Bioethanol dehydration: State of the art

Theoretical Foundations of Chemical Engineering

Volumn 44, Issue 4, 2010, Pages 545-556

  Frolkova, A K ^a   Raeva, V M ^a  

^a MIREA RUSSIAN TECHNOLOGICAL UNIVERSITY   (Russian Federation)

Author keywords

azeotropes; bioethanol dehydration; dehydrated ethanol; distillation; hybrid process; water ethanol mixtures

Indexed keywords

DEHYDRATED ETHANOL; DEHYDRATION OF ETHANOL; FERMENTATION PROCESS; HYBRID PROCESS; SEPARATION TECHNIQUES; STATE OF THE ART; WATER-ETHANOL MIXTURES;

BIOETHANOL; DEHYDRATION; DEWATERING; DISTILLATION; ETHANOL; FERMENTATION;

AZEOTROPES;

EID: 77955752049     PISSN: 00405795     EISSN: None     Source Type: Journal    
DOI: 10.1134/S0040579510040342     Document Type: Article

References (77)

1. W. Kaminski J. Marszalek A. Ciolkowska 2008 Renewable Energy Source-Dehydrated Ethanol Chem. Eng. J. 135 1 95 102 10.1016/j.cej.2007.03.017 1:CAS:528:DC%2BD2sXhtlahtb7N (Pubitemid 350088555)
2. A.V. Tsarev R.M. Balabin S.A. Karpov R.Z. Syunyaev 2007 Optimization of the Performance and Environmental Properties of Ethanol-Gasoline Fuels Using Microwave Treatment Alternat. Energet. Ekol. 52 8 69 74
3. O.J. Sanches C.A. Cardona 2008 Trends in Biotechnological Production of Fuel Ethanol from Different Feedstocks Bioresour. Technol. 99 13 5270 5295 10.1016/j.biortech.2007.11.013
4. C.A. Cardona O.J. Sanches 2007 Fuel Ethanol Production: Process Design Trends and Integration Opportunities Bioresour. Technol. 98 2 2415 2457 10.1016/j.biortech.2007.01.002 1:CAS:528:DC%2BD2sXjtVaiu70%3D (Pubitemid 46413752)
5. K.L. Wasewar V.G. Pangarkar 2006 Intensification of Recovery of Ethanol from Fermentation Broth Using Pervaporation: Economical Evaluation Chem. Biochem. Eng. Q. 20 2 135 145 1:CAS:528:DC%2BD28XotVCgtb8%3D
6. W.J. Blackburn J.M. Teague 1998 Coordinating California's Efforts to Promote Waste to Alcohol Production Appl. Biochem. Biotechnol. 70-72 821 841 10.1007/BF02920192
7. S.A. Karpov 2008 Current Aspects of Fuel Ethanol Production in Russia and Abroad Chem. Technol. Fuels Oils 44 1 1 4 10.1007/s10553-008-0001-x 1:CAS:528:DC%2BD1cXhtVKntLnO
8. www.abercade.ru/research/analysis/425.html, www.e-vid.ru/index-m-192-p- 63-article-17596.htm
9. L.A. Serafimov A.K. Frolkova 1997 Fundamental Principle of Concentration-Field Redistribution between Separation Regions as a Basis for the Design of Technological Systems Teor. Osn. Khim. Tekhnol. 31 2 193 201
10. Theor. Found. Chem. Eng. (Engl. Transl.), vol. 31, no. 2, pp. 159-166
11. Frolkova, A.K., Theoretical Foundations of Multicomponent Multiphase Separation Using Functional Complexes, Doctoral (Eng.) Dissertation, Moscow: Moscow Inst. of Fine Chemical Technology, 2000.
12. A.M. Polyakov 2004 Some Aspects of the Pervaporation Separation of Liquid Mixtures Krit. Tekhnol. Membr. 24 4 29 44
13. W. Kujawski 2000 Application of Pervaporation and Vapor Permeation in Environmental Protection Pol. J. Environ. Stud. 9 1 13 26 1:CAS:528: DC%2BD3cXitlGltL0%3D
14. S.L. Wee C.T. Tye S. Bhatia 2008 Membrane Separation Process- Pervaporation through Zeolite Membrane Sep. Purif. Technol. 63 3 500 516 10.1016/j.seppur.2008.07.010 1:CAS:528:DC%2BD1cXht12ltrfJ
