Application of the GRAAL model to leaching experiments with SON68 nuclear glass in initially pure water

Journal of Nuclear Materials

Volumn 392, Issue 3, 2009, Pages 552-567

  Frugier, P ^a   Chave, T ^b   Gin, S ^a   Lartigue, J E ^c  

^a CEA Marcoule   (France)

^b INSTITUT DE CHIMIE SÉPARATIVE DE MARCOULE   (France)

^c IRFM   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALTERATION LAYER; AQUEOUS ALTERATION; CALCULATION CODE; CHEMICAL EQUILIBRIUMS; CLOSED SYSTEMS; ELEMENT CONCENTRATIONS; ELEMENT DIFFUSION; EXPERIMENTAL CONDITIONS; EXPERIMENTAL DATA; FUNCTION OF TIME; GEOCHEMICAL MODELS; GLASS SURFACES; INTEGRAL PART; ION TRANSPORTS; LEACHING EXPERIMENTS; MECHANISTIC MODELS; MODEL RESULTS; NUCLEAR GLASS; PURE WATER; SOLUTION PH; SON68 GLASS;

CHEMICAL ELEMENTS; DIFFUSION; GELATION; LEACHING; REACTIVITY (NUCLEAR);

GLASS;

EID: 67651119883     PISSN: 00223115     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jnucmat.2009.04.024     Document Type: Article

References (37)

