The feasibility study of crude palm oil transesterification at 30°C operation

Bioresource Technology

Volumn 101, Issue 23, 2010, Pages 8948-8954

  Sim, Jia Huey ^a   Kamaruddin, Azlina Harun ^a   Bhatia, Subhash ^a  

^a SCHOOL OF CHEMICAL ENGINEERING   (Malaysia)

Author keywords

Fatty acid methyl ester (FAME); Lipase; Process parameters; Statistical analysis; Transesterification

Indexed keywords

AGITATION SPEED; BIODIESEL SYNTHESIS; CRUDE PALM OIL; ENZYME LOADING; FATTY ACID METHYL ESTER; FEASIBILITY STUDIES; MASS TRANSFER EFFECTS; MASS TRANSFER LIMITATION; MOLAR RATIO; OPTIMUM OPERATING CONDITIONS; PROCESS PARAMETERS; REACTION TIME; STATISTICAL ANALYSIS;

ACIDS; BIODIESEL; ENZYMES; ESTERIFICATION; ESTERS; FATTY ACIDS; MASS TRANSFER; METHANOL; STATISTICAL METHODS; SYNTHESIS (CHEMICAL); SYNTHETIC FUELS; VEGETABLE OILS;

TRANSESTERIFICATION;

BIODIESEL; METHANOL; PALM OIL;

BIOFUEL; ENZYME ACTIVITY; FATTY ACID; MASS TRANSFER; METHANOL; OPTIMIZATION; REACTION RATE; STATISTICAL ANALYSIS; SUBSTRATE; VEGETABLE OIL; VISCOSITY;

ARTICLE; FEASIBILITY STUDY; PRIORITY JOURNAL; PROCESS OPTIMIZATION; REACTION TIME; SYNTHESIS; TRANSESTERIFICATION; VISCOSITY;

ANALYSIS OF VARIANCE; BIOTECHNOLOGY; ESTERIFICATION; ESTERS; FEASIBILITY STUDIES; KINETICS; LIPASE; MODELS, CHEMICAL; PLANT OILS; TEMPERATURE;

EID: 77955661976     PISSN: 09608524     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.biortech.2010.07.039     Document Type: Article

References (24)

1. Abdullah A.Z., Razali N., Lee K.T. Optimization of mesoporous K/SBA-15 catalyzed transesterification of palm oil using response surface methodology. Fuel Process. Technol. 2009, 90:958-964.
2. Bambase M.E., Nakamura N., Tanaka J., Matsumura M. Kinetics of hydroxide-catalyzed methanolysis of crude sunflower oil for the production of fuel-graded methyl esters. J. Chem. Technol. Biotechnol. 2007, 82(3):273-280.
3. Bezbradica D., Karalazić I., Ognjanović N., Mijin D., Śiler-Marinković S., Kneźević Z. Studies on the specificity of Candida rugosa lipase catalyzed esterification reactions in organic media. J. Serb. Chem. Soc. 2006, 71(1):31-41.
4. Chen X., Du W., Liu D. Response surface optimization of biocatalytic biodiesel production with acid oil. Biochem. Eng. J. 2008, 40(3):423-429.
5. Deng L., Xu X.B., Haraldsson G.G., Tan T.W., Wang F. Enzymatic production of alkyl esters through alcoholysis: a critical evaluation of lipases and alcohols. J. Am. Oil Chem. Soc. 2005, 82(5):341-347.
6. Du W., Xu Y., Liu D. Lipase-catalysed transesterification of soya bean oil for biodiesel production during continuous batch operation. Biotechnol. Appl. Biochem. 2003, 38:103-106.
7. Fjerbaek L., Christensen K.V., Norddahl B. A review of the current state of biodiesel production using enzymatic transesterification. Biotechnol. Bioeng. 2009, 102(5):1298-1315.
8. Halim S.F.A., Harun Kamaruddin A. Catalytic studies of lipase on FAME production from waste cooking palm oil in a t-butanol system. Process Biochem. 2008, 43(12):1436-1439.
9. Iso M., Chen B., Eguchi M., Kudo T., Shrestha S. Production of biodiesel fuel from triglycerides and alcohol using immobilized lipase. J. Mol. Catal. B: Enzym. 2001, 16(1):53-58.
10. Jeong G.T., Yang H.S., Park D.H. Optimization of transesterification of animal fat ester using response surface methodology. Bioresour. Technol. 2009, 100(1):25-30.
11. Krawczyk T. Biodiesel-alternative fuel makes inroads but hurdle remain. Inform 1996, 7:801-829.
12. Köse Ö., Tüter M., Aksoy H.A. Immobilized Candida antarctica lipase-catalyzed alcoholysis of cotton seed oil in a solvent-free medium. Bioresour. Technol. 2002, 83(2):125-129.
13. Li L., Du W., Liu D., Wang L., Li Z. Lipase-catalyzed transesterification of rapeseed oils for biodiesel production with a novel organic solvent as the reaction medium. J. Mol. Catal. B: Enzym. 2006, 43(4):58-62.
14. Nie K., Xie F., Wang F., Tan T. Lipase catalyzed methanolysis to produce biodiesel: optimization of the biodiesel production. J. Mol. Catal. B: Enzym. 2006, 43(4):142-147.
15. Ognjanović N., Bezbradica D., Kneźević Z. Optimization of the production of biodiesel by a commercial immobilized lipase in a solvent-free system using a response surface methodology. J. Serb. Chem. Soc. 2008, 73(2):147-156.
16. Santos A.M.P., Oliveira M.G., Maugeri F. Modelling thermal stability and activity of free and immobilized enzymes as a novel tool for enzyme reactor design. Bioresour. Technol. 2007, 98(16):3142-3148.
17. Shah S., Gupta M.N. Lipase catalyzed preparation of biodiesel from Jatropha oil in a solvent free system. Process Biochem. 2007, 42(3):409-414.
18. Sim J.H., Kamaruddin A.H., Bhatia S. Effect of mass transfer and enzyme loading on the biodiesel yield and reaction rate in the enzymatic transesterification of crude palm oil. Energy Fuels 2009, 23:4651-4658.
19. Szczesna Antczak M., Kubiak A., Antczak T., Bielecki S. Enzymatic biodiesel synthesis - key factors affecting efficiency of the process. Renew. Energy 2009, 34(5):1185-1194.
20. Talukder M.M.R., Wu J.C., Van Nguyen T.B., Fen N.M., Melissa Y.L.S. Novozym 435 for production of biodiesel from unrefined palm oil: comparison of methanolysis methods. J. Mol. Catal. B: Enzym. 2009, 60:106-112.
21. Wang Y., Wu H., Zong M.H. Improvement of biodiesel production by lipozyme TL IM-catalyzed methanolysis using response surface methodology and acyl migration enhancer. Bioresour. Technol. 2008, 99(15):7232-7237.
22. Watanabe Y., Shimada Y., Sugihara A., Tominaga Y. Conversion of degummed soybean oil to biodiesel fuel with immobilized Candida antarctica lipase. J. Mol. Catal. B: Enzym. 2002, 17(5):151-155.
23. Watanabe Y., Shimada Y., Sugihara A., Noda H., Fukuda H., Tominaga Y. Continuous production of biodiesel fuel from vegetable oil using immobilized Candida antarctica lipase. J. Am. Oil Chem. Soc. 2000, 77(4):355-360.
24. Xiong J., Wu J., Xu G., Yang L. Kinetic study of lipase catalyzed asymmetric transesterification of mandelonitrile in solvent-free system. Chem. Eng. J. 2008, 138(3):258-263.