Selective decomposition of formic acid on molybdenum carbide: A new reaction pathway

Journal of Catalysis

Volumn 269, Issue 1, 2010, Pages 33-43

  Flaherty, David W ^a   Berglund, Sean P ^a   Mullins, C Buddie ^a  

^a The University of Texas at Austin   (United States)

Author keywords

Carboxyl; Formate; Infrared spectroscopy; Selective dehydrogenation; Transition metal carbide

Indexed keywords

ACTIVE SITE; BOND CLEAVAGES; C-H BOND; C-O BOND CLEAVAGE; CARBON BLOCKS; CARBOXYL; DIRECT ACTIVATION; KINETIC ANALYSIS; MOLECULAR BEAM SCATTERING; MOLYBDENUM CARBIDE; MONODENTATES; REACTION PATHWAYS; REFLECTION ABSORPTION INFRARED SPECTROSCOPY; SELECTIVE DECOMPOSITION; TRANSITION METAL CARBIDE;

ABSORPTION SPECTROSCOPY; ACTIVATION ANALYSIS; ACTIVATION ENERGY; CARBIDES; DEHYDRATION; DEHYDROGENATION; DEWATERING; FORMIC ACID; MOLYBDENUM; ORGANIC ACIDS; TRANSITION METALS;

INFRARED SPECTROSCOPY;

EID: 77955095154     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2009.10.012     Document Type: Article

References (74)

