Analytic implementation of the GRAAL model: Application to a R7T7-type glass package in a geological disposal environment

Journal of Nuclear Materials

Volumn 404, Issue 3, 2010, Pages 178-202

  Minet, Y ^a   Bonin, B ^b   Gin, S ^a   Frugier, P ^a  

^a DTCD/SECM/LCLT ^*  (France)

^b CEA SACLAY   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALTERATION LAYER; ALTERATION RATES; BORON CONCENTRATIONS; CORROSION PRODUCTS; GEOLOGICAL BARRIERS; GEOLOGICAL DISPOSALS; GLASS PACKAGES; INTEGRAL TEST; INTERNAL MODELS; LABORATORY EXPERIMENTS; LABORATORY TEST; MAIN CHARACTERISTICS; NUCLEAR GLASS; PARAMETER VALUES; PER UNIT VOLUME; PRECIPITATION KINETICS; PRECIPITATION THRESHOLD; PURE WATER; REASONABLE VALUE; SEMI-ANALYTICAL; SENSITIVITY STUDIES; SON68 GLASS; SURFACE AREA; TRANSIENT CONDITIONS; TWO PARAMETER;

ANALYTICAL GEOCHEMISTRY; BORON; BORON COMPOUNDS; CLAY PRODUCTS; DISSOLUTION; GEOLOGIC MODELS; PACKAGING;

BOROSILICATE GLASS;

EID: 77955983854     PISSN: 00223115     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jnucmat.2010.07.015     Document Type: Article

References (35)

