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To higher precision, the excitation energies of the lowest singlet and triplet interchain states are 6.055966 and 6.056037 eV, respectively.
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Hyperfine interactions are sometimes cited as a possible cause of intersystem crossing in conjugated polymers. However, as the nucleus of C 12 possess no magnetic dipole moment, the only possible hyperfine interaction involving π electrons is with their electric field gradients and the electric-quadrupole moment of the C 12 nuclei.
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