Organic two-step spin-transition-like behavior in a linear S = 1 array: 3′-methylbiphenyl-3,5-diyl bis(tert -butylnitroxide) and related compounds

Journal of the American Chemical Society

Volumn 132, Issue 28, 2010, Pages 9598-9599

  Nishimaki, Hirokazu ^a   Ishida, Takayuki ^a  

^a UNIVERSITY OF ELECTRO COMMUNICATIONS   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1 PHASE; ANTIFERROMAGNETIC COUPLING; DIMENSIONAL ARRAYS; FERROMAGNETIC COUPLING; METHOXY; RELATED COMPOUNDS; SOLID-SOLID PHASE TRANSITIONS; TITLE COMPOUNDS;

ANTIFERROMAGNETISM;

PHASE TRANSITIONS;

3' METHOXY DERIVATIVE; 3' METHYLBIPHENYL 3,5 DIYL BIS(TERT BUTYLNITROXIDE); FERROMAGNETIC MATERIAL; METHYL GROUP; NITROXIDE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BINDING; CHEMICAL REACTION; CONTROLLED STUDY; CROSS COUPLING REACTION; CRYSTAL; MAGNETISM; MELTING POINT; MOLECULE; SOLID; SOLID SOLID PHASE TRANSITION; TEMPERAMENT;

EID: 77954651359     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja102890g     Document Type: Article

References (21)

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17. p-p = 2.2 mT (see Figure 5Sa).
18. 2) (all data) = 0.1195; T = 116 K; 4175 unique reflections. For details, see the Supporting Information.
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21. 2) (all data) = 0.1111; T = 296 K; 4527 unique reflections. The cell was transformed for comparison with those of 3MeBPBN. For details, see the Supporting Information.