Aggregation-induced dissociation of HCl(H 2O) 4 below 1 K: The smallest droplet of acid

Science

Volumn 324, Issue 5934, 2009, Pages 1545-1548

  Gutberlet, Anna ^a   Schwaab, Gerhard ^a   Birer, Özgür ^a,b   Masia, Marco ^a,c   Kaczmarek, Anna ^a,d   Forbert, Harald ^a   Havenith, Martina ^a   Marx, Dominik ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

^b KOÇ UNIVERSITY   (Turkey)

^c UNIVERSITY OF SASSARI   (Italy)

^d NICOLAUS COPERNICUS UNIVERSITY   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

ACID; CHLORIDE; HELIUM; HYDRONIUM ION; WATER;

HELIUM; HYDROCHLORIC ACID; INFRARED SPECTROSCOPY; LOW TEMPERATURE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL PARAMETERS; DISSOCIATION; ELECTRICITY; INFRARED SPECTROSCOPY; INTERNATIONAL STANDARD UNIT; MOLECULE; PRIORITY JOURNAL; SIMULATION;

EID: 67649231737     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1171753     Document Type: Article

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42. The authors are grateful to W. Sander for helpful discussions and K. Merz for support in the synthesis of isotopically pure HCl. We thank D. Habig, S. Henkel, M. Ortlieb, and T. Poerschke for help with the experiment and data evaluation. Support by the Deutsche Forschungsgemeinschaft (grants HA 2394/13 and MA 1547/8 within FOR 618 WMolecular AggregationW) and Fonds der Chemischen Industrie is gratefully acknowledged, as well as computer resources from Bovilab@RUB and Rechnerverbund-Nordrhein-Westfalen (LiDO).