15. V.V. Namboodiri L.M. Vane 2007 High Permeability Membranes for the Dehydration of Low Water Content Ethanol by Pervaporation J. Membr. Sci. 306 s.1-2 209 215 10.1016/j.memsci.2007.08.050 1:CAS:528:DC%2BD2sXht12htLjP (Pubitemid 350051621)
16. F. Banat A.-RabF. Abu K. Bani-Melhem 2003 Desalination by Vacuum Membrane Distillation: Sensitivity Analysis Sep. Purif. Technol. 33 1 75 87 10.1016/S1383-5866(02)00221-6 1:CAS:528:DC%2BD3sXkt1Wrsr4%3D (Pubitemid 36720474)
17. S. Furukawa K. Goda Yi. Zhang T. Nitta 2004 Molecular Simulation Study on Adsorption and Diffusion Behavior of Ethanol/Water Molecules in NaA Zeolite Crystal J. Chem. Eng. Jpn. 37 1 67 74 10.1252/jcej.37.67 1:CAS:528: DC%2BD2cXpvVGltQ%3D%3D (Pubitemid 38454015)
18. H.J. Huang S. Ramaswamy W. Tschirner B.V. Ramarao 2008 A Review of Separation Technologies in Current and Future Biorefineries Sep. Purif. Technol. 62 1 1 21 10.1016/j.seppur.2007.12.011 1:CAS:528:DC%2BD1cXntl2ks7k%3D
19. Makarov, V.V. Petrykin, A.A., Skvortsov, E.A., et al., RF Patent 2?265?473, Byull. Izobret., 2005, no. 34.
20. L. Lu Q. Shao LuX. Huang 2007 Simulation of Adsorption and Separation of Ethanol-Water Mixtures with Zeolite and Carbon Nanotube Fluid Phase Equilib. 261 s.1-2 191 198 10.1016/j.fluid.2007.07.057 1:CAS:528:DC%2BD2sXhtFyks7rF (Pubitemid 47588717)
21. M.R. Ladisch M. Voloch J. Hong, et al. 1983 Cornmeal Adsorber for Dehydrating Ethanol Vapors Ind. Eng. Chem. Proc. Des. Dev. 23 437 445 10.1021/i200026a005
22. M. Simo C.J. Brown V. Hlavacek 2008 Simulation of Pressure Swing Adsorption in Fuel Ethanol Production Process Comput. Chem. Eng. 32 7 1635 1649 10.1016/j.compchemeng.2007.07.011 1:CAS:528:DC%2BD1cXlsV2lsLc%3D (Pubitemid 351608429)
23. A. Pucci 1989 Phase Equilibria of Alkanol/Alkane Mixtures in New Oil and Gas Process Development Pure Appl. Chem. 61 8 1363 1372 10.1351/pac198961081363 1:CAS:528:DyaL1MXltlOjtLc%3D
24. R.D. Offemanm S.K. Stephenson P. Franqui J.L. Cline 2008 Extraction of Ethanol with Higher Alcohol Solvents and Their Toxicity to Yeast Sep. Purif. Technol. 63 2 444 451 10.1016/j.seppur.2008.06.005
25. www.ethanolindia.net/molecular-sieves.html,vasatwiki.icrisat.org/index. php/Grain-alcohol#Purification
26. M.A. Rodrigues J. Almeida J. Li H.A. Matos E.G. De Azevendo 2006 Efficiency of Water Removal from Water/Ethanol Mixtures Using Supercritical Carbon Dioxide Braz. J. Chem. Eng. 23 2 205 212 10.1590/S0104-66322006000200007 1:CAS:528:DC%2BD28XlsVels70%3D
27. 2-Organic Binary Solvent Systems (Ethanol, Tetrahydrofuran, ortho-Xylene, meta-Xylene, para-Xylene) J. Supercrit. Fluids 43 3 383 389 10.1016/j.supflu.2007.07.020 1:CAS:528:DC%2BD2sXht1SrtbbL (Pubitemid 47588831)
28. A. Giivenc U. Mehmetoglu A. Calimi 1999 Supercritical Extraction of Ethanol Turk. J. Chem. 33 285 291
29. M. Budich G. Brunner 2003 Supercritical Fluid Extraction of Ethanol from Aqueous Solutions J. Supercrit. Fluids 25 1 45 55 10.1016/S0896-8446(02)00091-8 1:CAS:528:DC%2BD38Xpslaksbk%3D
30. C. Schacht C. Zetzl G. Brunner 2008 From Plant Materials to Ethanol by Means of Supercritical Fluid Technology J. Supercrit. Fluids 46 3 299 321 10.1016/j.supflu.2008.01.018 1:CAS:528:DC%2BD1cXhtVCgurfM
31. L'vov, S.V., Nekotorye voprosy rektifikatsii binarnykh i mnogokomponentnykh smesei (Topics in the Distillation of Binary and Multicomponent Mixtures), Moscow: Akad. Nauk SSSR, 1960.
