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Diels-Alder reaction of 7a and 17 produced a mixture of isomerized products 18 and 1.9 in 89% yield (5:3). "Chemical equation presented"
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Diels-Alder reaction of 7a and 17 produced a mixture of isomerized products 18 and 1.9 in 89% yield (5:3). "Chemical equation presented"
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34
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We also determined the stereochemistry of the other three isomers of 15 by extensive NMR spectroscopic analysis. See the Supporting Information
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Dienophile 7b was prepared from methyl picolinate in two steps including Homer-Wadsworth - Emmons reaction. Dienophile 7c was obtained by inflation of 7a
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Dienophile 7b was prepared from methyl picolinate in two steps including Homer-Wadsworth - Emmons reaction. Dienophile 7c was obtained by inflation of 7a.
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