Effects of triglyceride molecular structure on optimum formulation of surfactant-oil-water systems

Journal of Surfactants and Detergents

Volumn 13, Issue 2, 2010, Pages 189-194

  Phan, Tri T ^a,b   Harwell, Jeffrey H ^a,b   Sabatini, David A ^a,b  

^a UNIVERSITY OF OKLAHOMA   (United States)

^b University of Oklahoma   (United States)

Author keywords

EACN; Extended surfactant; Microemulsion; Oil hydrophobicity; Triglyceride; Vegetable oil

Indexed keywords

DOUBLE BONDS; DYNAMIC INTERFACIAL TENSION; EACN; ESTER GROUPS; EXTENDED SURFACTANTS; INTERFACIAL TENSION VALUES; OIL HYDROPHOBICITY; OIL UNSATURATION; OIL-WATER SYSTEM; OPTIMUM FORMULATION; SURFACTANT INTERACTION; TRIGLYCERIDE; TRIGLYCERIDE OIL;

CHAIN LENGTH; ESTERS; HYDROPHOBICITY; LUBRICATING OILS; MICROEMULSIONS; SALINITY MEASUREMENT; STRUCTURAL OPTIMIZATION; VEGETABLE OILS; WATERWORKS;

SURFACE ACTIVE AGENTS;

EID: 77955853374     PISSN: 10973958     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11743-009-1155-1     Document Type: Article

References (26)

1. Gunstone FD (2002) Vegetable oils in food technology: composition, properties and uses. Blackwell, Boca Raton
2. Hamilton RJ, Bhati A (1987) Recent advances in chemistry and technology of fats and oils. Elsevier Applied Science, New York
3. Knothe G (2006) Biodiesel and vegetable oil fuels: then and now. Inform 17:729-731
4. Baumann H, Buehler M, Fochem H, Hirsinger F, Zoebelein H, Falbe J (1988) Natural fats and oils-renewable raw materials for the chemical industry. Angew Chem Int Ed Engl 27:41-62
5. Kalustian P (1984) Pharmaceutical and cosmetic uses of palm and lauric products. J Am Oil Chem Soc 62:77-79
6. Crandall L (2003) Surfactant trends in personal-care products. Inform 14:270-271
7. McClements DJ (2005) Food emulsions: principles, practices, and techniques, 2nd edn. CRC Press, Boca Raton
8. Alander J, Warnheim T (1989) Model microemulsions containing vegetable oils part 1: nonionic surfactant systems. J Am Oil Chem Soc 66:1656-1660 (Pubitemid 20632660)
9. Alander J, Warnheim T (1989) Model microemulsions containing vegetable oils 2. Ionic surfactant systems. J Am Oil Chem Soc 66:1661-1665 (Pubitemid 20632661)
10. Miñana-Pérez M, Graciaa A, Lachaise J, Salager JL (1995) Solubilization of polar oils with extended surfactants. Colloids Surf A 100:217-224
11. von Corswant C, Soderman O (1997) Microemulsions based on soybean phosphatidylcholine and triglycerides. Phase behavior and microstructure. Langmuir 13:5061-5070
12. Huang L, Lips A, Co CC (2004) Microemulsification of triglyceride sebum and the role of interfacial structure on bicontinuous phase behavior. Langmuir 20:3559-3563
13. Engelskirchen S, Elsner N, Sottmann T, Strey R (2007) Triacylglycerol microemulsions stabilized by alkyl ethoxylate surfactants-a basic study. Phase behavior, interfacial tension and microstructure. J Colloid Interface Sci 312:114-121
14. Winsor P (1954) Solvent properties of amphiphilic compounds. Butterworths, London
15. Bourrel M, Schechter R (1988) Microemulsions and related systems. Marcel Dekker, New York
16. Salager JL, Anton RE, Sabatini DA, Harwell JH, Acosta EJ, Tolosa LI (2005) Enhancing solubilization in microemulsions-state of the art and current trends. J Surfact Deterg 8:3-21
17. Salager JL, Morgan J, Schechter RS, Wade WH, Vasquez E (1979) Optimum formulation of surfactant-oil-water systems for minimum tension and phase behavior. J Soc Petrol Eng 19:107-115
18. Miñana-Pérez M, Graciaa A, Lachaise J, Salager JL (1995) Solubilization of polar oils in microemulsions systems. Colloid Polym Sci 98:177-179
19. Aoudia M, Wade WH, Weerasooriya V (1995) Optimum microemulsions formulated with propoxylated guerbet alcohol and propoxylated tridecyl alcohol sodium sulfates. J Dispers Sci Technol 16:115-135
20. Nardello V, Chailloux N, Poprawski J, Salager JL, Aubry JM (2003) HLD concept as a tool for the characterization of cosmetic hydrocarbon oils. Polym Int 52:602-609
21. Witthayapanyanon A, Acosta EJ, Harwell JH, Sabatini DA (2006) Formulation of ultralow interfacial tension systems using extended surfactants. J Surf Deterg 9:331-339
22. Queste S, Salager JL, Strey R, Aubry JM (2007) The EACN scale for oil classification revisited thanks to fish diagrams. J Colloid Interface Sci 312:98-107
23. Witthayapanyanon A, Harwell JH, Sabatini DA (2008) Hydrophilic-lipophilic deviation (HLD) method for characterizing conventional and extended surfactants. J Colloid Interface Sci 325:259-266
24. Do LD, Witthayapanyanon A, Harwell JH, Sabatini DA (2009) Environmentally friendly vegetable oil microemulsions using extended-surfactants and linkers. J Surf Deterg 12:91-99
25. Velásquez J, Scorzza C, Vejar F, Forgiarini AM, Antón RE, Salager JL (2009) Effect of temperature and other variables on the optimum formulation of anionic extended surfactant-alkane-brine systems. J Surf Deterg. doi:10.1007/s11743-009-1142-6 (in press)
26. American Society of Chemist. The CAS registry via SciFinder scholar, version 2007. Accessed 16 Dec. 2008