32. N. Arifeen R. W. Ioannis K. Kookos, et al. 2007 Process Design and Optimization of Novel Wheat-Based Continuous Bioethanol Production System Biotechnol. Prog. 23 6 1394 1403 10.1021/bp0701517 1:CAS:528:DC%2BD2sXhtFehu7rE (Pubitemid 350261875)
33. www.chemsite.ru/abstract-25040.htm
34. Serafimov, L.A., Separation of Azeotropic Mixtures, in Azeotropiya i poliazetropiya (Azeotropy and Polyzeotropy), Sventoslavskii, V.V., Ed., Moscow: Khimiya, 1968, ch. XXI, pp. 1394-1403.
35. Timofeev, V.S. and Serafimov, L.A., Printsipy tekhnologii osnovnogo organicheskogo i neftekhimicheskogo sinteza (Principles of Basic Organic and Petrochemical Synthesis Technology), Moscow: Vysshaya Shkola, 2003.
36. Kogan, V.B., Azeotropnaya i ekstraktivnaya rektifikatsiya (Azeotropic and Extractive Distillation), Leningrad: Khimiya, 1971.
37. L.A. Serafimov A.K. Frolkova D.I. Bushina 2008 Extractive Distillation of Binary Azeotropic Mixtures Teor. Osn. Khim. Tekhnol. 42 5 521 530
38. Theor. Found. Chem. Eng. (Engl. Transl.), vol. 42, no. 5, pp. 507-516
39. R.R. Brito M.R.W. Maciel A.A. Meirelles 1997 New Extractive Distillation Configuration for Separating Binary Azeotropic Mixtures The First European Congress on Chemical Engineering, Florence, Italy 2 1333 1336
40. C. Hua X. Li S. Xu P. Bai 2007 Design and Operation of Batch Extractive Distillation with Two Reboilers Chin. J. Chem. Eng. 15 2 286 290 10.1016/S1004-9541(07)60072-X 1:CAS:528:DC%2BD2sXls1WqtL4%3D (Pubitemid 46710439)
41. Kotai, B., Lang, P., and Modla, G., Batch Extractive Distillation As Hybrid Process: Separation of Minimum Boiling Azeotropes, Chem. Eng. Sci., 2007, vol. 2.
42. Anokhina, E., Grigorieva, A., and Timoshenko, A., Ethanol Dehydration in the Complex Column with Refining Side Section, Proc. 35th Int. Conf. of Slovak Society of Chemical Engineering, Tatranske Matliare, Slovakia, 2008, p. 171.
43. M. Seiler D. Kohler W. Arlt 2003 Hyperbranched Polymers: New Selective Solvents for Extractive Distillation and Solvent Extraction Sep. Purif. Technol. 30 2 179 197 10.1016/S1383-5866(02)00197-1 1:CAS:528:DC%2BD3sXmvFyq
44. J. Zhao C.-C. Dong C.-X. Li, et al. 2006 Isobaric Vapor-Liquid Equilibria for Ethanol-Water System Containing Different Ionic Liquids at Atmospheric Pressure Fluid Phase Equilib. 242 2 147 153 10.1016/j.fluid.2006.01.023 1:CAS:528:DC%2BD28XisFerurY%3D
45. X.-C. Jiang J.-F. Wang C.-X. Li, et al. 2007 Vapor Pressure Measurement for Binary and Ternary Systems Containing Methanol, Ethanol and Ionic Liquid 1-Ethyl-3-Ethylimidazolium Diethylphosphate J. Chem. Thermodyn. 39 6 841 846 10.1016/j.jct.2006.11.013 1:CAS:528:DC%2BD2sXks12ht7c%3D (Pubitemid 46617549)
46. N. Calvar B. Gonzalez E. Gomez A. Dominguez 2007 Study of the Behaviour of the Azeotropic Mixture Ethanol-Water with Imidazolium-Based Ionic Liquids Fluid Phase Equilib. 259 1 51 56 10.1016/j.fluid.2007.03.021 1:CAS:528:DC%2BD2sXovFSls7w%3D (Pubitemid 47214655)
47. J.-F. Wang C.-X. Li Z.-H. Wang, et al. 2007 Vapor Pressure Measurement for Water, Methanol, Ethanol, and Their Binary Mixtures in the Presence of an Ionic Liquid 1-Ethyl-3-Methylimidazolium Dimethylphosphate Fluid Phase Equilib. 255 2 186 192 10.1016/j.fluid.2007.04.010 1:CAS:528:DC%2BD2sXmtVSrsb8%3D (Pubitemid 46810165)
