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Volumn , Issue 23, 2010, Pages 4372-4375

Inductively heated oxides inside microreactors - Facile oxidations under flow conditions

Author keywords

Inductive heating; Metal oxides; Microreactors; Oxidation

Indexed keywords


EID: 77955368979     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.201000628     Document Type: Article
Times cited : (37)

References (39)
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    • Enabling technologies include techniques such as nonconventional heating, solid-phase assistance and new reactor designs. They allow carrying out syntheses faster and performing workup more efficiently. We first reviewed and defined enabling technologies for organic synthesis in: A. Kirschning, W. Solodenko, K. Mennecke, Chem. Eur. J. 2006, 12, 5972-5990.
    • (2006) Chem. Eur. J , vol.12 , pp. 5972-5990
    • Kirschning, A.1    Solodenko, W.2    Mennecke, K.3
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    • [1])
    • [1]).
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    • 77955363346 scopus 로고    scopus 로고
    • For All Reactions Described, Leaching Values Were Determined for Fe, Cr and Ni, Respectively, by Using ICP-OES Analysis: Average Values for Fe: 4.15 Ppm; Cr: 1.75 Ppm; Ni: 0.15 Ppm
    • For all reactions described, leaching values were determined for Fe, Cr and Ni, respectively, by using ICP-OES analysis: Average values for Fe: 4.15 ppm; Cr: 1.75 ppm; Ni: 0.15 ppm.
  • 12
    • 0345732180 scopus 로고    scopus 로고
    • Selected reviews on chemically functionalized flow-through systems: a) G. Jas, A. Kirschning, Chem. Eur. J. 2003, 9, 5708-5723;
    • (2003) Chem. Eur. J , vol.9 , pp. 5708-5723
    • Jas, G.1    Kirschning, A.2
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    • (Ed.: M. Benaglia), John Wiley & Sons Ltd., Chichester, chapter 13
    • j) S. Ceylan, A. Kirschning in Recoverable and Recyclable Catalysts (Ed.: M. Benaglia), John Wiley & Sons Ltd., Chichester, 2009, chapter 13, pp. 379 - 411.
    • (2009) Recoverable and Recyclable Catalysts , pp. 379-411
    • Ceylan, S.1    Kirschning, A.2
  • 22
    • 0343145601 scopus 로고    scopus 로고
    • for MagTrieve™;
    • When two identical fixed-bed reactors are employed in a parallel setup, the flow can be switched to the second reactor once the oxidant inside the first flow reactor is exhausted. This reactor can then be reactivated; see also: R. Lee, D. Donald, Tetrahedron Lett. 1997, 38, 3857 - 3860 for MagTrieve™;
    • (1997) Tetrahedron Lett. , vol.38 , pp. 3857-3860
    • Lee, R.1    Donald, D.2
  • 23
    • 33947479742 scopus 로고
    • 2. In an integrated, flow system the LC-online determination can be used to determine, when the oxidant is exhausted, and the reactor has to be exchanged
    • 2. In an integrated, flow system the LC-online determination can be used to determine, when the oxidant is exhausted, and the reactor has to be exchanged.
    • (1962) J. Org. Chem. , vol.27 , pp. 1597-1601
    • Naka- Gawa, K.1    Konaka, R.2    Nakata, T.3
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    • [1])
    • [1]).
  • 25
    • 77955365079 scopus 로고    scopus 로고
    • It has to be noted, that the stream of reactants is rapidly heated within the first cm of the reactor until the solution reaches the desired temperature. After that first zone dispersion is kept to a minimum. Furthermore, the design of the inductor allowed maximum homogeneity of the magnetic field inside the flow reactor, which guarantees homogeneous heating conditions all through the reactor
    • It has to be noted, that the stream of reactants is rapidly heated within the first cm of the reactor until the solution reaches the desired temperature. After that first zone dispersion is kept to a minimum. Furthermore, the design of the inductor allowed maximum homogeneity of the magnetic field inside the flow reactor, which guarantees homogeneous heating conditions all through the reactor.
  • 32
    • 77955394802 scopus 로고    scopus 로고
    • 3-phenylpropenai
    • c) 3-phenylpropenai
  • 34
    • 77955398437 scopus 로고    scopus 로고
    • 2-methoxybenzonitrile
    • d.) 2-methoxybenzonitrile
  • 36
    • 77955376014 scopus 로고    scopus 로고
    • 3,4-dimethoxybenzonitrile
    • e) 3,4-dimethoxybenzonitrile
  • 38
    • 77955370435 scopus 로고    scopus 로고
    • 2-phenylchrornen-4-oňe
    • f) 2-phenylchrornen-4-oňe


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.