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We performed cyclic-voltammetry measurements to evaluate the relative energy difference between the HOMO of TMTSF and the LUMO of TCNQ. By regarding the electrochemical half-wave potentials as the corresponding donor or acceptor levels, we obtained the relative energy difference of 230 meV in acetonitrile and 270 meV in dichloromethane, respectively (Pt working electrode, Ag/AgCl reference electrode). These values are in good agreement with those extracted from transport measurements (2 Ea ∼140-240 meV).
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