High capacity and excellent stability of lithium ion battery anode using interface-controlled binder-free multiwall carbon nanotubes grown on copper

ACS Nano

Volumn 4, Issue 6, 2010, Pages 3440-3446

  Lahiri, Indranil ^a   Oh, Sung Woo ^b   Hwang, Jun Y ^c   Cho, Sungjin ^d   Sun, Yang Kook ^b   Banerjee, Rajarshi ^c   Choi, Wonbong ^a,b  

^a The Department of Electrical and Computer Engineering   (United States)

^b Hanyang University   (South Korea)

^c UNIVERSITY OF NORTH TEXAS   (United States)

^d MARQUETTE UNIVERSITY   (United States)

Author keywords

Carbon nanotube; Intercalation; Lithium ion batteries; Specific capacity; Stability

Indexed keywords

CAPACITY DEGRADATION; CARBON NANOTUBE WALLS; CATALYST DEPOSITION; CHARGING/DISCHARGING; CURRENT COLLECTOR; HIGH CAPACITY; HIGH SPECIFIC CAPACITY; ION INTERCALATION; LI-ION BATTERIES; LITHIUM ION BATTERIES; LITHIUM-ION BATTERY; MULTI-WALL CARBON NANOTUBES; RATE CAPABILITIES; SPECIFIC CAPACITIES; TWO-STEP PROCESS;

BINDERS; CARBON NANOTUBES; CHEMICAL VAPOR DEPOSITION; IONS; LITHIUM; LITHIUM ALLOYS; LITHIUM COMPOUNDS;

MULTIWALLED CARBON NANOTUBES (MWCN);

CARBON NANOTUBE; COPPER; LITHIUM;

ARTICLE; CHEMISTRY; ELECTRODE; ENERGY TRANSFER; EQUIPMENT; EQUIPMENT DESIGN; INSTRUMENTATION; MATERIALS TESTING; NANOTECHNOLOGY; PARTICLE SIZE; POWER SUPPLY; ULTRASTRUCTURE;

COPPER; ELECTRIC POWER SUPPLIES; ELECTRODES; ENERGY TRANSFER; EQUIPMENT DESIGN; EQUIPMENT FAILURE ANALYSIS; LITHIUM; MATERIALS TESTING; NANOTECHNOLOGY; NANOTUBES, CARBON; PARTICLE SIZE;

EID: 77955891935     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn100400r     Document Type: Article

References (42)

