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Volumn 49, Issue 12, 2010, Pages 5686-5700

Influence of the redox active ligand on the reactivity and electronic structure of a series of Fe(TIM) complexes

Author keywords

[No Author keywords available]

Indexed keywords

IRON; LIGAND; MACROCYCLIC COMPOUND; ORGANOMETALLIC COMPOUND; ZINC;

EID: 77953580333     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic100586h     Document Type: Article
Times cited : (26)

References (57)
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    • 4* when used in a generic sense, irrespective of their true oxidation state (ranging from 0 to 4-).
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    • Kadish, K. M., Smith, K. M., and Guilard, R., Eds.; Academic Press: New York
    • Synthesis and Organic Chemistry; Kadish, K. M., Smith, K. M., and Guilard, R., Eds.; Academic Press: New York, 2000; Vol. 1.
    • (2000) Synthesis and Organic Chemistry , vol.1
  • 21
    • 77953579785 scopus 로고    scopus 로고
    • Vers. 2008/1; Bruker AXS Inc.: Madison, WI
    • SADABS, Vers. 2008/1; Bruker AXS Inc.: Madison, WI, 2003.
    • (2003) SADABS
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    • 0004150157 scopus 로고    scopus 로고
    • 6.14; Bruker AXS Inc.: Madison, WI
    • ShelXTL, 6.14; Bruker AXS Inc.: Madison, WI, 2003.
    • (2003) ShelXTL
  • 23
    • 0003984036 scopus 로고    scopus 로고
    • In, Version 2.7, Revision 0; Institut für Physikalische und Theoretische Chemie, Universität Bonn: Bonn, Germany
    • Neese, F. In An ab initio, DFT and Semiempirical Electronic Structure Package, Version 2.7, Revision 0; Institut für Physikalische und Theoretische Chemie, Universität Bonn: Bonn, Germany, 2009.
    • (2009) An Ab Initio, DFT and Semiempirical Electronic Structure Package
    • Neese, F.1
  • 38
    • 77953586913 scopus 로고    scopus 로고
    • Molekel; http:\\www.cscs.ch/molkel/.
    • Molekel
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    • 77953556165 scopus 로고    scopus 로고
    • note
    • Q = 2.23 mm/s); Scarborough, C. C, Wieghardt, K., unpublished.
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    • note
    • 6). Attempts to use other proton sources, including pyridinium-hexafluorophosphate, were unsuccessful.
  • 54
    • 77953563229 scopus 로고    scopus 로고
    • note
    • The EPR spectrum appears to be concentration dependent: at higher concentrations (>100 μM), a minor second component is apparent in the EPR spectrum. The origin of the observed spectral changes is not known. No differences are observed in the Mössbauer spectrum of solid samples of 7 vs frozen solutions in THF, suggesting that the electronic structure of 7 remains the same in solution.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.