: Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
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Creutz, C.1
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0001061355
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43
-
-
85088260948
-
-
note
-
DCT are expected to follow the same minor variation in energy as that seen for the LMCT bands in Tables 1-5.
-
-
-
-
44
-
-
0001369156
-
-
See also ref 7
-
The rationale for this method of estimating U has been published: Didziuslis, S. V.; Cohen, S. L.; Gerwirth, A. A.; Solomon, E. I. J. Am. Chem. Soc. 1988, 110, 250. See also ref 7.
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Didziuslis, S.V.1
Cohen, S.L.2
Gerwirth, A.A.3
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33845282895
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Myser, T.K.4
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48
-
-
0542404083
-
-
note
-
Equation 9 is derived from the substitution of the Van Vleck expression for magnetic susceptibility into eq 7.
-
-
-
-
49
-
-
11944256353
-
-
It is also possible to determine -2J from temperature-dependent chemical shift data. See: Cotton, F. A.; Eglin, J. L.; Hong, B.; James, C. A. J. Am. Chem. Soc. 1992, 114, 4915. The solvents used in this study have a limited temperature range and are not optimal for these measurements. In addition, the donor-acceptor interaction between the solvent and animine protons is expected to be temperature dependent.
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Cotton, F.A.1
Eglin, J.L.2
Hong, B.3
James, C.A.4
-
50
-
-
85088251203
-
-
note
-
1/2.
-
-
-
-
51
-
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0000315542
-
-
LaChance-Galang, K. J.; Doan, P. E.; Clarke, M. J.; Rao, U.; Yamano, A.; Hoffman, B. M. J. Am. Chem. Soc. 1995, 117, 3529.
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LaChance-Galang, K.J.1
Doan, P.E.2
Clarke, M.J.3
Rao, U.4
Yamano, A.5
Hoffman, B.M.6
-
52
-
-
0542428032
-
-
note
-
No EPR signal was observed for the complexes in solution at room temperature or as glasses at 77 K.
-
-
-
-
54
-
-
0040567760
-
-
Hush, N. S.; Edgar, A.; Seattle, J. K. Chem, Phys. Lett. 1980, 69, 128.
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Hush, N.S.1
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55
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0001411309
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Joss, S.; Reust, H.; Ludi, A. J. Am. Chem. Soc. 1981, 103, 981.
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Joss, S.1
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56
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84977291643
-
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Aquino, M. A. S.; Crutchley, R. J.; Lee, F. L.; Gabe, E. J.; Bensimon, C. Acta Crystallogr. 1993, C49, 1543.
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-
Aquino, M.A.S.1
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Gabe, E.J.4
Bensimon, C.5
-
57
-
-
0000011727
-
-
4+ showed the dicyd bridging ligand to be planar but with eyanamides in the syn conformation: Rezvani, A. R.; Bensimon, C.; Cromp, B.; Reber, C.; Greedan, J. E.; Kondratiev, V. V.; Crutchley, R. J. Inorg. Chem. 1997, 36, 3322. A crystal structure of the pentaammine analogue in ref 14 showed a planar bridging ligand with cyanamides in the anti conformation.
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-
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Rezvani, A.R.1
Bensimon, C.2
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Greedan, J.E.5
Kondratiev, V.V.6
Crutchley, R.J.7
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58
-
-
84977291643
-
-
Aquino, M. A. S.; Crutchley, R. J.; Lee, F. L.; Gabe, E. J.; Bensimon, C. Acta Crystallogr. 1993, C49, 1543.
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Acta Crystallogr.
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-
Aquino, M.A.S.1
Crutchley, R.J.2
Lee, F.L.3
Gabe, E.J.4
Bensimon, C.5
-
59
-
-
0542428003
-
-
note
-
Recent high-temperature magnetic susceptibility measurements have raised our lower limit for -J from that reported in ref 14.
-
-
-
-
61
-
-
85088274551
-
-
note
-
F is essentially an electron-pairing term which should remain constant for a series of similar complexes
-
-
-
-
62
-
-
85088273940
-
-
note
-
est is calculated by using eq 9 for the experimental range of g = 2.0-2.4 for Ru(III) complexes.
-
-
-
-
63
-
-
85088254287
-
-
note
-
dπ was calculated from MLCT oscillator strengths. See ref 12.
-
-
-
-
64
-
-
0002367256
-
-
Naklicki, M. L.; White, C. A.; Krondratiev, V. V.; Crutchley, R. J. Inorg. Chim. Acta 1996, 242, 63.
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Inorg. Chim. Acta
, vol.242
, pp. 63
-
-
Naklicki, M.L.1
White, C.A.2
Krondratiev, V.V.3
Crutchley, R.J.4
-
65
-
-
0001934217
-
-
Chance, B., DeVault, D. C., Frauenfelder, H., Marcus, R. A., Schrieffer, J. R., Sutin, N., Eds.; Academic Press: New York
-
F is small, it could well be canceled by second-order antiferromagnetic contributions. See ref 9a.
-
(1974)
Tunneling in Biological Systems
, pp. 729
-
-
Okamura, M.Y.1
Fredkin, O.R.2
Isaacson, R.A.3
Feher, G.4
-
66
-
-
0003898192
-
-
F is small, it could well be canceled by second-order antiferromagnetic contributions. See ref 9a.
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(1985)
Chem. Phys. Lett.
, vol.113
, pp. 104
-
-
Bertrand, P.1
-
67
-
-
0542380475
-
-
note
-
The ammine becomes more "amide-like" and contributes π electron density to Ru(III).
-
-
-
-
69
-
-
85088275623
-
-
note
-
2 gave a planar conformer with anti cyanamide groups.
-
-
-
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