1. Levy R.B., and Boudart M. Science 181 (1973) 547-549
2. In: Oyama S.T. (Ed). The Chemistry of Transition Metal Carbides and Nitrides (1996), Blackie Academic and Professional, London
3. Chen J.G., Frühberger B., Eng J.J., and Bent B.E. J. Mol. Catal. A 131 (1998) 285-299
4. Hwu H.H., and Chen J.G. Chem. Rev. 105 (2005) 185-212
5. Oyama S.T. Catal. Today 15 (1992) 179-200
6. Chen J.G. Chem. Rev. 96 (1996) 1477-1498
7. Patt J., Moon D.J., Phillips C., and Thompson L. Catal. Lett. 65 (2000) 193-195
8. Rebrov E.V., Kuznetsov S.A., De Croon M., and Schouten J.C. Catal. Today 125 (2007) 88-96
9. Moon D.J., and Ryu J.W. Catal. Lett. 92 (2004) 17-24
10. Nagai M., and Matsuda K. J. Catal. 238 (2006) 489-496
11. Liu P., and Rodriguez J.A. J. Phys. Chem. B 110 (2006) 19418-19425
12. G.B. Haxel, J.B. Hedrick, G.J. Orris, Rare Earth Elements - Critical Resources for High Technology, USGS Fact Sheets, U.S.G. Survey.
13. Rhee Y.W., Ha S.Y., and Masel R.I. J. Power Sources 117 (2003) 35-38
14. Rice C., Ha R.I., Masel R.I., Waszczuk P., Wieckowski A., and Barnard T. J. Power Sources 111 (2002) 83-89
15. Rice C., Ha S., Masel R.I., and Wieckowski A. J. Power Sources 115 (2003) 229-235
16. Waszczuk P., Barnard T.M., Rice C., Masel R.I., and Wieckowski A. Electrochem. Commun. 4 (2002) 599-603
17. Larsen R., Ha S., Zakzeski J., and Masel R.I. J. Power Sources 157 (2006) 78-84
18. Markovic N.M., and Ross P.N. Surf. Sci. Rep. 45 (2002) 117-229
19. Heo P., Nagao M., Sano M., and Hibino T. J. Electrochem. Soc. 154 (2007) B53-B56
20. Weigert E.C., Stottlemyer A.L., Zellner M.B., and Chen J.G.G. J. Phys. Chem. C 111 (2007) 14617-14620
21. Columbia M.R., and Thiel P.A. J. Electroanal. Chem. 369 (1994) 1-14
22. Benziger J.B., and Madix R.J. Surf. Sci. 79 (1979) 394-412
23. Falconer J.L., and Madix R.J. J. Catal. 51 (1978) 47-63
24. Yamakata A., Kubota J., Kondo J.N., Hirose C., Domen K., and Wakabayashi F. J. Phys. Chem. B 101 (1997) 5177-5181
25. Erley W., and Sander D. J. Vac. Sci. Technol., A 7 (1989) 2238-2244
26. Sun Y.K., and Weinberg W.H. J. Chem. Phys. 94 (1991) 4587-4599
27. Davis J.L., and Barteau M.A. Surf. Sci. 256 (1991) 50-66
28. Jeroro E., and Vohs J.M. Catal. Lett. 130 (2009) 271-277
29. Thomas F.S., and Masel R.I. Surf. Sci. 573 (2004) 169-175
30. Columbia M.R., Crabtree A.M., and Thiel P.A. J. Am. Chem. Soc. 114 (1992) 1231-1237
31. Avery N.R. Appl. Surf. Sci. 11-2 (1982) 774-783
32. Kizhakevariam N., and Stuve E.M. J. Vac. Sci. Technol., A 8 (1990) 2557-2562
33. Dahlberg S.C., Fisk G.A., and Rye R.R. J. Catal. 36 (1975) 224-234
34. Flaherty D.W., Hahn N.T., Ferrer D., Engstrom T.R., Tanaka P.L., and Mullins C.B. J. Phys. Chem. C 113 (2009) 9820-9825
35. Frühberger B., and Chen J.G. Surf. Sci. 342 (1995) 38-46
36. Frühberger B., and Chen J.G. J. Am. Chem. Soc. 118 (1996) 11599-11609
37. Hwu H.H., Zellner M.B., and Chen J.G. J. Catal. 229 (2005) 30-44
38. Wang J., Castonguay M., Deng J., and McBreen P.H. Surf. Sci. 374 (1997) 197-207
39. Colaianni M.L., Chen J.G., Weinberg W.H., and Yates J.T. J. Am. Chem. Soc. 114 (1992) 3735-3743
40. He J.W., Kuhn W.K., and Goodman D.W. Surf. Sci. 262 (1992) 351-358
41. Mikawa Y., Brasch J.W., and Jakobsen R.J. J. Mol. Spectrosc. 24 (1967) 314-329
42. Xu C., and Goodman D.W. J. Phys. Chem. 100 (1996) 1753-1760
43. Crowell J.E., Chen J.G., and Yates J.T. J. Chem. Phys. 85 (1986) 3111-3122
44. Sander D., and Erley W. J. Vac. Sci. Technol., A 8 (1990) 3357-3360
45. Barros R.B., Garcia A.R., and Ilharco L.M. Surf. Sci. 591 (2005) 142-152
46. Hwu H.H., and Chen J.G. Surf. Sci. 536 (2003) 75-87
47. Zaera F., Kollin E.B., and Gland J.L. Surf. Sci. 166 (1986) L149-L154
48. Okada M., Baddorf A.P., and Zehner D.M. Surf. Sci. 373 (1997) 145-152
49. Queeney K.T., and Friend C.M. J. Phys. Chem. B 102 (1998) 5178-5181
50. Bandara A., Kubota J., Wada A., Domen K., and Hirose C. J. Phys. Chem. 100 (1996) 14962-14968
51. Bandara A., Kubota J., Wada A., Domen K., and Hirose C. J. Phys. Chem. B 101 (1997) 361-368
52. Haq S., Love J.G., Sanders H.E., and King D.A. Surf. Sci. 325 (1995) 230-242
53. Avery N.R. Appl. Surf. Sci. 14 (1983) 149-156
54. Chen J.G., Colaianni M.L., Weinberg W.H., and Yates J.T. Chem. Phys. Lett. 177 (1991) 113-117
55. Jaworowski A.J., Smedh M., Borg M., Sandell A., Beutler A., Sorensen S.L., Lundgren E., and Andersen J.N. Surf. Sci. 492 (2001) 185-194
56. Hayden B.E., Prince K., Woodruff D.P., and Bradshaw A.M. Phys. Rev. Lett. 51 (1983) 475-478
57. Frühberger B., and Chen J.G. Surf. Sci. 342 (1995) 38-46
58. Chen J.G., and Frühberger B. Surf. Sci. 367 (1996) L102-L110
59. Pierson H.O. Handbook of Refractory Carbides and Nitrides: Properties, Characteristics, Processing and Applications (1996), Noyes Publications, Westwood, NJ
60. Kröger J., Lehwald S., and Ibach H. Phys. Rev. B: Condens. Matter 58 (1998) 1578
61. Xu C., and Goodman D.W. J. Am. Chem. Soc. 117 (1995) 12354-12355
62. Benziger J.B., Ko E.I., and Madix R.J. J. Catal. 54 (1978) 414-425
63. Benziger J.B., Ko E.I., and Madix R.J. J. Catal. 58 (1979) 149-153
64. Ko E.I., and Madix R.J. Appl. Surf. Sci. 3 (1979) 236-250
65. Madix R.J., Falconer J., and McCarty J. J. Catal. 31 (1973) 316-318
66. McCarty J., and Madix R.J. J. Catal. 38 (1975) 402-417
67. Chen D.A., and Friend C.M. J. Am. Chem. Soc. 120 (1998) 5017-5023
68. Chen Y.X., Heinen M., Jusys Z., and Behm R.J. Langmuir 22 (2006) 10399-10408
69. Grabow L.C., Gokhale A.A., Evans S.T., Dumesic J.A., and Mavrikakis M. J. Phys. Chem. C 112 (2008) 4608-4617
70. Gokhale A.A., Dumesic J.A., and Mavrikakis M. J. Am. Chem. Soc. 130 (2008) 1402-1414
71. Zeinalipour-Yazdi C.D., and Efstathiou A.M. J. Phys. Chem. C 112 (2008) 19030-19039
72. Gong X.Q., Hu P., and Raval R. J. Chem. Phys. 119 (2003) 6324-6334
73. Ojifinni R.A., Froemming N.S., Gong J., Pan M., Kim T.S., White J.M., Henkelman G., and Mullins C.B. J. Am. Chem. Soc. 130 (2008) 6801-6812
74. Tominaga H., and Nagai M. J. Phys. Chem. B 109 (2005) 20415-20423