Thermodynamic study of the solubility of procaine HCl in some ethanol + water cosolvent mixtures

Journal of Chemical and Engineering Data

Volumn 55, Issue 8, 2010, Pages 2900-2904

  Delgado, Daniel R ^a   Vargas, Edgar F ^b   Martinez, Fleming ^a  

^a UNIVERSIDAD NACIONAL DE COLOMBIA   (Colombia)

^b UNIVERSIDAD DE LOS ANDES   (Colombia)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; ELECTROLYTES; ENTHALPY; ENTROPY; ETHANOL; MIXTURES; SOLUBILITY;

COSOLVENT EFFECTS; COSOLVENT MIXTURES; DISSOLUTION PROCESS; ENTHALPY-ENTROPY COMPENSATION; ETHANOL + WATERS; THERMODYNAMIC FUNCTIONS; THERMODYNAMIC STUDIES; TRANSFER PROPERTIES;

DRUG DELIVERY;

EID: 77955107663     PISSN: 00219568     EISSN: 15205134     Source Type: Journal    
DOI: 10.1021/je900958z     Document Type: Article

References (26)

1. White, H. S. Remington: The Science and Practice of Pharmacy, 20th ed.; Gennaro, A. R., Ed.; Lippincott Williams & Wilkins: Philadelphia, PA, 2000; pp 1400-1406.
2. Dosch, M. P. Atlas of Neural Therapy with Local Anesthetics, 2nd ed.; Georg Thieme Verlag: Stuttgart, 2003.
3. Labastidas, I.; Martínez, F. Aspectos termodinámicos de la solubilidad acuosa de algunas sales orgánicas de interés farmacéutico. Acta Farm. Bonaerense 2006, 25, 55-63.
4. Torres, D. R.; Blanco, L. H.; Vargas, E. F.; Martínez, F. Calorimetric enthalpies of solution for lidocaine-HCl and procaine-HCl in water at 298.15 K. J. Chem. Eng. Data 2009, 54, 786-790.
5. Avdeef, A.; Box, K. J.; Comer, J. E. A.; Hibbert, C.; Tam, K. Y. pH-Metric log P10. Determination of liposomal membrane-water partition coefficients of ionizable drugs. Pharm. Res. 1998, 15, 209-215.
6. Vilallonga, F. A.; Phillips, E. W. Surface activities of procaine, lidocaine, and tetracaine and their interaction energies with phospho- lipid monolayers. J. Pharm. Sci. 2006, 68, 314-316.
7. Torres, D. R.; Blanco, L. H.; Martínez, F.; Vargas, E. F. Apparent molal volumes of lidocaine-HCl and procaine-HCl in aqueous solution as a function of temperature. J. Chem. Eng. Data 2007, 52, 1700-1703.
8. Jiménez, J. A.; Martínez, F. Temperature dependence of solubility of acetaminophen in propylene glycol + ethanol mixtures. J. Solution Chem. 2006, 35, 335-352. (Pubitemid 43873231)
9. Rubino, J. T. Encyclopedia of Pharmaceutical Technology;
10. Swarbrick, J.; Boylan, J. C., Eds.; Marcel Dekker, Inc.: New York, 1988; Vol. 3, pp 375-398.
11. Yalkowsky, S. H. Solubility and Solubilization in Aqueous Media; American Chemical Society and Oxford University Press: New York, 1999; pp 91-134.
12. Pacheco, D. P.; Martínez, F. Thermodynamic analysis of the solubility of naproxen in ethanol + water cosolvent mixtures. Phys. Chem. Liq. 2007, 45, 581-595. (Pubitemid 47399976)
13. US Pharmacopeia, 23rd ed.; The United States Pharmacopeial Convention: Rockville, MD, 1994; pp 1297-1298.
14. Martin, A.; Bustamante, P.; Chun, A. H. C. Physical Pharmacy: Physical Chemical Principles in the Pharmaceutical Sciences, 4th ed.; Lea & Febiger: Philadelphia, PA, 1993.
15. Florence, A. T.; Atwood, D. Physicochemical Principles of Pharmacy, 3rd ed.; MacMillan Press Ltd.: London, 1998, pp 64-67.
16. Budavari, S.; O'Neil, M. J.; Smith, A.; Heckelman, P. E.; Obenchain, J. R., Jr.; Gallipeau, J. A. R.; D'Arecea, M. A. The Merck Index: An Encyclopedia ofChemicals, Drugs, and Biologicals, 13th ed.; Merck & Co., Inc.: Whitehouse Station, NJ, 2001; p 1387.
17. Aulton, M. E. Pharmaceutics: The Science ofDosage Forms Design, 2nd ed.; Churchill Livingstone: London, 2002; pp 309-322.
18. Klotz, I. M.; Rosenberg, R. M. Chemical Thermodynamics: Basic Theory and Methods, 6th ed.; John Wiley & Sons, Inc.: New York, 2000; pp 438-448.
19. Bevan, J.; Boerio-Goates, J. Chemical Thermodynamics: Principles and Applications; Academic Press: New York, 2000; pp 295- 301.
20. Connors, K. A. Thermodynamics of Pharmaceutical Systems: An Introduction for Students of Pharmacy; Wiley-Interscience: Hoboken, NJ, 2002; pp 96-105.
21. Krug, R. R.; Hunter, W. G.; Grieger, R. A. Enthalpy-entropy compensation. 2. Separation of the chemical from the statistical effects. J. Phys. Chem. 1976, 80, 2341-2351.
22. Bustamante, P.; Romero, S.; Peña, A.; Escalera, B.; Reillo, A. Enthalpy-entropy compensation for the solubility of drugs in solvent mixtures: paracetamol, acetanilide, and nalidixic acid in dioxane-water. J. Pharm. Sci. 1998, 87, 1590-1596.
23. Bevington, P. R. Data Reduction and Error Analysis for the Physical Sciences; McGraw-Hill Book Co.: New York, 1969; pp 56-91.
24. Perlovich, G. L.; Kurkov, S. V.; Kinchin, A. N.; Bauer-Brandl, A. Thermodynamics of solutions III: Comparison of the solvation of (+)- naproxen with other NSAIDs. Eur. J. Pharm. Biopharm. 2004, 57, 411-420.
25. Bustamante, P.; Romero, S.; Reillo, A. Thermodynamics of paracetamol in amphiprotic and amphiprotic-aprotic solvent mixtures. Pharm. Sci. 1995, 1, 505-507.
26. Tomlinson, E. Enthalpy-entropy compensation analysis of pharmaceutical, biochemical and biological systems. Int. J. Pharm. 1983, 13, 115-144.