1. Frugier P., Gin S., Minet Y., Chave T., Bonin B., Godon N., Lartigue J.E., Jollivet P., Ayral A., De Windt L., and Santarini G. J. Nucl. Mater. 380 (2008) 8
2. Assemblée Nationale, Projet de loi de programme relatif à la gestion durable des matières et des déchets radioactifs, in: 590 ed., 2006, p. 1.
3. r operational model for the long-term behavior of vitrified R7T7 waste packages, in: Advances for Future Nuclear Fuel Cycles Nimes, Atalante France, 2004, p. 1.
4. van der Lee J., De Windt L., Lagneau V., and Goblet P. Comput. Geosci. 29 (2003) 265
5. Conradt R. J. Am. Ceram. Soc. 91 (2008) 728
6. Gin S., Jegou C., Frugier P., and Minet Y. Chem. Geol. 255 (2008) 14
7. Zhang L., and Lüttge A. J. Phys. Chem. B 112 (2008) 1736
8. M. Arab, C. Cailleteau, F. Angeli, F. Devreux, Experimental study and Monte Carlo modeling of calcium borosilicate glasses leaching, in: D. Dunn, C. Poinssot, B. Begg (Eds.), Scientific Basis for Nuclear Waste Management XXX, 985 ed., Materials Research Society, Boston, Massachussetts, USA, 2007, p. 193.
9. Ledieu A., Devreux F., Barboux P., and Minet Y. Nucl. Sci. Eng. 153 (2006) 285
10. C. Cailleteau, F. Angeli, F. Devreux, S. Gin, J. Jestin, P. Jollivet, O. Spalla, Nature Mater., in press.
11. Frugier P., Martin C., Ribet I., Advocat T., and Gin S. J. Nucl. Mater. 346 (2005) 194
12. Grambow B., and Muller R. J. Nucl. Mater. 298 (2001) 112
13. Spalla O., Barboux P., Sicard L., Lyonnard S., and Bley F. J. Non-Cryst. Solids 347 (2004) 56
14. Devreux F., Ledieu A., Barboux P., and Minet Y. J. Non-Cryst. Solids (2003) 1
15. I. Ribet, S. Gin, E. Vernaz, R. Do Quang, Long-term behavior of nuclear glass: the r(t) operational model, in: GLOBAL 2001, Paris, 2001, p. 1.
16. McGrail B.P., Bacon D.H., Icenhower J., Mann F.M., Puigh R.J., Schaef H.T., and Mattigod S.V. J. Nucl. Mater. 298 (2001) 95
17. Munier I., Crovisier J.L., Grambow B., Fritz B., and Clément A. J. Nucl. Mater. 324 (2004) 97
18. B.P. McGrail, J. Icenhower, J.G. Darab, D.K. Shuh, D.R. Baer, V. Shutthanandan, S. Thevuthasan, G. Engelhard, J.L. Steele, E.A. Rodriguez, P. Liu, K.E. Ivanov, C.H. Booth, P. Nachimuthu, Ion-Exchange Processes and Mechanisms in Glasses, Pacific Northwest Laboratory (Ed.), 2001, p. 1.
19. Valle N., Sterpenich J., and Libourel G. Geochim. Cosmochim. Acta (2001) 1
20. Techer I., Advocat T., Lancelot J., and Liotard J.M. Chem. Geol. 176 (2001) 235
21. Verney-Carron A., Gin S., and Libourel G. Geochim. Cosmochim. Acta 72 (2008) 5372
22. J. van der Lee, L. De Windt, Chess tutorial and cookbook, Updated for version 3.0, in: École des Mines de Paris (Ed.), LHM/RD/02/13 ed., 2002.
23. T.J. Wolery, A software package for geochemical modelling of aqueous systems: package overview and installation guide (version 7.0), in: Lawrence Livermore National Laboratory (USA) (Ed.), UCRL-MA-110662 ed., 1992.
24. Jégou C., Gin S., and Larché F. J. Nucl. Mater. 280 (2000) 216
25. Munier I., Grambow B., Fritz B., and Clement A. J. Nucl. Mater. 324 (2004) 97
26. Grambow B. Am. Ceram. Soc. (1984) 474
27. Ribet S., and Gin S. J. Nucl. Mater. 324 (2004) 152
28. Armelao L., Bassan A., Bertoncello R., Biscontin G., Daolio S., and Glisenti A. J. Cult. Heritage 1 (2000) 375
29. Chave T., Frugier P., Ayral A., and Gin S. J. Nucl. Mater. 362 (2007) 466
30. G. de Combarieu, Altération du verre de confinement de déchets type R7T7 en condition de stockage géologique. Ph.D. Thesis, Univ. Paris XI, Orsay, France, p. 1.
31. T. Chave, Etude des mécanismes d'altération par l'eau du verre R7T7 en milieu confiné, compréhension et modélisation de la cinétique résiduelle, in: Université Montpellier II, Science et Technique du Languedoc, 2008, p. 1.
32. P. Van Iseghem, M. Aertsens, S. Gin, D. Deneele, B. Grambow, P. McGrail, D. Strachan, G. Wicks, A critical evaluation of the dissolution mechanisms of high-level waste glasses in conditions of relevance for geological disposal (GLAMOR), in: SCK·CEN, CEA, Subatech, PNNL, SRNL (Eds.), EUR 23097 ed., 2007, p. 1.
33. P. Frugier, S. Gin, J.E. Lartigue, E. Deloule, SON68 glass dissolution kinetics at high reaction progress: mechanisms accounting for the residual alteration rate, in: Mat. Res. Soc. Symp. Proc. vol. 932, 2006, p. 305.
34. Boksay Z., Bouquet G., and Dobos S. Phys. Chem. Glasses 9 (1968) 69
35. S. Gin, C. Jegou, Limiting mechanisms of borosilicate glass alteration kinetic:effect of glass composition, in: A.A. Balkema (Ed.), Water-Rock Interaction, first ed., Villasimius, Italy, 2001, p. 279.
36. I.S. Muller, S. Ribet, I.L. Pegg, S. Gin, P. Frugier, Characterization of alteration phases on HLW glasses after 15 years of PCT leaching, Ceram. Trans., vol. 176, Am. Ceram. Society, Westerville, OH, 2006, p. 191.
37. M. Aertsens, The BRAG and GM2003 models for glass dissolution, in Mater. Res. Soc. Symp. Proc., vol 985, 2007, p. 117.