1. N. Jacquet-Francillon, R. Bonniaud, and C. Sombret Radiochimica Acta 25 1978 231 240
2. Assemblée Nationale, Loi no. 2006-739 du 28/06/2006 de programme relative la gestion des matires et des déchets radioactifs. < www.legifrance.gouv.fr >.
3. ANDRA, Dossier 2005 Argile, Tome "Phenomenological Evolution of a Geological Repository", ANDRA Report C.RP.ADS.04.0025, 2005, pp. 1-525.
4. R.C. Ewing, Natural glasses: analogues for radioactive waste forms, in: G.J. McCarthy (Ed.), MRS Symposium - Scientific Basis for Nuclear Waste Management, vol. 1, 1979, pp. 57-66.
5. A. Verney-Carron, S. Gin, and G. Libourel Geochimica et Cosmochimica Acta 72 2008 5372 5385
6. A. Verney-Carron, S. Gin, P. Frugier, and G. Libourel Geochimica et Cosmochimica Acta 74 2010 2291 2315
7. P. van Iseghem, K. Lemmens, M. Aertsens, S. Gin, I. Ribet, B. Grambow, J.L. Crovisier, M. Del Nero, E. Curti, B. Schwyn, B. Luckscheiter, T. McMenamin, Chemical durability of high-level waste glass in repository environment: main conclusions and remaining uncertainties from the GLASTAB and GLAMOR projects, in: MRS Symposium - Scientific Basis for Nuclear Waste Management XXIX, vol. 932, 2006, pp. 293-304.
8. P. Frugier, S. Gin, Y. Minet, T. Chave, B. Bonin, N. Godon, J.E. Lartigue, P. Jollivet, A. Ayral, L. De Windt, and G. Santarini Journal of Nuclear Materials 380 2008 8 21
9. P. Frugier, T. Chave, S. Gin, and J.E. Lartigue Journal of Nuclear Materials 392 2009 552 567
10. C. Cailleteau, F. Angeli, F. Devreux, S. Gin, J. Jestin, P. Jollivet, and O. Spalla Nature Materials 7 2008 978 983
11. P. Jollivet, F. Angeli, C. Cailleteau, F. Devreux, P. Frugier, and S. Gin Journal of Non-Crystalline Solids 354 2008 4952 4958
12. B. Grambow, A general rate equation for nuclear waste glass corrosion, in: C.M. Jantzen, J.A. Stone, R.C. Ewing (Eds.), MRS Symposium - Scientific Basis for Nuclear Waste Management VII, vol. 44, 1985, pp. 15-27.
13. B. Grambow, and R. Muller Journal of Nuclear Materials 298 2001 112 124
14. N. Rajmohan, P. Frugier, S. Gin, Modeling the passivating layer of nuclear waste glasses: 1. Experimental observations, Chemical Geology, accepted for publication.
15. I. Ribet, S. Gin, E. Vernaz, R. Do Quang, Long-term behavior of nuclear glass: the r(t) operational model, in: GLOBAL 2001, Paris, 2001, pp. 1-9.
16. I. Ribet, S. Bétrémieux, S. Gin, F. Angeli, C. Jégou, Long-term behavior of vitrified waste packages, in: GLOBAL 2009, Paris, 2009.
17. J.D. Rimstidt, and H.L. Barnes Geochimica et Cosmochimica Acta 44 1980 1683 1699
18. G. Geneste, F. Bouyer, and S. Gin Journal of Non-Crystalline Solids 352 2006 3147 3152
19. T. Advocat, J.L. Crovisier, E. Vernaz, G. Ehret, H. Charpentier, Hydrolysis of R7T7 nuclear waste glass in dilute media: mechanisms and rate as a function of pH, in: T.A. Abrajano Jr., L.H. Johnson (Eds.), MRS Symposium - Scientific Basis for Nuclear Waste Management XIV, vol. 212, 1991, pp. 57-64.
20. T. Chave, Etude des mécanismes d'altération par l'eau du verre R7T7 en milieu confiné, compréhension et modélisation de la cinétique résiduelle. PhD Thesis, Université Montpellier II, Sciences et Techniques du Languedoc, 2008, pp. 1-254.
21. E. Vernaz, and J.L. Dussossoy Applied Geochemistry 7 1992 13 22
22. T. Chave, P. Frugier, A. Ayral, and S. Gin Journal of Nuclear Materials 362 2007 466 473
23. J. Anthony, R. Bideaux, K. Bladh, and M. Nichols Handbook of Mineralogy Mineralogical Society of America 2001 Mineral Data Publishing Berlin
24. S. Gin, and J.P. Mestre Journal of Nuclear Materials 295 2001 83 96
25. S. Ribet, and S. Gin Journal of Nuclear Materials 324 2004 152 164
26. T. Advocat, J.L. Chouchan, J.L. Crovisier, C. Guy,V. Daux, C. Jégou, S. Gin, E. Vernaz, Borosilicate nuclear waste glass alteration kinetics: Chemical inhibition and affinity control, in: MRS Symposium - Scientific Basis for Nuclear Waste Management XXI, vol. 506, 1998, pp. 63-70.
27. P. Appere, Altération de pastille de verre et de poudre de verre nucléaire en régime dynamique. Industrial Project Report (Projet industriel), Ecole des Mines d'Als, 1996, pp. 1-51.
28. F. Delage, Etude de la fonction cinétique d'un verre nucléaire. PhD Thesis, Université de Montpellier II, Sciences et Techniques du Languedoc, 1992, pp. 1-178.
29. P. Frugier, S. Gin, J.E. Lartigue, E. Deloule, SON68 glass dissolution kinetics at high reaction progress: Mechanisms accounting for the residual alteration rate, in: MRS Symposium - Scientific Basis for Nuclear Waste Management XXIX, vol. 932, 2006, pp. 305-312.
30. P. Jollivet, Y. Minet, M. Nicolas, and E. Vernaz Journal of Nuclear Materials 281 2000 231 243
31. r operational model for the long-term behavior of vitrified R7T7 waste packages, in: Advances for Future Nuclear Fuel Cycles Nimes, Atalante, France, 2004, pp. 1-8.
32. C. Pozo, O. Bildstein, J. Raynal, M. Jullien, and E. Valcke Applied Clay Science 35 2007 258 267
33. V. Lagneau, Influence des processus géochimiques sur le transport en milieu poreux: application au colmatage des barrires de confinement potentielles dans un stockage en formation géologique. PhD Thesis, Ecole des Mines de Paris, 2000, pp. 1-186.
34. A. Vinsot, S. Mettler, and S. Vechner Physics and Chemistry of the Earth 33 2008 S75 S86
35. E.C. Gaucher, C. Tournassat, F.J. Pearson, P. Blanc, C. Crouzet, C. Lerouge, and S. Altmann Geochimica et Cosmochimica Acta 73 2009 6470 6487