1. Nazri, G.-A.; Pistoia, G. In Lithium Batteries: Science and Technology; Springer Science+Business Media: New York, 2009.
2. Manev, V.; Naidenov, I.; Puresheva, B.; Zlatilova, P.; Pistoia, G. Electrochemical Performance of Natural Brazilian Graphite as Anode Material for Lithium-Ion Rechargeable Cells. J. Power Sources 1995, 55, 211-215.
3. Dai, H.; Javey, A.; Pop, E.; Mann, D.; Lu, Y. Electrical Transport Properties and Field Effect Transistors of Carbon Nanotubes. Nano 2006, 1, 1-13.
4. Yang, Z.-H.; Wu, H.-Q. Electrochemical Intercalation of Lithium into Raw Carbon Nanotubes. Mater. Chem. Phys. 2001, 71, 7-11.
5. Frackowiak, E.; Béguin, F. Electrochemical Storage of Energy in Carbon Nanotubes and Nanostructured Carbons. Carbon 2002, 40, 1775-1787.
6. Shin, H.-C.; Liu, M.; Sadanadan, B.; Rao, A. M. Electrochemical Insertion of Lithium into Multiwalled Carbon Nanotubes Prepared by Catalytic Decomposition. J. Power Sources 2002, 112, 216-221.
7. Eom, J. Y.; Kwon, H. S. Improved Lithium Insertion/Extraction Properties of Single-Walled Carbon Nanotubes by High-Energy Ball Milling. J. Mater. Res. 2008, 23, 2458-2466.
8. Landi, B. J.; Ganter, M. J.; Schauerman, C. M.; Cress, C. D.; Raffaelle, R. P. Lithium Ion Capacity of Single Wall Carbon Nanotube Paper Electrodes. J. Phys. Chem. C 2008, 112, 7509-7515.
9. Guo, A. P.; Zhao, Z. W.; Liu, H. K.; Dou, S. X. Electrochemical Lithiation and Delithiation of MWNT-Sn/SnNi Nanocomposites. Carbon 2005, 43, 1392-1399.
10. Yoo, E. J.; Kim, J.; Hosono, E.; Zhoi, H.-S.; Kudo, T.; Honma, I. Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries. Nano Lett. 2008, 8, 2277-2282.
11. Boukamp, B. A.; Lesh, G. C.; Huggins, R. A. All-Solid Lithium Electrodes with Mixed-Conductor Matrix. J. Electrochem. Soc. 1981, 128, 725-729.
12. 2/Graphene Nanoporous Electrodes with Three-Dimensionally Delaminated Flexible Structure. Nano Lett. 2009, 9, 72-75.
13. Fan, J.; Wang, T.; Yu, C.; Tu, B.; Jiang, Z.; Zhao, D. Ordered, Nanostructured Tin-Based Oxides/Carbon Composite as the Negative-Electrode Material for Lithium-Ion Batteries. Adv. Mater. 2004, 16, 1432-1436.
14. Chan, C. K.; Peng, H.; Liu, G.; McIlwrath, K.; Zhang, X. F.; Huggins, R. A.; Cui, Y. High-Performance Lithium Battery Anodes Using Silicon Nanowires. Nat. Nanotechnol. 2008, 3, 31-35.
15. Shu, J.; Li, H.; Yang, R.; Shi, Y.; Huang, X. Cage-like Carbon Nanotubes/Si Composite as Anode Material for Lithium Ion Batteries. Electrochem. Commun. 2006, 8, 51-54. (Pubitemid 43006158)
16. 2 Nanotubes with Coaxially Grown Carbon Nanotube Overlayers. Adv. Mater. 2006, 18, 645-649.
17. Zhang, Y.; Zhang, X. G.; Zhang, H. L.; Zhao, Z. G.; Li, F.; Liu, C.; Cheng, H. M. Composite Anode Material of Silicon/Graphite/Carbon Nanotubes for Li ion Batteries. Electrochim. Acta 2006, 51, 4994-5000.
18. Eom, J. Y.; Park, J. W.; kwon, H. S.; Rajendran, S. Electrochemical Insertion of Lithium into Multiwall Carbon Nanotube/Silicon Composites Produced by Ball Milling. J. Electrochem. Soc. 2006, 153, A1678-A1684.
19. Wang, W.; Kumta, P. N. Reversible High Capacity Nanocomposite Anodes of Si/C/SWNTs for Rechargeable Li ion Batteries. J. Power Sources 2007, 172, 650-658.
20. Park, M.-S.; Needham, S. A.; Wang, G.-X.; Kang, Y.-M.; Park, J.-S.; Dou, S.-X.; Liu, H.-K. Nanostructured SnSb/Carbon Nanotube Composites Synthesized by Reductive Precipitation for Lithium-Ion Batteries. Chem. Mater. 2007, 19, 2406-2410.
