Infrared spectra of HCl-H2O clusters in helium nanodroplets

Journal of Physical Chemistry Letters

Volumn 1, Issue 15, 2010, Pages 2233-2238

  Flynn, Steven D ^a   Skvortsov, Dmitry ^b   Morrison, Alexander M ^a   Liang, Tao ^a   Choi, Myong Yong ^b,c   Douberly, Gary E ^a   Vilesov, Andrey F ^b  

^a UNIVERSITY OF GEORGIA   (United States)

^b UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

^c Gyeongsang National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

CLUSTER-BASED; HELIUM NANODROPLETS; INFRARED SPECTRUM; ION PAIRS; MIXED CLUSTERS; PRESSURE DEPENDENCE; SPECTRAL BROADENING; STRETCH VIBRATIONS; TRANSITION MOMENTS; VIBRATIONAL BANDS; WATER MOLECULE;

DROP FORMATION; HELIUM;

INFRARED SPECTROSCOPY;

EID: 77955345536     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz100637m     Document Type: Article

References (36)

1. n HCl, n = 1-3 J. Phys. Chem. 1995, 99, 14323-14333
2. n (n = 3, 4) Clusters J. Phys. Chem. A 1999, 103, 4631-4640
3. 4: Cluster Model of the Photodetachment of the Chloride Anion in Water J. Phys. Chem. A 2003, 107, 1557-1562
4. 4, M = H, Li, Na Clusters: Finite-Size Models of the Photodetachment of the Chloride Anion in Salt Solutions Phys. Chem. Chem. Phys. 2005, 7, 970-974
5. Svanberg, M.; Pettersson, J. B. C.; Bolton, K. Coupled QM/MM Molecular Dynamics Simulations of HCl Interacting with Ice Surfaces and Water Clusters: Evidence of Rapid Ionization J. Phys. Chem. A 2000, 104, 5787-5798
6. Buch, V.; Sadlej, J.; Aytemiz-Uras, N.; Devlin, J. P. Solvation and Ionization Stages of HCI on Ice Nanocrystals J. Phys. Chem. A 2002, 106, 9374-9389
7. n, n = 1-4 J. Chem. Phys. 2003, 119, 11695-11703
8. n clusters: Consequences or anharmonic vibrational spectroscopy J. Phys. Chem. A 2001, 105, 8323-32
9. Ault, B. S.; Pimentel, G. C. Infrared-Spectrum of Water Hydrochloric Acid Complex in Solid Nitrogen J. Phys. Chem. 1973, 77, 57-61
10. Schriver, A.; Silvi, B.; Maillard, D.; Perchard, J. P. Structure of Water Hydrochloric Acid Complexes in Argon and Nitrogen Matrices from IR-Spectra J. Phys. Chem. 1977, 81, 2095-2102
11. Amirand, C.; Maillard, D. Spectrum and Structure of Water-Rich Water-Hydracid Complexes from Matrix Isolation Spectroscopy: Evidence for Proton Transfer J. Mol. Struct. 1988, 176, 181-201
12. Farnik, M.; Weimann, M.; Suhm, M. A. Acidic Protons before Take-off: A Comparative Jet Fourier Transform Infrared Study of Small Hcl- And Hbr-Solvent Complexes J. Chem. Phys. 2003, 118, 10120-10136
13. Devlin, J. P.; Farnik, M.; Suhm, M. A.; Buch, V. Comparative FTIR Spectroscopy of HX Adsorbed on Solid Water: Ragout-Jet Water Clusters vs Ice Nanocrystal Arrays J. Phys. Chem. A 2005, 109, 955-958
14. Weimann, M.; Farnik, M.; Suhm, M. A. A First Glimpse at the Acidic Proton Vibrations in HCl-Water Clusters via Supersonic Jet FTIR Spectroscopy Phys. Chem. Chem. Phys. 2002, 4, 3933-3937
15. 4 Below 1 K: The Smallest Droplet of Acid Science 2009, 324, 1545-1548
16. Zwier, T. S. Squeezing the Water Out of HCl(aq) Science 2009, 324, 1522-1523
17. 1-3, in Helium Nanodroplets: Studies of Free OH Vibrational Stretching Modes J. Phys. Chem. A 2009, 113, 7360-7365