48. Z. Jin J. Xiao-Chuan L. Chun-Xi W. Zi-Hao 2006 Vapor Pressure Measurement for Binary and Ternary Systems Containing a Phosphoric Ionic Liquid Fluid Phase Equilib. 247 s.1-2 190 198
49. Y. Ge L. Zhang X. Yuan, et al. 2008 Selection of Ionic Liquids as Entrainers for Separation of (Water + Ethanol) J. Chem. Thermodyn. 40 8 1248 1252 10.1016/j.jct.2008.03.016 1:CAS:528:DC%2BD1cXovFyiur0%3D
50. W. Jun-Feng L. Chun-Xi W. Zi-Hao 2007 Measurement and Prediction of Vapor Pressure of Binary and Ternary Systems Containing 1-Ethyl-3-Methylimidazolium Ethyl Sulfate J. Chem. Eng. Data 52 4 1307 1312 10.1021/je700038w (Pubitemid 47218441)
51. N. Calvar B. Gonzalez E. Gomez A. Dominguez 2008 Vapor-Liquid Equilibria for Ternary System Ethanol + Water + 1-Ethyl-3-Methylimidazolium Ethyl Sulfate and Corresponding Binary Systems Containing the Ionic Liquids at 101.3 kPa J. Chem. Eng. Data 53 3 820 825 10.1021/je700710d 1:CAS:528:DC%2BD1cXit1yjur4%3D
52. L.D. Simoni Y. Lin J.F. Brennecke M.A. Stadtherr 2008 Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC Ind. Eng. Chem. Res. 47 1 256 272 10.1021/ie070956j 1:CAS:528:DC%2BD2sXhtlyjsbvE (Pubitemid 351147661)
53. J.L. Torres H.E. Grenhlein L.R. Lynd 1989 Computer Simulation of the Dartmouth Process for Separation of Dilute Ethanol/Water Mixtures Appl. Biochem. Biotechnol. 20/21 621 633 10.1007/BF02936513
54. R.T.P. Pinto M.R. Wolf-Maciel L. Lintome 2000 Saline Extractive Distillation Process for Ethanol Purification Comput. Chem. Eng. 24 2 1689 1694 10.1016/S0098-1354(00)00455-5 1:CAS:528:DC%2BD3cXlsVeqt7Y%3D (Pubitemid 30608416)
55. E.L. Ligero T.M.K. Ravagnani 2002 Simulation of Salt Extractive Distillation with Spray Dryer Salt Recovery for Anhydrous Ethanol Production J. Chem. Eng. Jpn. 35 6 557 563 10.1252/jcej.35.557 1:CAS:528:DC%2BD38XkvFOls70%3D (Pubitemid 34817252)
56. M. Llano-Restrepo J. Aguilar-Arias 2003 Modeling and Simulation of Saline Extractive Distillation Columns for the Production of Absolute Ethanol Comput. Chem. Eng. 27 4 527 549 10.1016/S0098-1354(02)00215-6 1:CAS:528: DC%2BD3sXhsFOhsbw%3D (Pubitemid 36343086)
57. E.L. Ligero T.M.K. Ravagnani 2003 Dehydration of Ethanol with Salt Extractive Distillation-A Comparative Analysis between Processes with Salt Recovery Chem. Eng. Process. 42 7 543 552 10.1016/S0255-2701(02)00075-2 1:CAS:528:DC%2BD3sXis12mt78%3D (Pubitemid 36453949)
58. L. Zhigang W. Hongyou Z. Rongqi D. Zhanting 2002 Influence of Salt Added to Solvent on Extractive Distillation Chem. Eng. J. 87 2 149 156 10.1016/S1385-8947(01)00211-X (Pubitemid 34817236)
59. I.D. Gil A.M. Uyazan J.L. Aguilar, et al. 2008 Separation of Ethanol and Water by Extractive Distillation with Salt and Solvent As Entrainer: Process Simulation Braz. J. Chem. Eng. 25 1 207 215 10.1590/S0104-66322008000100021 1:CAS:528:DC%2BD1cXntVSnur4%3D
60. Hilmen, E.-K., Separation of Azeotropic Mixtures: Tools for Analysis and Studies on Batch Distillation Operation, Thesis Submitted for the Degree of Dr. Eng., Norwegian University of Science and Technology, Department of Chemical Engineering, 2001.
61. C.J.G. Vasconcelos M.R. Wolf-Maciel 2000 Dynamic and Control of High Purity Heterogeneous Azeotropic Distillation Process Comput. Aided Chem. Eng. 8 217 222 10.1016/S1570-7946(00)80038-3 1:CAS:528:DC%2BD3cXksFykurs%3D