21. Li, C.; Sun, N.; Ni, J.; Wang, J.; Chu, H.; Zhou, H.; Li, M.; Li, Y. Controllable Preparation and Properties of Composite Materials Based on Ceria Nanoparticles and Carbon Nanotubes. J. Solid State Chem. 2008, 181, 2620-2625.
22. 2-Au Coaxial Nanocable for Lithium-Ion Batteries with High Rate Capability. Chem. Mater. 2008, 20, 6951-6956.
23. Zheng, S.-F.; Hu, J.-S.; Zhong, L.-S.; Song, W.-G.; Wan, L.-J.; Guo, Y.-G. Introducing Dual Functional CNT Networks into CuO Nano/Micro Spheres toward Superior Electrode Materials for Lithium-Ion Batteries. Chem. Mater. 2008, 20, 3617-3622.
24. 4 Cathode of Li ion Batteries. J. Power Sources 2002, 109, 422-426.
25. 4 Water-Soluble Binder Electrode for Li ion Batteries. J. Power Sources 2007, 163, 1047-1052.
26. Zhang, S. S.; Xu, K.; Jow, T. R. Evaluation on a Water-Based Binder for the Graphite Anode of Li ion Batteries. J. Power Sources 2004, 138, 226-231.
27. Roth, E. P.; Doughty, D. H.; Franklin, J. DSC Investigation of Exothermic Reactions Occurring at Elevated Temperatures in Lithium-Ion Anodes Containing PVDF-Based Binders. J. Power Sources 2004, 134, 222-234.
28. Ishihara, T.; Nakasu, M.; Yoshio, M.; Nishiguchi, H.; Takita, Y. Carbon Nanotube Coating Silicon Doped with Cr as a High Capacity Anode. J. Power Sources 2005, 146, 161-165.
29. Choi, W. B.; Cho, S. J.; Lahiri, I. High Efficiency Lithium Ion Battery Anode Using Interface-Controlled Binder-Free Carbon Nanotubes Grown on Metal/Alloy Substrates. U. S. Patent Appl. No. 61/222, 481 (Filing date: 07/02/2009).
30. 2Sb Nanocomposites. Electrochem. Commun. 2002, 4, 260-265.
31. Masarapu, C.; Subramanian, V.; Zhu, H.; Wei, B. Long-Cycle Electrochemical Behavior of Multiwall Carbon Nanotubes Synthesized on Stainless Steel in Li ion Batteries. Adv. Funct. Mater. 2009, 19, 1008-1014.
32. Cui, L.-F.; Yang, Y.; Hsu, C.-M.; Cui, Y. Carbon-Silicon Core-Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries. Nano Lett. 2009, 9, 3370-3374.
33. Kakshedikar, N. A.; Maier, J. Lithium Storage in Carbon Nanostructures. Adv. Mater. 2009, 21, 2664-2680.
34. Maurin, G.; Bousquet, Ch.; Henn, F.; Bernier, P.; Almairac, R.; Simon, B. Electrochemical Intercalation of Lithium into Multiwall Carbon Nanotubes. Chem. Phys. Lett. 1999, 312, 14-18. (Pubitemid 129556567)
35. Nishidate, K.; Hasegawa, M. Energetics of Lithium Ion Adsorption on Defective Carbon Nanotubes. Phys. Rev. B 2005, 71, 245418.
36. Watts, P. C. P.; Hsu, W.-K.; Kroto, H. W.; Walton, D. R. M. Are Bulk Defective Carbon Nanotubes Less Electrically Conducting. Nano Lett. 2003, 3, 549-553.
37. Parthangal, P. M.; Cavicchi, R. E.; Zachariah, M. R. A Generic Process of Growing Aligned Carbon Nanotubes Arrays on Metals and Metal Alloys. Nanotechnoloqy 2007, 18, 185605-1-5.
38. Matsuda, Y.; Deng, W.-Q.; Goddard, W. A. III. Contact Resistance Properties between Nanotubes and Various Metals from Quantum Mechanics. J. Phys. Chem. C 2007, 111, 11113-11116.
39. Zhang, J.; Wang, X.; Yang, W.; Yu, W.; Feng, T.; Li, Q.; Liu, X.; Yang, C. Interaction between Carbon Nanotubes and Substrate and its Implication in Field Emission Mechanism. Carbon 2006, 44, 418-422.
40. Huang, R.; Fan, X.; Shen, W.; Zhu, J. Carbon-Coated Silicon Nanowire Array Films for High-Performance Lithium-Ion Battery Anodes. Appl. Phys. Lett. 2009, 95, 133119.
41. Park, M.-H.; Kim, M. G.; Joo, J.; Kim, K.; Kim, J.; Ahn, S.; Cui, Y.; Cho, J. Silicon Nanotube Battery Anodes. Nano Lett. 2009, 9, 3844-3847.
42. Lahiri, I.; Seelaboyina, R.; Hwang, J. Y.; Banerjee, R.; Choi, W. Enhanced Field Emission from Multiwalled Carbon Nanotubes Grown on Pure Copper Substrate. Carbon 2010, 48, 1531-1538.