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Volumn 49, Issue 28, 2010, Pages 4788-4790

Cleavage of the Sn-Sn multiple bond in a distannyne by cyclooctatetraene: Formation of the π-bound inverse sandwich complex [(Ar'Sn) 2(μ2-η2:η3-cot)]

Author keywords

Delocalization; Distannyne; Terphenyl ligands; Tin; X ray analysis

Indexed keywords

BOND CLEAVAGES; CHEMICAL EQUATIONS; CYCLOOCTATETRAENE; DELOCALIZATIONS; DISTANNYNE; MULTIPLE BONDS; SANDWICH COMPLEXES; TERPHENYL LIGANDS;

EID: 77954006372     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201001276     Document Type: Article
Times cited : (53)

References (42)
  • 34
    • 77953979556 scopus 로고    scopus 로고
    • note
    • max = 50.50; reflections measured = 35237, 11921 independent, R1(I>2σ(I) data) = 0.0407; wR2(all data) = 0.0841. CCDC 767849 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif.
  • 38
    • 77953970370 scopus 로고    scopus 로고
    • note
    • [2] The geometry of [MeSn(cot)SnMe] was first optimized at the B3LYP/Lanl2DZ level and identified as a true local minimum on the energy potential surface by frequency calculations. The geometry was then optimized at the higher B3LYP/ cc-pVTZ-PP level. Molecular orbitais were calculated at the B3LYP/cc-pVTZ-PP//B3LYP/cc-pVTZ-PP level. The calculated geometries and molecular orbitais were generated with Chemcraft (G. A. Zhurko).
  • 41
    • 77953979896 scopus 로고    scopus 로고
    • P. P. Power, Nature 2010, 463, 111.
    • (2010) Nature , vol.463 , pp. 111
    • Power, P.P.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.