Reaction of 2-(2,2,2-Trifluoroethylidene)-1,3-dithiane 1-Oxide with ketones under pummerer conditions and its application to the synthesis of 3-Trifluoromethyl-Substituted five-membered heteroarenes

Angewandte Chemie - International Edition

Volumn 49, Issue 13, 2010, Pages 2340-2343

  Kobatake, Takayuki ^a   Yoshida, Suguru ^a   Yorimitsu, Hideki ^a   Oshima, Koichiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Heterocycles; Ketones; Pummerer rearrangement; Sulfoxides; Triflic anhydride

Indexed keywords

CHEMICAL ENGINEERING; CHEMICAL REACTIONS; CHEMISTRY;

CARBONYL OXYGEN ATOMS; CATIONIC SULFURS; HETEROCYCLES; NUCLEOPHILIC ATTACK; PUMMERER REARRANGEMENTS; SIGMATROPIC REARRANGEMENTS; SULFOXIDES; TRIFLIC ANHYDRIDE;

KETONES;

EID: 77953504249     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.200906774     Document Type: Article

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