62. Zielinski, L., Bioethanol Dehydration in Pressure Swing Adsorption Proces, www.msuil.ru/unesco.forum.doc1/17doc
63. K. Koczka P. Mizsey Z. Fonyo 2007 Rigorous Modelling and Optimization of Hybrid Separation Processes Based on Pervaporation Central Eur. J. Chem. 5 4 1124 1147 10.2478/s11532-007-0050-8 1:CAS:528:DC%2BD1cXotlKmsA%3D%3D
64. V.V. Kafarov L.S. Gordeev M.B. Glebov 1996 Separation of Azeotropic Mixtures in Membrane-Rectification Processes Teor. Osn. Khim. Tekhnol. 30 2 180 187 1:CAS:528:DyaK28XitlSis7k%3D
65. Theor. Found. Chem. Eng. (Engl. Transl.), vol. 30, no. 2, pp. 160-167
66. Z. Olujic P. Perez F.T. De Bruijn, et al. 2006 Augmenting Distillation by Membranes: Developments and Prospects Chem. Biochem. Eng. Q 203 301 318
67. Z. Szitkai Z. Lelkes E. Rev Z. Fonyo 2002 Optimization of Hybrid Ethanol Dehydration Systems Chem. Eng. Process. 41 7 631 646 10.1016/S0255-2701(01) 00192-1 1:CAS:528:DC%2BD38XktFOru7w%3D (Pubitemid 34776230)
68. M.T. Del Pozo Gomez A. Klein J.-U. Repke G. Wozny 2008 A New Energy-Integrated Pervaporation Distillation Approach Desalination 224 s.1-3 28 33
69. Bologa, M.K. and Maksimuk, E.P., Recovery of Process Liquids in an Electric Field, Int. Conf. Fizikar 2005, Baku, 2005, no. 114, p. 430.
70. Banat Fawzi, A., Abu Al-Rub Fahmi, A., and Simandl Jana, Analysis of VaporLiquid Equilibrium of Etha-nolWater System via Headspace Gas Chromatogra-phy: Effect of Molecular Sieves, Sep. Purif. Technol., 2000, vol. 18, no. 2, pp. 111118. (Pubitemid 30213653)
71. R. Ohashi Y. Kamoshita M. Kishimoto T. Suzuki 1998 Continuous Production and Separation of Ethanol without Effluence of Waste-Water Using a Distiller Integrated SCM-Reactor System J. Ferment. Bioeng. 86 2 220 225 10.1016/S0922-338X(98)80117-7 1:CAS:528:DyaK1cXms1eksbw%3D (Pubitemid 28427734)
72. A. Kaseno I. Miyazawa T. Kokugan 1998 Effect of Product Removal by a Pervaporation on Ethanol Fermentation J. Ferment. Bioeng. 86 5 488 493 10.1016/S0922-338X(98)80157-8 1:CAS:528:DyaK1MXhvVOhtL0%3D (Pubitemid 29008738)
73. R.L. Calibo M. Matsumura H. Kataoka 1989 Continuous Ethanol Fermentation of Concentrated Sugar Solutions Coupled with Membrane Distillation Using a PTFE Module J. Ferment. Bioeng. 67 1 40 45 10.1016/0922-338X(89)90084-6 1:CAS:528:DyaL1MXhvFWhsrw%3D
74. K. Kargupta S. Datta S.K. Sanyal 1998 Analysis of the Performance of a Continuous Membrane Bioreactor with Cell Recycling during Ethanol Fermentation Biochem. Eng. J. 1 1 31 37 10.1016/S1369-703X(97)00006-5 1:CAS:528: DyaK1cXjsFSnsb8%3D
75. K. Ghosh K.B. Ramachandran 2007 Analysis of the Effect of In Situ Product Removal on the Stability and Performance of a Continuous Bioreactor with Cell Separator for Ethanol Production Chem. Biochem. Eng. Q. 21 3 285 296 1:CAS:528:DC%2BD2sXht1ersLrO
76. A.G. Moura J.R. Medeiros 2008 Applying Consistent Technology for Fuel Ethanol Production Sugar Technol. 10 1 20 24 10.1007/s12355-008-0003-3 1:CAS:528:DC%2BD1cXhsV2ht7bF
77. V. Van Hoof L. Abeele A. Buekenhoudt, et al. 2004 Economic Comparison between Azeotropic Distillation and Hybrid Systems Combining Distillation with Pervaporation for the Dehydration of Isopropanol Sep. Purif. Technol. 37 1 33 49 10.1016/j.seppur.2003.08.003