18. Choi, M. Y.; Douberly, G. E.; Falconer, T. M.; Lewis, W. K.; Lindsay, C. M.; Merritt, J. M.; Stiles, P. L.; Miller, R. E. Infrared Spectroscopy of Helium Nanodroplets: Novel Methods for Physics and Chemistry Int. Rev. Phys. Chem. 2006, 25, 15-75
19. Callegari, C.; Lehmann, K. K.; Schmied, R.; Scoles, G. Helium Nanodroplet Isolation Rovibrational Spectroscopy: Methods and Recent Results J. Chem. Phys. 2001, 115, 10090-10110
20. Toennies, J. P.; Vilesov, A. F. Superfluid Helium Droplets: A Uniquely Cold Nanomatrix for Molecules and Molecular Complexes Angew. Chem., Int. Ed. 2004, 43, 2622-2648
21. Stienkemeier, F.; Lehmann, K. K. Spectroscopy and Dynamics in Helium Nanodroplets J. Phys. B: At. Mol. Opt. Phys. 2006, 39, R127-R66
22. Slipchenko, M.; Kuyanov, K.; Sartakov, B.; Vilesov, A. F. Infrared Intensity in Small Ammonia and Water Clusters J. Chem. Phys. 2006, 124, 241101/1-241101/4
23. Skvortsov, D.; Choi, M. Y.; Vilesov, A. F. Study of HCl Clusters in Helium Nanodroplets: Experiments and Ab Initio Calculations as Stepping Stones from Gas Phase to Bulk J. Phys. Chem. A 2007, 111, 12711-12716
24. 3-Bands of Water J. Phys. Chem. A 2006, 33, 10046-10052
25. Toennies, J. P.; Vilesov, A. F. Spectroscopy of Atoms and Molecules in Liquid Helium Annu. Rev. Phys. Chem. 1998, 49, 1-41
26. 2O-HCl in Liquid Helium Nanodroplets J. Phys. Chem. A. 2007, 111, 12192-12199
27. Lewerenz, M.; Schilling, B.; Toennies, J. P. Successive Capture and Coagulation of Atoms and Molecules to Small Clusters in Large Liquid Helium Clusters J. Chem. Phys. 1995, 102, 8191-8207
28. Kong, W.; Bulthuis, J. Orientation of Asymmetric Top Molecules in a Uniform Electric Field: Calculations for Species without Symmetry Axes J. Phys. Chem. A 2000, 104, 1055-1063
29. Franks, K. J.; Li, H. Z.; Kong, W. Orientation of Pyrimidine in the Gas Phase Using a Strong Electric Field: Spectroscopy and Relaxation Dynamics J. Chem. Phys. 1999, 110, 11779-11788
30. 4He Droplets J. Chem. Phys. 2000, 112, 4485-4495
31. Nauta, K.; Miller, R. E. Formation of Cyclic Water Hexamer in Liquid Helium: The Smallest Piece of Ice Science 2000, 287, 293-295
32. Slipchenko, M. N.; Sartakov, B. G.; Vilesov, A. F.; Xantheas, S. S. Study of NH Stretching Vibrations in Small Ammonia Clusters by Infrared Spectroscopy in He Droplets and Ab Initio Calculations J. Phys. Chem. A 2007, 111, 7460-7471
33. Devlin, J. P.; Uras, N.; Sadlej, J.; Buch, V. Discrete Stages in the Solvation and Ionization of Hydrogen Chloride Adsorbed on Ice Particles Nature 2002, 417, 269-271
34. Martin-Llorente, B.; Fernandez-Torre, D.; Herrero, V. J. Vibrational Spectra of Crystalline Hydrates of Atmospheric Relevance: Bands of Hydrated Protons Chem. Phys. Lett. 2006, 427, 300-304
35. Masia, M.; Forbert, H.; Marx, D. Connecting Structure to Infrared Spectra of Molecular and Autodissociated HCl-Water Aggregates J. Phys. Chem. A 2007, 111, 12181-12191
36. Headrick, J. M.; Diken, E. G.; Walters, R. S.; Hammer, N. I.; Christie, R. A.; Cui, J.; Myshakin, E. M.; Duncan, M. A.; Johnson, M. A.; Jordan, K. D. Spectral Signatures of Hydrated Proton Vibrations in Water Clusters Science 2005, 308, 1765-1769